A pyrolysis waste-to-energy conversion system has a muffle furnace housing a rotating retort drum within the furnace and having an inlet sleeve and an outlet sleeve extending through inlet and outlet ends of the muffle furnace. A rotating retort drum drive applies rotary drive to the inlet rotating retort drum sleeves and an in-feed auger is within a tube within the inlet sleeve. An out-feed auger is within a tube within the outlet sleeve and arranged to deliver char and pyrolysis syngas to a char processing system and a syngas processing system. The inlet sleeve and said outlet sleeve are arranged to provide a gas seal to prevent air ingress or syngas egress to and from the rotating retort drum. A gas cleaning system has a cracking tower arranged to retain inlet gas at an elevated temperature for a residence time, and a gas quench and scrubber system.

A pyrolysis waste-to-energy conversion system has a muffle furnace housing a rotating retort drum within the furnace and having an inlet sleeve and an outlet sleeve extending through inlet and outlet ends of the muffle furnace. A rotating retort drum drive applies rotary drive to the inlet rotating retort drum sleeves and an in-feed auger is within a tube within the inlet sleeve. An out-feed auger is within a tube within the outlet sleeve and arranged to deliver char and pyrolysis syngas to a char processing system and a syngas processing system. The inlet sleeve and said outlet sleeve are arranged to provide a gas seal to prevent air ingress or syngas egress to and from the rotating retort drum. A gas cleaning system has a cracking tower arranged to retain inlet gas at an elevated temperature for a residence time, and a gas quench and scrubber system.

An atmospheric pressure water ion generating device is arranged in a triphase organic matter pyrolysis system which includes a steam generating device and a pyrolysis and carbonization reaction device. The water ion generating device includes a connecting pipe connected with the steam generating device, and having an interior that is penetrated, a heating tube having a first end connected with the connecting pipe and having an interior provided with an air channel, and a spraying head connected with a second end of the heating tube, and having an interior that is tapered. The air channel has a surface provided with an alloy catalyst layer. The spraying head is provided with a nozzle which is connected with the pyrolysis and carbonization reaction device.

A pyrolysis gas reforming system is provided. The pyrolysis gas reforming system includes a pyrolysis unit configured to perform pyrolysis of waste, an oil-gas separation unit configured to separate a product generated by the pyrolysis unit into oil and gas, a pyrolysis gas purification unit configured to refine pyrolysis gas generated through the separation by the oil-gas separation unit, a pyrolysis gas reforming unit configured to generate synthesis gas by reforming the pyrolysis gas purified by the pyrolysis gas purification unit, a hydrogen gas shift reaction unit configured to convert carbon monoxide contained in the synthesis gas generated by the pyrolysis gas reforming unit into hydrogen and carbon dioxide, and a hydrogen separation unit configured to separate hydrogen from the synthesis gas discharged from the hydrogen gas shift reaction unit, wherein combustion gas generated by a burner of the pyrolysis gas reforming unit and used to supply heat to the pyrolysis gas reforming unit is used to supply heat to the pyrolysis unit.

Embodiments of the present invention may provide managing waste including providing non-sorted solid waste (1), processing non-sorted solid waste in a waste handling system (21), shredding (26) non-sorted solid waste to create shredded non-sorted solid waste (27) in a waste handling system; introducing shredded non-sorted solid waste into a thermochemical conversion reactor (4); heating and even chemically converting a shredded non-sorted solid waste; producing hydrochar (22) and a recyclable materials fraction (23); recycling water (24) used in the heating and chemically processing of the shredded non-sorted solid waste in a thermochemical conversion reactor in said waste handling system; sorting (25) the recyclable materials fraction; fueling (28) a thermochemical conversion reactor with hydrochar (22); and perhaps even recycling heat from a thermochemical conversion reactor in the waste handling system.

In some variations, the disclosure provides a renewable biocarbon composition comprising from 50 wt % to 99 wt % total carbon, wherein the biocarbon composition is characterized by a base-acid ratio selected from 0.1 to 10, an iron-calcium ratio selected from 0.05 to 5, iron-plus-calcium parameter selected from 5 to 50 wt %, a slagging factor selected from 0.001 to 1, and/or a fouling factor or modified fouling factor selected from 0.1 to 10. Some variations provide a process comprising: providing a biomass feedstock; pyrolyzing the biomass feedstock to generate an intermediate biocarbon stream; washing or treating the intermediate biocarbon stream with an acid, a base, a salt, a metal, H.sub.2, H.sub.2O, CO, CO.sub.2, or a combination thereof, and/or introducing an additive in the process, to adjust a base-acid ratio or other compositional parameter; and recovering a biocarbon composition comprising from 50 wt % to 99 wt % total carbon and optimized for a compositional parameter.

Electric-powered, closed-loop, continuous-feed, endothermic energy-conversion systems and methods are disclosed. In one embodiment, the presently disclosed energy-conversion system includes a shaftless auger. In another embodiment, the presently disclosed energy-conversion system includes a drag conveyor. In yet another embodiment, the presently disclosed energy-conversion system includes a distillation and/or fractionating stage. The endothermic energy-conversion systems and methods feature mechanisms for natural resource recovery, refining, and recycling, such as secondary recovery of metals, minerals, nutrients, and/or carbon char.

A method for thermally decomposing a carbonaceous waste material including: filling a reactor defined by a reactor wall with the waste material and an auxiliary material, resulting in a reactor content, the auxiliary material including abrasive particles; heating the reactor contents in the absence of oxygen, such that gaseous products are formed by pyrolysis of the waste material and the abrasive particles do not melt or thermally decompose; moving the reactor contents during the pyrolysis, the moving being adapted to mix the reactor contents and to cause the abrasive particles to scrape over at least parts of the reactor wall. The auxiliary material has a composition to include a component adapted to bind halogens present in the gaseous products and/or so that the brittleness of the auxiliary material is greater than the brittleness of the reactor wall.

A method for producing a pyrolysis oil is described. In said method, a feedstock to be treated is first pyrolyzed in a pyrolysis zone, in which the feedstock is heated to a temperature of 250 degrees Celsius to 700 degrees Celsius; and pyrolyzed solids and pyrolysis vapors are formed. The pyrolysis vapors are then reformed at a temperature of 450 degrees Celsius to 1,200 degrees Celsius in a post-conditioning zone, in which the pyrolysis vapors are brought into contact with a catalyst bed, wherein the pyrolysis oil is formed. In this case, the catalyst comprises a pyrolyzed solid, which can be obtained according to the pyrolysis, described above. Finally the pyrolysis oil is separated from the additional pyrolysis products, which are formed, in a separation unit.

Provided is a carbonizing furnace capable of improving combustion efficiency of combustible gas generated by combustion of organic waste and of improving carbonization efficiency of organic waste by appropriately controlling the temperature of carbide. Provided is a pyrolytic furnace in which heating gas can be suppressed from outflowing to the outside from a gap between the upper surface of the body part of the pyrolytic furnace and the outer circumferential surface of a reaction tube where a pyrolysis reaction between carbide and a gasification agent is caused, and in which the temperature of a region where the pyrolysis reaction is caused can be suppressed from being reduced. Provided is a water gas generation system which improves thermal efficiency without using a dedicated heat source for generating water steam to be used as a gasification agent for carbide, promotes a pyrolysis reaction, and thereby, achieves the excellent heat efficiency. Provided are a hydrogen gas generation system and a power generation system which use water gas generated by a water gas generation system including a carbonizing furnace and a pyrolytic furnace and which have excellent productivity. Provided is a carbonizing furnace which improves combustion efficiency by controlling the supply amount of air being supplied to the carbonizing furnace according to the temperature of combustion gas in the carbonizing furnace, and which improves carbonization efficiency by controlling the discharge amount of carbide to be discharged to the outside according to the temperature of carbide or the deposit amount of organic waste in the carbonizing furnace, to make the temperature of carbide appropriate, and by controlling the temperature of air being supplied to the carbonizing furnace. In addition, provided is a pyrolytic furnace which blocks outflow of heating gas or water gas by providing seal portions at the attachment positions of a body part, a reaction tube, and a water gas outlet part, etc. of the pyrolytic furnace, and which maintains a pyrolysis reaction temperature by providing a pyrolysis promoting mechanism to the reaction tube. Provided is a water gas generation system which has excellent thermal efficiency and in which a combustion gas flow path is formed so as to allow combustion gas generated by a carbonizing furnace to flow through a carbonizing furnace, a pyrolytic furnace, a steam superheater, a steam generator, a dryer, and the like. Provided is a hydrogen gas generation system or a power generation system formed by combining the water gas generation system with a hydrogen purifying apparatus or a power generation equipment.