The invention relates to a process and system arrangement to generate benzene, toluene and xylenes in a refinery. The process relies on recycling a C.sub.9+ aromatic bottoms stream from an aromatic recovery complex back to rejoining a hydrotreated naphtha stream as it enters a catalytic reformer. The aromatic bottoms can be further reacted through both the reformer and the subsequent aromatic recovery complex to transform to higher value compounds, thereby reducing waste or reducing bottoms' presence in gasoline pools.

The invention relates to removing contaminants from oil using solid sorbents that are comprised primarily of carbon and preferably of coke particles. The coke particles have an affinity for contaminants in oil and are sized to be filtered from oil without plugging. Most contaminants have such a small size that they tend to plug up filters. As the contaminants agglomerate onto the solid sorbent, the resulting particles form a filter cake on conventional filter materials in such a way as to allow the oil to pass on through without significant pressure drop or delay.

The invention is directed to utilization of a series of cross-linked 1,4-benzenediamine-co-alkyldiamine polymers and the use of the polymers to remove mercury from a hydrocarbon in fluid form.

A method for predicting selective performance of an adsorbent is disclosed. The adsorbent is selected from a list of metals and/or metal cations for use in removing contaminants as thiophene derivatives in hydrocarbon feed. The metals or metal cations are identified from a list having a positive value for E.sub.rel, wherein the metal or metal cation having the largest value for E.sub.rel is the most selective adsorbent.

Dehydration method for a liquid or gaseous effluent selected from LPG, gasoline, diesel, kerosene, solvents and natural gases, by inserting the liquid or gaseous effluent against gravity through a drying column having a drying bed with an initial height (H+h) constituted in its lower area by an inert material bed having the height of h and in its upper area by deliquescent desiccants having an initial height of H. The deliquescent desiccants have an initial weight of between 3 and 40 g, the h/H ratio is lower than 0.49, and the inert material has a specific surface area greater than 100 m2/m3 and lower than 800 m2/m3. The method further includes separating water obtained from the liquid or gaseous effluent.

Disclosed is a process for the purification of an organic composition (OC1) by adsorption using an assembly containing at least two adsorbers. The organic composition (OC1) comprising at least one alkane, at least one olefin and at least one compound containing oxygen and/or sulphur is fed into a first adsorber (A1) of the assembly in order to obtain an organic composition (OC2) comprising at least one alkane, at least one olefin and a reduced amount of at least one compound containing oxygen and/or sulphur compared to the respective amount in organic composition (OC1). Hydrogenation of the organic composition (OC2) provides a stream (S2) comprising at least one alkane and a reduced amount of at least one olefin compared to the respective amount in organic composition (OC2) obtained after feeding into the first adsorber (A1). A second adsorber (A2) of the assembly is regenerated by contact with stream (S2).

Described herein is a base oil synthesis via ionic catalyst oligomerization further utilizing a hydrophobic process for removing an ionic catalyst from a reaction mixture with a silica gel composition, specifically a reaction mixture comprising an oligomerization reaction to produce PAO utilizing an ionic catalyst wherein the ionic catalyst is removed post reaction.

A process for upgrading a naphtha feed includes separating the naphtha feed into at least a light naphtha fraction, contacting the light naphtha fraction with hydrogen in the presence of at least one cyclization catalyst, and contacting the cyclization effluent with at least one cracking catalyst. Contacting the light naphtha fraction with hydrogen in the presence of at least one cyclization catalyst may produce a cyclization effluent comprising a greater concentration of naphthenes compared to the light naphtha fraction. Contacting the cyclization effluent with at least one cracking catalyst under conditions sufficient to crack at least a portion of the cyclization effluent may produce a fluid catalytic cracking effluent comprising light olefins, gasoline blending components, or both. A system for upgrading a naphtha feed includes a naphtha separation unit, a cyclization unit disposed downstream of the naphtha separation unit, and a fluid catalytic cracking unit disposed downstream of the cyclization unit.

A multi-stage process for reducing the environmental contaminants in an ISO8217 compliant Feedstock Heavy Marine Fuel Oil involving a core desulfurizing process and a ultrasound treatment process as either a pre-treating step or post-treating step to the core process. The Product Heavy Marine Fuel Oil complies with ISO 8217 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process is also disclosed.

A process of removing at least one metal contaminant, such as copper, from a fluid hydrocarbon, for example, crude oil or a liquid hydrocarbon fuel, such as an aviation fuel. The process involves contacting the metal-contaminated fluid hydrocarbon with a sorbent selected from graphene oxide or a functionalized graphene oxide, particularly, a graphene oxide treated with a polycarboxylic acid, such as a saccharide polycarboxylic acid or a salt thereof, examples of which include alginic acid and Group IA and IIA salts thereof. The process removes greater than 99 percent of the metal contaminant without reducing concentrations of advantageous fuel additives, such as, antioxidants, icing inhibitors and corrosion inhibitors. Also described are a purified fluid hydrocarbon composition and a metal contaminant filter system.