C10B55/00

Using stimulus to convert coal to mesophase pitch and carbon fibers

A method for forming mesophase pitch can include applying a stimulus to a first amount of coal tar to form a first amount of mesophase pitch. The stimulus can include one or more of an electromagnetic field (EMF) or a magnetic field. The method can further include evaluating a characteristic of the first amount of mesophase pitch, changing a parameter of the stimulus in response to evaluating the characteristic of the first amount of mesophase pitch, and applying the stimulus exhibiting the changed parameters to a second amount of coal tar to form mesophase pitch.

Using stimulus to convert coal to mesophase pitch and carbon fibers

A method for forming mesophase pitch can include applying a stimulus to a first amount of coal tar to form a first amount of mesophase pitch. The stimulus can include one or more of an electromagnetic field (EMF) or a magnetic field. The method can further include evaluating a characteristic of the first amount of mesophase pitch, changing a parameter of the stimulus in response to evaluating the characteristic of the first amount of mesophase pitch, and applying the stimulus exhibiting the changed parameters to a second amount of coal tar to form mesophase pitch.

Method and system for utilizing selectively de-coupleable connections for modular installation of a coke drum
09850430 · 2017-12-26 · ·

In one aspect, the present invention relates to a coke drum module, the coke drum module includes a support frame. A coke drum is disposed within the support frame. A strut is removably connected to the support frame and the coke drum. The strut becomes unloaded responsive to the coke drum contacting a support pad. The coke drum module further includes a compression member removably connected to the support frame and the coke drum. The compression member is oriented generally perpendicularly to the strut. A rigid connection is present between the coke drum and the support frame during transportation of the coke drum module. Upon removal of the strut and the compression member, the rigid connection is not present.

Method and system for utilizing selectively de-coupleable connections for modular installation of a coke drum
09850430 · 2017-12-26 · ·

In one aspect, the present invention relates to a coke drum module, the coke drum module includes a support frame. A coke drum is disposed within the support frame. A strut is removably connected to the support frame and the coke drum. The strut becomes unloaded responsive to the coke drum contacting a support pad. The coke drum module further includes a compression member removably connected to the support frame and the coke drum. The compression member is oriented generally perpendicularly to the strut. A rigid connection is present between the coke drum and the support frame during transportation of the coke drum module. Upon removal of the strut and the compression member, the rigid connection is not present.

Process for depolymerizing coal to co-produce pitch and naphthalene

A method of depolymerizing coal includes preparing a high temperature depolymerizing medium consisting of heavy hydrocarbon oils and mixing it with coal to form a mixture, performing an optional first distillation at a temperature below 250 C. to recover naphthalene, heating the mixture to a temperature between 350 C. and 450 C. to create a digested coal, centrifuging the digested coal to remove ash and obtain a centrate, and distillation of the centrate into separate fractions. The high temperature depolymerizing medium may be a heavy hydrocarbon with a hydrogen to carbon (H/C) ratio higher than 7.0% and may include liquids chosen from the group consisting of: coal tar distillate, decant oil, anthracene oil, and heavy aromatic oils. The high temperature depolymerizing medium may be blended with an oil, preferably with H/C ratio higher than 10.0%, such as soybean oil, other biomass derived oil, lignin, petroleum oil, pyrolysis oil such that the overall hydrogen-to-carbon mass ratio in a digestion reactor is over 7.0% for the mixture of depolymerizing medium and coal. The depolymerized coal is an aromatic liquid that can itself be, either wholly or in part, a depolymerizing medium so that the process can be repeated.

Process for depolymerizing coal to co-produce pitch and naphthalene

A method of depolymerizing coal includes preparing a high temperature depolymerizing medium consisting of heavy hydrocarbon oils and mixing it with coal to form a mixture, performing an optional first distillation at a temperature below 250 C. to recover naphthalene, heating the mixture to a temperature between 350 C. and 450 C. to create a digested coal, centrifuging the digested coal to remove ash and obtain a centrate, and distillation of the centrate into separate fractions. The high temperature depolymerizing medium may be a heavy hydrocarbon with a hydrogen to carbon (H/C) ratio higher than 7.0% and may include liquids chosen from the group consisting of: coal tar distillate, decant oil, anthracene oil, and heavy aromatic oils. The high temperature depolymerizing medium may be blended with an oil, preferably with H/C ratio higher than 10.0%, such as soybean oil, other biomass derived oil, lignin, petroleum oil, pyrolysis oil such that the overall hydrogen-to-carbon mass ratio in a digestion reactor is over 7.0% for the mixture of depolymerizing medium and coal. The depolymerized coal is an aromatic liquid that can itself be, either wholly or in part, a depolymerizing medium so that the process can be repeated.

DELAYED COKING PLANT COMBINED HEATING AND POWER GENERATION

A system includes a heat exchange system and a power generation system. The heat exchange system includes first, second, and third heat exchangers each operable as a continuous source of heat from a delayed coking plant. The first and second heat exchangers heat first and second fluid streams to produce heated first and second fluid streams, respectively. The heated second fluid stream has a lower temperature and a greater quantity of heat than the heated first fluid stream. The third heat exchanger heats a third fluid stream to produce a heated third fluid stream that includes the heated first fluid stream and a hot fluid stream. The heated third fluid stream has a lower temperature than the heated first fluid stream. The power generation system generates power using heat from the heated second and third fluid streams.

DELAYED COKING PLANT COMBINED HEATING AND POWER GENERATION

A system includes a heat exchange system and a power generation system. The heat exchange system includes first, second, and third heat exchangers each operable as a continuous source of heat from a delayed coking plant. The first and second heat exchangers heat first and second fluid streams to produce heated first and second fluid streams, respectively. The heated second fluid stream has a lower temperature and a greater quantity of heat than the heated first fluid stream. The third heat exchanger heats a third fluid stream to produce a heated third fluid stream that includes the heated first fluid stream and a hot fluid stream. The heated third fluid stream has a lower temperature than the heated first fluid stream. The power generation system generates power using heat from the heated second and third fluid streams.

Defoaming systems and methods in hydrocarbon processes

Methods for defoaming in hydrocarbon processes include the steps of providing a defoaming agent, and introducing the agent into a hydrocarbon process to inhibit or control foaming in the hydrocarbon process. These methods may be particularly useful in coking processes, especially as to foaming in coke drums. In certain embodiments, defoaming agents may comprise a plurality of carbon nanoparticles. In some embodiments, drag reducing agents may comprise high-molecular weight alkanes. Advantages include, but are not limited to, more efficient and effective foam inhibition, reduced or eliminated product contamination, reduced or eliminated catalyst poisoning, increased refinery production rate, debottlenecking the coker, and reduced cost and consequences of applying too much antifoam.

Defoaming systems and methods in hydrocarbon processes

Methods for defoaming in hydrocarbon processes include the steps of providing a defoaming agent, and introducing the agent into a hydrocarbon process to inhibit or control foaming in the hydrocarbon process. These methods may be particularly useful in coking processes, especially as to foaming in coke drums. In certain embodiments, defoaming agents may comprise a plurality of carbon nanoparticles. In some embodiments, drag reducing agents may comprise high-molecular weight alkanes. Advantages include, but are not limited to, more efficient and effective foam inhibition, reduced or eliminated product contamination, reduced or eliminated catalyst poisoning, increased refinery production rate, debottlenecking the coker, and reduced cost and consequences of applying too much antifoam.