A lubricating oil composition for internal combustion engines is disclosed. The composition exhibits a lower coefficient of friction and improved cleaning properties without causing a deterioration in thermal and oxidation stability.

Disclosed herein is an overbased alkaline earth metal hydrocarbyl-substituted salicylate detergent comprising both carbonate and borate moieties and exhibiting the following characteristics: a basicity index of at least 3.8; a ratio of soap content to mass % boron is greater than 55 mmol/kg; a soap content of at least 330 mmol/kg; a TBN, measured according to ASTM D2896, of at least 220 mg KOH/g; and a mass ratio of borate to carbonate from 0.75 to 6.0, wherein the alkaline earth metal comprises calcium and/or magnesium, and the hydrocarbyl substitution comprises 9 to 30 carbon atoms. Methods of making the boron-containing salicylate detergent, specifically to be package-stable, are also disclosed, as well as package-stable lubricant additive package concentrates and lubricating oil compositions containing same.

Disclosed herein is an overbased alkaline earth metal hydrocarbyl-substituted salicylate detergent comprising both carbonate and borate moieties and exhibiting the following characteristics: a basicity index of at least 3.8; a ratio of soap content to mass % boron is greater than 55 mmol/kg; a soap content of at least 330 mmol/kg; a TBN, measured according to ASTM D2896, of at least 220 mg KOH/g; and a mass ratio of borate to carbonate from 0.75 to 6.0, wherein the alkaline earth metal comprises calcium and/or magnesium, and the hydrocarbyl substitution comprises 9 to 30 carbon atoms. Methods of making the boron-containing salicylate detergent, specifically to be package-stable, are also disclosed, as well as package-stable lubricant additive package concentrates and lubricating oil compositions containing same.

The invention provides a lubricant composition containing an oil of lubricating viscosity and a boron-containing en.) compound, wherein the boron containing compound comprises a borate ester comprising at least one alkyl group having a branch at the ? position or higher. The invention further relates to a method of lubricating an internal combustion engine with the lubricant composition.

The invention provides a lubricant composition containing an oil of lubricating viscosity and a boron-containing en.) compound, wherein the boron containing compound comprises a borate ester comprising at least one alkyl group having a branch at the ? position or higher. The invention further relates to a method of lubricating an internal combustion engine with the lubricant composition.

A process for producing a borated polyalkenyl succinimide dispersant composition in which the boron is incorporated primarily as cyclic metaboric acid moieties and the equivalents of boron incorporated per equivalent of nitrogen in the succinimide carrier is greater than 2; in which process a slurry of orthoboric acid is added to a polyalkenyl succinimide to form a reaction mixture, which reaction mixture is then heated under conditions (at a temperature and pressure and for a time) sufficient to remove from the reaction mixture from about 0.8 to about 1.2 moles of water of reaction per mole of boric acid charged.

A process for producing a borated polyalkenyl succinimide dispersant composition in which the boron is incorporated primarily as cyclic metaboric acid moieties and the equivalents of boron incorporated per equivalent of nitrogen in the succinimide carrier is greater than 2; in which process a slurry of orthoboric acid is added to a polyalkenyl succinimide to form a reaction mixture, which reaction mixture is then heated under conditions (at a temperature and pressure and for a time) sufficient to remove from the reaction mixture from about 0.8 to about 1.2 moles of water of reaction per mole of boric acid charged.

The lubricating oil composition of the present invention contains, together with a base oil, a viscosity index improver (A) including a comb-shaped polymer (A1), a detergent dispersant (B) including an alkali metal borate (B1) and an organometallic compound (B2) containing a metal atom selected from an alkali metal atom and an alkaline earth metal atom, and a friction modifier (C) including a molybdenum-containing friction modifier, with the total content of an alkali metal atom and an alkaline earth metal atom being 2,000 mass ppm or less. The lubricating oil composition of the present invention has excellent detergency, fuel saving properties, and LSPI-preventing properties.

The lubricating oil composition of the present invention contains, together with a base oil, a viscosity index improver (A) including a comb-shaped polymer (A1), a detergent dispersant (B) including an alkali metal borate (B1) and an organometallic compound (B2) containing a metal atom selected from an alkali metal atom and an alkaline earth metal atom, and a friction modifier (C) including a molybdenum-containing friction modifier, with the total content of an alkali metal atom and an alkaline earth metal atom being 2,000 mass ppm or less. The lubricating oil composition of the present invention has excellent detergency, fuel saving properties, and LSPI-preventing properties.

A method for improving corrosion protection and friction coefficient in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition comprising a lubricating oil base stock as a major component, and a mixture of (i) at least one organic molybdenum compound, and (ii) at least one borated ester, as a minor component. Corrosion protection and friction coefficient are improved as compared to corrosion protection and friction coefficient achieved using a lubricating oil containing a minor component other than the mixture of (i) at least one organic molybdenum compound, and (ii) at least one borated ester.