A method for producing steel in which iron ore is reduced with hydrogen and the resulting intermediate product of reduced iron ore is subjected to further metallurgical processing; the hydrogen is produced through electrolysis of water; the electrical energy required for the electrolysis is regenerative energy from hydroelectric, wind, and/or photovoltaic sources and the hydrogen and/or the intermediate product is produced regardless of demand, whenever enough regeneratively produced electrical energy is available; and unneeded intermediate product is stored until there is demand or it is used so that the regenerative energy that is stored therein is also stored; and using a calculation model to calculate a required discharge rate in a reduction shaft to achieve a desired metallization grade of the steel by tracing batches of the iron ore in the reduction shaft, and using the calculation model to calculate the amount of carbon-containing gas or hydrogen-containing gas to add to the hydrogen for the reduction.

A method for mitigating the buildup of direct reduced iron (DRI) clusters on the walls of a direct reduction (DR) furnace, comprising: injecting one or more of lime, dolomite, and another anti-sticking agent into a charge disposed within a reduction zone of the DR furnace, wherein the one or more of lime, dolomite, and another anti-sticking agent is injected into the charge by one or more of: (1) injecting the one or more of lime, dolomite, and another anti-sticking agent into a bustle gas stream upstream of a bustle of the DR furnace; (2) injecting the one or more of lime, dolomite, and another anti-sticking agent into the bustle gas stream in the bustle of the DR furnace; (3) injecting the one or more of lime, dolomite, and another anti-sticking agent into the bustle gas stream through a pipe collocated with a bustle gas port through which the bustle gas stream is introduced into the DR furnace; and (4) injecting the one or more of lime, dolomite, and another anti-sticking agent directly into the reduction zone of the DR furnace separate from the bustle gas stream.

Provided is an apparatus for manufacturing reduced iron and a method for manufacturing reduced iron. The method for manufacturing reduced iron includes the steps of: i) drying ores in an ore drier; ii) supplying the dried ores to at least one reduction reactor; iii) reducing the ores in the at least one reduction reactor and manufacturing reduced iron; iv) discharging exhaust gas by which the ores are reduced in the reduction reactor; v) branching the exhaust gas and providing the branched exhaust gas as ore feeding gas; and vi) exchanging heat between the exhaust gas and the ore feeding gas and transferring the sensible heat of the exhaust gas to the ore feeding gas. In the steps of supplying the dried ores to the at least one reduction reactor, the dried ores are supplied to the at least one reduction reactor by using the ore feeding gas.

A method for producing granular metallic iron of the present invention includes: an agglomeration step of obtaining agglomerates through agglomeration of a mixture that contains an iron oxide-containing material and a carbonaceous reducing agent; and a granulation step of obtaining granular metallic iron by heating the agglomerates, reducing iron oxides in the agglomerates, aggregating generated metallic iron to be granular while separating the metallic iron from slag generated as a by-product, and thereafter cooling and solidifying the metallic iron, wherein agglomerates satisfying all the conditions given by formulas (1) to (3) below are used as the agglomerates: (1) [(total CaO amount+total SiO.sub.2 amount+total Al.sub.2O.sub.3 amount)/total Fe amount]≧0.250; (2) (total CaO amount/total SiO.sub.2 amount)≧0.9; (3) [total Al.sub.2O.sub.3 amount/(total CaO amount+total SiO.sub.2 amount+total Al.sub.2O.sub.3 amount)]×100≧9.7. In the formulas, the total CaO amount, the total SiO.sub.2 amount, the total Al.sub.2O.sub.3 amount and the total Fe amount respectively represent the mass percentage of CaO, the mass percentage of SiO.sub.2, the mass percentage of Al.sub.2O.sub.3 and the mass percentage of Fe contained in the agglomerates.

A DRI product and method of forming the DRI product. DRI is formed from a reducing process, and thereafter the DRI is subjected to another heat treatment that produces a DRI product. The DRI product formed has a metallic shell around at least a portion of a DRI core. The heat treatment may be delivered through the use of a plasma torch, a gas burner, an oven, or any other like heat source. The heat treatment may heat the DRI for a fraction of a second and quickly cool the DRI in order to melt the surface and form the metallic shell without vaporizing a significant portion of the DRI and without losing a significant amount of the latent energy in the DRI.

Direct reduction process and plant for producing DRI comprising a reduction reactor and at least one reducing gas heater typically comprising a convective heating section and a radiant heating section for raising the reducing gas temperature to a level adequate for iron oxides reduction to metallic iron, typically above 850° C., wherein the reducing gas fed to the reduction reactor comprises a stream of reducing gas recycled from the reduction reactor and a make-up stream of coke oven gas containing carbon compounds which may form carbon deposits in the heating path of said heater, namely BTX and other complex carbon compounds. The heater is provided with means for feeding oxidizing agents, for example steam, steam and air and/or oxygen at predetermined heating tubes successively for eliminating the carbon deposits which may form inside the heating tubes of said heater without interrupting the operation of the plant. The make-up stream of cold COG can be combined with the recycled gas at a point in the gas heating path of the heater where the tubes have a skin wall temperature of at least 700° C., or when the mixture of recycled gas and COG is at a temperature above 700° C. for minimizing clogging or fouling of heating equipment.

A method and a device for reducing iron-oxide-containing feedstocks, in which a reducing gas is fed to a reducing unit (1) containing the iron-oxide-containing feedstocks. The reducing gas is generated by introducing a process gas having reduction potential into a heating appliance (3) for heating the process gas, which is withdrawn as reducing gas therefrom. In the heating appliance (3), heat energy is transferred to the process gas. The heat energy is formed by combustion of a fuel gas containing organic substances, including coke oven gas with addition of technically pure oxygen. The flames of the combustion have an adiabatic flame temperature of above 1000° C., wherein, in the combustion of the fuel gas, at least some of the organic substances present in the fuel gas are cracked.

A method of starting a molten bath-based process for smelting a metalliferous material is disclosed. The method includes using the heat flux of water-cooled elements in lower parts of a smelting vessel to provide an indication of molten bath temperature during at least an early part of the start-up method and adjusting injection rates of oxygen-containing gas and/or carbonaceous material into the smelting vessel to control the molten bath temperature during start-up without exceeding critical heat flux levels and tripping the start-up method.

Disclosed are catalysts, methods, and systems for the bi-reforming of hydrocarbons. The method includes contacting a catalyst material with a reactant feed that includes hydrogen (H.sub.2), carbon monoxide (CO), carbon dioxide (CO.sub.2), methane (CH.sub.4), and water (H.sub.2O) to produce a product stream that has a H.sub.2/CO molar ratio of 1.4:1 to 2:1. The catalyst can have a metal oxide core, a redox metal oxide layer deposited on a surface of the metal oxide core, and a catalytically active metal deposited on the surface of the redox metal oxide layer. A dopant can be included in the redox metal oxide layer. The catalyst can have a corm-shell type structure.

Methods and systems for producing steel or similar molten-iron-containing materials in melting or smelting furnaces utilizing pre-reduced iron ore, known also as direct reduced iron (DRI) or sponge iron, wherein the emission of CO.sub.2 and other greenhouse gases is significantly low. Such methods and systems are based on producing DRI in a direct reduction furnace with a reducing gas comprising hydrogen; melting at least a portion of the DRI in a melting furnace in order to generate hot gases; producing steam and/or hot water using the heat contained in the hot gases. From the steam and/or hot water hydrogen is produced by electrolysis, at least a portion of which is fed to the direct reduction furnace as a component of the reducing gas to produce the DRI.