The present invention relates to a coke reducing additive composition capable of simultaneously (a) reducing coke formation and (b) increasing distillate yield during pyrolysis of a feedstock in the presence of a plastic material, wherein the feedstock is a vacuum residue (VR), plastic material is a waste plastic material or an olefin polymer (OP) material, or a mixture thereof, and the coke reducing additive composition comprises a naphthenate, preferably a calcium naphthenate, or sodium naphthenate, or a mixture thereof, and to a method of employing the coke reducing additive composition, and to a method of use of the coke reducing additive composition of the present invention.

Particularly, in another embodiment, the present invention relates to a coke reducing additive composition capable of simultaneously (a) reducing formation of coke deposits on walls of the processing unit; and (b) reducing fouling caused due to deposits of coke products on walls of the processing unit during pyrolysis of a feedstock in the presence of a plastic material, wherein the feedstock is a vacuum residue (VR), plastic material is a waste plastic material or an olefin polymer (OP) material, or a mixture thereof, and the coke reducing additive composition comprises a naphthenate, preferably a calcium naphthenate, or sodium naphthenate, or a mixture thereof, and to a method of employing the coke reducing additive composition, and to a method of use of the coke reducing additive composition of the present invention.

Particularly, in yet another embodiment, the present invention relates to a method to convert a waste plastic into useful chemical commodity.

The present invention provides a process for production of graphite coke from an admixture of coal and petroleum-based hydrocarbons. This particularly describes a process wherein a mixture of coal tar pitch and hydrocarbon feedstock such as CLO is purified in a solvent treatment step and the purified mixed feedstock is subjected to thermal cracking to produce high quality graphite/needle coke. This process also provides a synergy in improved coke quality coke formation while using an admixture of coal tar pitch and CLO while subjected to common purification and coking steps.

This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.

The present disclosure generally relates to systems and methods utilizing regenerative agriculture for the procurement, production, refinement and/or transformation of low carbon intensity transportation fuels, including low carbon intensity biodiesel and/or renewable diesel, low carbon intensity biogasoline, low carbon intensity aviation, marine and kerosene fuels as well as fuel oil blends, low carbon intensity ethanol, and low carbon intensity hydrogen, that may be beneficially commercialized directly to consumers. In further aspects, the systems and methods of the present disclosure advantageously generate low carbon intensity comestibles, including sustainably-sourced meal and/or feed. The disclosed systems and methods may be utilized and optimized such that the resulting fuels and foodstuffs are characterized by a reduction in greenhouse gas production and a diminution in the fertilizer, pesticide and water required for producing the associated crop feedstocks.

The present disclosure generally relates to systems and methods utilizing regenerative agriculture for the procurement, production, refinement and/or transformation of low carbon intensity transportation fuels, including low carbon intensity biodiesel and/or renewable diesel, low carbon intensity biogasoline, low carbon intensity aviation, marine and kerosene fuels as well as fuel oil blends, low carbon intensity ethanol, and low carbon intensity hydrogen, that may be beneficially commercialized directly to consumers. In further aspects, the systems and methods of the present disclosure advantageously generate low carbon intensity comestibles, including sustainably-sourced meal and/or feed. The disclosed systems and methods may be utilized and optimized such that the resulting fuels and foodstuffs are characterized by a reduction in greenhouse gas production and a diminution in the fertilizer, pesticide and water required for producing the associated crop feedstocks.

In one aspect, the present invention relates to a furnace having a heated portion arranged adjacent to an unheated portion. A plurality of straight tubes are formed of a first material and are at least partially disposed in the heated portion. A plurality of return bends are operatively coupled to the plurality of straight tubes. The plurality of return bends are formed of a second material and are at least partially disposed in the unheated portion. The first material exhibits a maximum temperature greater than the second material thereby facilitating increased run time of the furnace. The second material exhibits wear-resistance properties greater than the first material thereby facilitating wear-resistance of the furnace.

Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.

Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.

A method of producing an aromatic chemical, comprises: providing a feedstock comprising biomass to a first reactor to produce a first product stream, wherein the first product stream comprises methane and carbon dioxide; combining the first product stream with a recycle stream to form a second reactor feed stream; passing the second reactor feed stream through a second reactor to produce a second product stream comprising aromatics and hydrogen gas; recovering aromatics from the second product stream to create a recovery stream depleted of aromatics; combining the recovery stream with a stream comprising carbon dioxide to form a combined recovery stream; passing the combined recovery stream to a third reactor to produce the recycle stream comprising gas; and forming an aromatic chemical from the second product stream.

In this invention, a portion of the products from a pyrolysis reactor are reacted in a process to form one or more chemical intermediates.