C10C3/00

Production of carbon fiber from asphaltenes
11731878 · 2023-08-22 · ·

There is provided a process and system for producing carbon fiber products. The process can involve deasphalting a heavy hydrocarbon feedstock, which can contain native asphaltenes, to produce a solid asphaltene particulate material, which can be further treated to produce the carbon fiber products. In some implementations, the solid asphaltene particulate material can be extruded in the presence of a polymer. In some implementations, the solid asphaltene particulate material can be chemically treated with a chemical agent including a Lewis acid, an oxidizing agent and/or a reducing agent before extrusion. In some implementations, the process can further produce activated carbon fibers.

METHODS AND APPARATUS FOR TREATING BITUMEN MIXTURES
20220145186 · 2022-05-12 ·

Disclosed are methods for preparing a high-viscosity non-hazardous bitumen composition for transportation in a railcar, wherein the method may include: (a) providing to a fractionator system a low-viscosity bitumen composition previously residing in a pipeline having a first viscosity and comprising a miscible blend of hydrocarbons, which blend was prepared by mixing a first diluent composition with a first bitumen composition; (b) heating the low-viscosity bitumen composition in the fractionator system at an operating temperature of from 170 C to 232 C to provide a first light fraction and a first heavy fraction; (c) removing at least a portion of the first heavy fraction from the fractionator system, wherein the first heavy fraction has a second viscosity that is higher than the first viscosity; (d) forming a high-viscosity non-hazardous bitumen composition from at least a portion of the first heavy fraction; and (e) directing the high-viscosity non-hazardous bitumen composition to a railcar.

METHOD OF PREPARING HEAVY OIL-DERIVED ANISOTROPIC PITCH FOR CARBON FIBER BASED ON MESOGEN SEPARATION
20220135884 · 2022-05-05 ·

The present disclosure relates to a method of preparing an anisotropic pitch for carbon fiber, and more particularly, to a method of preparing an anisotropic pitch of preparing a pitch having a low softening point by thermally polymerizing heavy oil or residue oil generated in an oil refining process, extracting only a mesogen component, and then heat-treating at a high temperature for a short time. The anisotropic pitch prepared in the present disclosure has advantages of exhibiting the anisotropic content of 100% and controlling the anisotropic content only a simple temperature control as desired and may be used as a precursor of a high value-added carbon material such as carbon fiber and an anode material for a lithium secondary battery.

METHOD OF PREPARING HEAVY OIL-DERIVED ANISOTROPIC PITCH FOR CARBON FIBER BASED ON MESOGEN SEPARATION
20220135884 · 2022-05-05 ·

The present disclosure relates to a method of preparing an anisotropic pitch for carbon fiber, and more particularly, to a method of preparing an anisotropic pitch of preparing a pitch having a low softening point by thermally polymerizing heavy oil or residue oil generated in an oil refining process, extracting only a mesogen component, and then heat-treating at a high temperature for a short time. The anisotropic pitch prepared in the present disclosure has advantages of exhibiting the anisotropic content of 100% and controlling the anisotropic content only a simple temperature control as desired and may be used as a precursor of a high value-added carbon material such as carbon fiber and an anode material for a lithium secondary battery.

Integrated process for mesophase pitch and petrochemical production

An integrated method for mesophase pitch and petrochemicals production. The method including supplying crude oil to a reactor vessel; heating the crude oil in the reactor vessel to a predetermined temperature for a predetermined amount of time; reducing asphaltene content in the crude oil by allowing polymerization reactions to occur in the reactor vessel at an elevated pressure in the absence of oxygen; producing a three-phase upgraded hydrocarbon product comprising gas, liquid, and solid hydrocarbon components, where the liquid hydrocarbon component comprises deasphalted oil and the solid hydrocarbon component comprises mesophase pitch; separating the gas, liquid, and solid hydrocarbon components; directly utilizing the liquid hydrocarbon component for petrochemicals production; and directly utilizing the solid hydrocarbon component for carbon artifact production.

ASPHALT COMPOSITION COMPRISING A MIXTURE OF AN ISOCYANATE AND A PLASTICIZER AS PERFORMANCEADDITIVES

An asphalt composition comprising 0.1 to 8 wt.-% based on the total weight of the composition of an Isocyanate as thermosetting reactive compound and 0.1 to 8 wt.-% based on the total weight of the composition of a plasticizer selected from the group consisting of orthophthalates, terephthalates, cyclohexanoates, azelates, actetates, butyrates, valeriates, alkylsulfonates, adipates, benzoates, dibenzoates, citrates, maleates, phosphates, sebacates, sulfonamides, epoxy es-ters, trimellitates, glycerol esters, succinates, mineral oils and polymeric plasticizers or mixtures thereof, wherein the polymeric plasticizer is selected from the group consisting of Hexanedioic acid polymer with 2,2-dimethyl-1,3-propanediol and 1,2-propanediol isononyl ester, Hexanedioic acid polymer with 1,2-propanediol octyl ester and Hexanedioic acid polymer with 1,2-propanediol acetate or mixtures thereof.

Pitch process
11319491 · 2022-05-03 ·

A process for making mesophase and/or isotropic pitch. An aromatic rich liquid is charged at high temperature and pressure to a first thermal polymerization reactor to produce an effluent stream which is flashed to remove unconverted or partially converted feed as a vapor yielding a liquid phase enriched in isotropic pitch. The enriched isotropic pitch liquid is charged to a second thermal reactor and reactor effluent flashed to produce mesophase pitch and a vapor phase. The vapor phases from both flashing steps are condensed and combined for recycle of a liquid aromatic rich stream to the first reactor. Flashing from the first reactor cools the liquid phase which is enriched in isotropic pitch. This enriched stream is mixed with a superheated fluid, preferably steam, upstream of the second reactor.

Apparatus, system and method for providing a bitumen-rich stream from bitumen-containing materials

Method and apparatus to facilitate recycling of at least one fraction of bitumen-containing materials. This can be accomplished by dissolving the at least one fraction, for example, maltenes or asphaltenes in roofing shingles, into at least one solvent. In one aspect, the apparatus comprises a dissolution vessel, a tumbler positioned therein, and at least one solvent distributor. The tumbler is configured to facilitate wetting the bitumen-containing materials with solvent. In a second aspect, a system comprises the apparatus, a solid-liquid separator, for example, a vibratory screen, and at least one solvent-fraction separator, for example, a flash drum. The at least one solvent can comprise one or more solvents useful to extract the at least one fraction. In a third aspect, a first fraction is extracted from the bitumen-containing materials with a first solvent composition, then a second fraction is extracted from the remaining bitumen-containing materials with a second solvent composition.

METHOD FOR PRODUCING PITCH

The present invention provides pitch for manufacturing carbon materials, the pitch having a high fixed carbon content and low viscosity and being obtained by using a petroleum-based heavy oil as a material. Pitch is produced by a method comprising: a step for preparing a material oil containing a petroleum-based heavy oil and an indene compound represented by general formula (1) (step 1); a step for thermally treating the material oil (step 2); and a step for distilling the thermally treated product and obtaining pitch as a high-boiling-point component (step 3). (In general formula (1), Ar represents an aromatic ring having 1 to 3 rings; R.sub.1 to R.sub.4 each independently represent a hydrogen atom, an alkyl group having 1 to 3 carbon atoms or an alkenyl group having 2 to 3 carbon atoms; R.sub.5 represents an alkyl group having 1 to 3 carbon atoms or an alkenyl group having 2 to 3 carbon atoms; m represents an integer from 1 to 3; n represents an integer from 0 to 4 (when the number of rings of Ar is 1), an integer from 0 to 6 (when the number of rings of Ar is 2), or an integer from 0 to 8 (when the number of rings of Ar is 3); adjacent R.sub.5s may be bonded together to form an alicyclic ring; and a hydrogen atom is bonded to Ar which is not substituted by R.sub.5.)

Methods for forming resins and other byproducts from raw coal

A method of producing at least one or more resins is disclosed. The method includes providing an amount of raw coal. The raw coal includes one or more impurities therein. The method also includes beneficiating the amount of raw coal to selectively removing at least a portion of some of the one or more impurities in the raw coal to form beneficiated coal. Additionally, the method includes processing the beneficiated coal to produce an amount of pitch. The method further includes modifying at least some of the pitch to produce the one or more resins. The one or more resins include a selected amount of a remainder of the one or more impurities that were not removed while beneficiating the amount of the raw coal, processing the beneficiated coal, and modifying at least some of the pitch.