Provided is a carbon dioxide recovery device including an absorption part that produces a compound of carbon dioxide and an amine contained in an absorbing solution, and a regeneration part that includes an anode that desorbs the carbon dioxide from the compound to produce a complex compound of the amine, and a cathode that is electrically connected to the anode and regenerates the amine from the complex compound.

Pathways are disclosed for the production of liquefied petroleum gas (LPG) products comprising propane and/or butane, and in certain cases renewable products having non-petroleum derived carbon. In particular, a gaseous feed mixture comprising CO.sub.2 in combination with CH.sub.4 and/or H.sub.2 is converted by reforming and/or reverse water-gas shift (RWGS) reactions, further in combination with LPG synthesis. A preferred gaseous feed mixture comprises biogas or otherwise a mixture of CO.sub.2 and H.sub.2 that is not readily upgraded using conventional processes. Catalysts described herein have a high activity for reforming (including dry reforming) of CH.sub.4, as well as simultaneously catalyzing RWGS. These attributes improve the management of CO.sub.2 that is input to the disclosed processes, particularly in those utilizing recycle operation to increase overall CO.sub.2 conversion. Economics of small scale operations may be improved, if necessary, using an electrically heated reforming reactor in the first or initial reforming stage or RWGS stage.

The present disclosure relates to the field of Fischer-Tropsch synthesis reaction catalysts, and discloses a pure phase ε/ε′ iron carbide catalyst for Fischer-Tropsch synthesis reaction, a preparation method thereof and a Fischer-Tropsch synthesis process, wherein the method comprises the following steps: (1) subjecting the nanometer iron powder or a nano-powder iron compound capable of obtaining the nanometer iron powder through in-situ reduction and H.sub.2 to a surface purification treatment at the temperature of 250-510° C.; (2) pretreating the material obtained in the step (1) with H.sub.2 and CO at the temperature of 80-180° C., wherein the molar ratio of H.sub.2/CO is 1.2-2.8:1; (3) carrying out carbide preparation with the material obtained in the step (2), H.sub.2 and CO at the temperature of 180-280° C., wherein the molar ratio of H.sub.2/CO is 1.0-3.0:1. The preparation method has the advantages of simple and easily obtained raw materials, simple and convenient operation steps, being capable of preparing the 100% pure phase ε/ε′ iron carbide catalyst having lower selectivity of CO.sub.2 and CH.sub.4 and higher selectivity of effective products.

A feedstock delivery system transfers a carbonaceous material, such as municipal solid waste, into a product gas generation system. The feedstock delivery system includes a splitter for splitting bulk carbonaceous material into a plurality of carbonaceous material streams. Each stream is processed using a weighing system for gauging the quantity of carbonaceous material, a densification system for forming plugs of carbonaceous material, a de-densification system for breaking up the plugs of carbonaceous material, and a gas and carbonaceous material mixing system for forming a carbonaceous material and gas mixture. A pressure of the mixing gas is reduced prior to mixing with the carbonaceous material, and the carbonaceous material to gas weight ratio is monitored. A transport assembly conveys the carbonaceous material and gas mixture to a first reactor where at least the carbonaceous material within the mixture is subject to thermochemical reactions to form the product gas.

Fischer-Tropsch process for the synthesis of hydrocarbons by bringing a feedstock including synthesis gas into contact with a catalyst prepared by the following: a porous support is brought into contact with a cobalt metal salt of which the melting point of the cobalt metal salt is between 30 and 150° C. for between 5 minutes and 5 hours, in order to form a solid mixture, the weight ratio of said cobalt metal salt to the porous oxide support being between 0.1 and 1; the solid mixture obtained is heated with stirring under atmospheric pressure at a temperature between the melting point of the cobalt metal salt and 200° C. for a period of time of between 30 minutes and 12 hours; the solid obtained is calcined at a temperature above 200° C. and below or equal to 1100° C.

A process for commencing a continuous reaction in a reactor system includes introducing a catalyst to a catalyst processing portion of the reactor system, the catalyst initially having a first temperature of 500 C or less, and contacting the catalyst at the first temperature with a commencement fuel gas stream, which includes at least 80 mol % commencement fuel gas, in the catalyst processing portion. Contacting of the catalyst with the commencement fuel gas stream causes combustion of the commencement fuel gas. The process includes maintaining the contacting of the catalyst with the commencement fuel gas stream until the temperature of the catalyst increases from the first temperature to a second temperature at which combustion of a regenerator fuel source maintains an operating temperature range in the catalyst processing portion.

Methods and apparatus for compact and easily maintainable waste reformation. Some embodiments include a rotary oven reformer adapted and configured to provide synthesis gas from organic waste. Some embodiments include a rotary oven with simplified operation both as to reformation of the waste, usage of the synthesized gas and other products, and easy removal of the finished waste products, preferably in a unit of compact size for use in austere settings. Yet other embodiments include Fischer-Tropsch reactors of synthesized gas. Some of these reactors include heat exchanging assemblies that provide self-cleaning effects, efficient utilization of waste heat, and ease of cleaning.

The invention proposes a method comprising (i) using a lignocellulosic raw material based process for production of synthetic gas; (ii) introducing the syngas to a Fischer-Tropsch (FT) catalytic synthesis (FTS) process and generating Fischer-Tropsch products, wherein the synthetic gas production process comprises the steps a) extracting lignins and hemicelluloses by putting solid lignocellulosic raw material in contact with a mixture composed of at least water and formic acid, at atmospheric pressure under temperature between 80° C. and 110° C., b) fractionating the obtained primary solid fraction (PSF) and primary liquid fraction (PLF); c) recovering and obtaining an intermediate liquid fraction (ILF); d) separating the lignins; e) gasifying at least part of said primary solid fraction (PSF) for producing synthetic gas.

The invention proposes a method comprising (i) using a lignocellulosic raw material based process for production of synthetic gas; (ii) introducing the syngas to a Fischer-Tropsch (FT) catalytic synthesis (FTS) process and generating Fischer-Tropsch products, wherein the synthetic gas production process comprises the steps a) extracting lignins and hemicelluloses by putting solid lignocellulosic raw material in contact with a mixture composed of at least water and formic acid, at atmospheric pressure under temperature between 80° C. and 110° C., b) fractionating the obtained primary solid fraction (PSF) and primary liquid fraction (PLF); c) recovering and obtaining an intermediate liquid fraction (ILF); d) separating the lignins; e) gasifying at least part of said primary solid fraction (PSF) for producing synthetic gas.

The present invention relates to catalytically active material, comprising grains of non-graphitizing carbon with iron nanoparticles dispersed therein, wherein d.sub.p, the average diameter of iron nanoparticles in the non-graphitizing carbon grains, is in the range of 1 nm to 20 nm, D, the average distance between iron nanoparticles in the non-graphitizing carbon grains, is in the range of 2 nm to 150 nm, and ω, the combined total mass fraction of metal in the non-graphitizing carbon grains, is in the range of 30 wt % to 70 wt % of the total mass of the non-graphitizing carbon grains, and wherein d.sub.p, D and ω conform to the following relation: 4.5 d.sub.p/ω>D≥0.25 d.sub.p/ω. The present invention, further, relates to a process for the manufacture of material according to the invention, as well as its use as a catalyst.