Tools and techniques for biochar production and biochar products are provided in accordance with various embodiments. For example, some embodiments include a method of biochar production that may include introducing a compound that includes at least carbon, oxygen, and hydrogen into a reaction chamber. The compound may be heated to a temperature of at least 1,000 degrees Celsius in the reaction chamber such that the compound reacts through a pyrolysis reaction to produce biochar. The produced biochar may be collected and/or further processed in some cases. In some embodiments, the compound includes at least biomass or a waste product. In some embodiments, the temperature of the reaction chamber is at least 1,100 degrees Celsius. In some embodiments, the compound has a residence time in the reaction chamber between 10 seconds and 1,000 seconds to produce the biochar. Some embodiments include biochar that may include graphite or graphene.

The present invent provides improved rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. In an embodiment, biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. In one embodiment, the liquid product itself is used as the quench media.

The present invent provides improved rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. In an embodiment, biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. In one embodiment, the liquid product itself is used as the quench media.

A method for recovering fibers embedded in a composite material including loading a furnace chamber with a volume of the composite material; thermolyzing the composite material in the furnace chamber, resulting in a gaseous fraction that is continuously evacuated from the furnace chamber, and a residue of fibers covered with char that is left in the furnace chamber; cracking the gaseous fraction from the thermolyzing operation, resulting in a mixture of condensable and non-condensable gases that can be recycled; injecting a stream of an oxygen-containing gas into the still hot furnace chamber after the thermolyzing is completed therein, to burn the char from the fibers in an exothermic combustion.

Embodiments of the invention provide a portable charcoal system and method of operating thereof, wherein the portable charcoal system comprises a first compartment adapted to burn a material, a second compartment connected to the first compartment and adapted to receive the material from the first compartment, and a third compartment adapted to receive the material from the second compartment, the third compartment comprising an auger adapted to move the material from a back end to a front end, and out of the third compartment. The portable charcoal system further includes a source of air.

A shear retort mill for slow ablative pyrolysis features friction heating between shearing surfaces on a rotating disk and a static or rotating cylindrical drum enclosing the disk. A feed enters the workspace between the rotating disk and the bottom of the drum through a hollow feed shaft coupled to the rotating disk. Preferably, an auger compacts and moves the feed downward, and a shredder reduces the feed's particle size. The feed is increasingly ground and pyrolyzed as it is forced between the drum and disk shearing surface. As the dense processed material extrudes at the edge of the workspace, the gases and liquid products are forced inward by the barrier of dense solids. A static exhaust pipe at the center of the rotating feed shaft allows for the exit of these gases, which preferably go to a heat exchanger to recover any condensable fractions.

A shear retort mill for slow ablative pyrolysis features friction heating between shearing surfaces on a rotating disk and a static or rotating cylindrical drum enclosing the disk. A feed enters the workspace between the rotating disk and the bottom of the drum through a hollow feed shaft coupled to the rotating disk. Preferably, an auger compacts and moves the feed downward, and a shredder reduces the feed's particle size. The feed is increasingly ground and pyrolyzed as it is forced between the drum and disk shearing surface. As the dense processed material extrudes at the edge of the workspace, the gases and liquid products are forced inward by the barrier of dense solids. A static exhaust pipe at the center of the rotating feed shaft allows for the exit of these gases, which preferably go to a heat exchanger to recover any condensable fractions.

Biogenic activated carbon compositions disclosed herein comprise at least 55 wt % carbon, some of which may be present as graphene, and have high surface areas, such as Iodine Numbers of greater than 2000. Some embodiments provide biogenic activated carbon that is responsive to a magnetic field. A continuous process for producing biogenic activated carbon comprises countercurrently contacting, by mechanical means, a feedstock with a vapor stream comprising an activation agent including water and/or carbon dioxide; removing vapor from the reaction zone; recycling at least some of the separated vapor stream, or a thermally treated form thereof, to an inlet of the reaction zone(s) and/or to the feedstock; and recovering solids from the reaction zone(s) as biogenic activated carbon. Methods of using the biogenic activated carbon are disclosed.

Treated biochar and methods for treating biochar are provided. The method for treating the biochar includes forcing, assisting or accelerating the movement of an infiltrant into the pores of the biochar, whereby the treatment affects properties of the biochar that provide for a more reliable and predictable biochar for use in various applications, including, but not limited to, agricultural applications.

Processes are provided for the oxidative solubilization of metal-containing petroleum cokes in a basic aqueous solution, so as to segregate a solid metal-containing residue from a solubilized and demineralized organics fraction. Oxidation conditions are provided that optimize the yield of soluble partial oxidation products and minimize the generation of CO.sub.2. In some embodiments, a nanocrystalline copper tetrasilicate oxidation catalyst belonging to the Gillespite group of minerals may be used (Cuprorivaite (CaCuSi.sub.4O.sub.10), Wesselsite (SrCuSi.sub.4O.sub.10), Effenbergerite (BaCuSi.sub.4O.sub.10), or combinations thereof). The pH of the solubilized organics fraction may be reduced, under conditions that precipitate an upgraded carbonaceous material, in some embodiments comprising humic acid analogs, yielding a barren leachate solution.