This invention is directed to the discovery of a reactive catalytic fast pyrolysis (RCFP) process utilizing hydrogen at low pressures.

This invention is directed to the discovery of a reactive catalytic fast pyrolysis (RCFP) process utilizing hydrogen at low pressures.

This invention is directed to the discovery of a reactive catalytic fast pyrolysis (RCFP) process utilizing hydrogen at low pressures.

This invention is directed to the discovery of a reactive catalytic fast pyrolysis (RCFP) process utilizing hydrogen at low pressures.

Methods, processes, systems, or apparatus are provided to remove contaminants such as metals and chlorine present in a pyrolysis stream to form reduced-contaminant liquid biomass. In certain embodiments, for example, a metal chelating agent is dissolved into a metal-containing pyrolysis stream condensate to form metal chelate complex, followed by filtering to obtain the reduced-contaminant liquid biomass.

Tools and techniques for pyroligneous acid production are provided in accordance with various embodiments. For example, a method of pyroligneous acid production is provided. The method may include: introducing a compound that includes at least carbon, oxygen, and hydrogen into a reaction chamber; heating the compound to a temperature of at least 700 degrees Celsius in the reaction chamber such that the compound reacts through a pyrolysis reaction to produce a liquid, where the liquid may include pyroligneous acid; and/or collecting the produced liquid. In some cases, the residence time of the compound may be less than 1,000 seconds. Temperatures above 1,000 degrees Celsius may be utilized in some cases. The produced liquid may be separated into an oil component and a water component that includes the pyroligneous acid. A lighter fraction may be distilled from the water component, where the lighter component includes the pyroligneous acid.

Tools and techniques for pyroligneous acid production are provided in accordance with various embodiments. For example, a method of pyroligneous acid production is provided. The method may include: introducing a compound that includes at least carbon, oxygen, and hydrogen into a reaction chamber; heating the compound to a temperature of at least 700 degrees Celsius in the reaction chamber such that the compound reacts through a pyrolysis reaction to produce a liquid, where the liquid may include pyroligneous acid; and/or collecting the produced liquid. In some cases, the residence time of the compound may be less than 1,000 seconds. Temperatures above 1,000 degrees Celsius may be utilized in some cases. The produced liquid may be separated into an oil component and a water component that includes the pyroligneous acid. A lighter fraction may be distilled from the water component, where the lighter component includes the pyroligneous acid.

A process for upgrading pyrolysis oil that includes heating pyrolysis oil in the absence of added catalyst at 100 C. to 200 C. temperature and 50 bar to 250 bar pressure, and heating the product of the first heating in the absence of added catalyst at 200 C. to 400 C. temperature and 50 bar to 250 bar pressure. Also, the product obtained by this process and the use of treated pyrolysis oil. Further, methods where the treated pyrolysis oil is fed to a power plant for producing electricity; is burned in a boiler for producing heating oil and/or is used as transportation fuel or as a blending component in transportation fuel.

There is described a processor for use in the microwave torrefaction of biomass material which comprises, a micronized biomass char material and a method of producing a biomass char material, and a method of producing L-glucosan.

There is described a processor for use in the microwave torrefaction of biomass material which comprises, a micronized biomass char material and a method of producing a biomass char material, and a method of producing L-glucosan.