C22B1/00

Multi-stage reaction and separation systems of a CO2-based hydrometallurgical process

The present invention is a CO.sub.2 based hydrometallurgical multistage reaction and separation system comprising: a pre-washing device configured to fully mix the feedstock, such as industrial solid waste, mineral and mine tailings with auxiliary reagents and water at specific ratio, a reactor configured to treat the washed slurry with CO.sub.2 bubbling and discharge the treated slurry to the next stage, multistage separators configured to separate solid particles from treated slurry and recycle the unreacted solids back into the pre-washing device, a by-product preparation device configured to generate calcium and magnesium based products from filtrate containing target elements, a water recirculating device configured to recycle the remaining liquor back to the system. The present invention ensures the whole system is able to continuously and consistently react at maximum capacity through continuous slurry feeding and CO.sub.2 bubbling into the reactors which also enables multistage circulating reaction.

METHOD FOR RECOVERING VALUABLE METALS FROM SPENT LITHIUM-ION-BATTERIE

This invention is directed to a method for recovering valuable metals from spent lithium-ion-batteries using CO.sub.2/CO/H.sub.2O gas mixture, or reducing gas comprising CH.sub.4, or solid carbon or combination thereof.

METHOD FOR RECOVERING VALUABLE METALS FROM SPENT LITHIUM-ION-BATTERIE

This invention is directed to a method for recovering valuable metals from spent lithium-ion-batteries using CO.sub.2/CO/H.sub.2O gas mixture, or reducing gas comprising CH.sub.4, or solid carbon or combination thereof.

Methods for recovery of rare earth elements from coal

Methods of recovering rare earth elements, vanadium, cobalt, or lithium from coal are described. The coal is dissolved in a first solvent to dissolve organic material in the coal and create a slurry containing coal ash enriched with rare earth elements, vanadium, cobalt, or lithium. The enriched coal ash is separated from the first solvent. Residual organic material is removed from the coal ash. The rare earth elements, vanadium, cobalt, or lithium can then be recovered from the coal ash. The coal ash is mixed with an acid stream that dissolves the rare earth elements, thereby creating (i) a leachate containing the rare earth elements and (ii) leached ash. The leachate is heated to obtain acid vapor and an acid-soluble rare earth concentrate. The acid-soluble rare earth concentrate can be fed to a hydrometallurgical process to separate and purify the rare earth elements.

METHOD FOR THE EXTRACTION OF LITHIUM FROM AN ELECTRIC BATTERY COMPRISING SOLID METALLIC LITHIUM
20220102774 · 2022-03-31 ·

A method for the extraction of lithium from an assembly of at least one cell of an electric battery including solid metallic lithium, such as a Lithium-Metal-Polymer battery, the method having an extraction phase including the following steps: positioning the assembly in an orientation in which a first edge of the assembly from which extend(s) one or more negative electrode or electrodes is located below a second edge of the assembly, opposite the first edge, and from which extend(s) one or more positive electrode or electrodes; and heating the assembly to a treatment temperature greater than or equal to the melting temperature of the solid metallic lithium. An installation implementing such a method is also provided.

Process, apparatus, and system for recovering materials from batteries
11273453 · 2022-03-15 · ·

An apparatus for carrying out size reduction of battery materials under immersion conditions can include a housing configured to hold an immersion liquid comprising at least one of sodium hydroxide and calcium hydroxide. A first feed chute may define an opening therein for receiving battery materials of a first type into the housing and a first submergible comminuting device may be disposed within the housing and submerged in the immersion liquid to receive the battery materials of the first type from the first feed chute. The first submergible comminuting device may be configured to cause a size reduction of the battery materials of the first type to form a first reduced-size battery material.

Method for recovering scandium from red mud left from alumina production

The present invention relates to rare earth metallurgy, in particular a method for recovering scandium from the red mud byproduct of alumina production. The method includes repulping red mud, sorption leaching scandium therefrom with the use of an ion-exchange sorbing agent to obtain a rich-in-scandium ion exchanger and depleted-in-scandium pulp, desorbing scandium with a solution of sodium hydrocarbonate to obtain a desorbed ion exchanger which is returned to the sorption leaching stage and a solution of industrial reclaim scandium which is transferred to obtain a deposited concentrated scandium, wherein scandium is continuously sorption-leached from red mud pulp in the phosphorous-containing ion exchanger in a countercurrent mode upon direct contact of the pulp with the ion exchanger, scandium is desorbed from the organic phase of the ion exchanger by a solution with a concentration of Na.sub.2CO.sub.3 of 200-450 g/dm.sup.3 to obtain industrial reclaim scandium, from which a scandium concentrate is recovered.

Method for recovering scandium from red mud left from alumina production

The present invention relates to rare earth metallurgy, in particular a method for recovering scandium from the red mud byproduct of alumina production. The method includes repulping red mud, sorption leaching scandium therefrom with the use of an ion-exchange sorbing agent to obtain a rich-in-scandium ion exchanger and depleted-in-scandium pulp, desorbing scandium with a solution of sodium hydrocarbonate to obtain a desorbed ion exchanger which is returned to the sorption leaching stage and a solution of industrial reclaim scandium which is transferred to obtain a deposited concentrated scandium, wherein scandium is continuously sorption-leached from red mud pulp in the phosphorous-containing ion exchanger in a countercurrent mode upon direct contact of the pulp with the ion exchanger, scandium is desorbed from the organic phase of the ion exchanger by a solution with a concentration of Na.sub.2CO.sub.3 of 200-450 g/dm.sup.3 to obtain industrial reclaim scandium, from which a scandium concentrate is recovered.

Method of processing a pyrite-containing slurry

A method of processing a pyrite-containing slurry including removing pyrite from the pyrite-containing slurry and forming (i) an inert stream and (ii) a pyrite-containing material. Using the pyrite-containing material in a downstream leach step in which pyrite in the pyrite-containing material generates acid and heat that facilitates leaching a metal, such as copper or nickel or zinc or cobalt, from a metal-containing material.

METHOD FOR RECYCLING ALUMINUM ALLOYS USING CONTAMINANT CONCENTRATION ESTIMATES FOR QUALITY CONTROL
20220111395 · 2022-04-14 ·

A method of recycling aluminum alloy wheels, the method comprising (a) providing a feed of aluminum alloy wheels; (b) fragmenting the aluminum alloy wheels into a plurality of fragments; (c) cleaning the plurality of fragments to at least partly remove at least one contaminant element therefrom; (d) determining a contaminant concentration estimate for each contaminant element in the plurality of fragments; and (e) operating a data processor to either approve or reject the plurality of fragments, based on an aggregate contaminant concentration calculation. When the plurality of fragments is approved, they may be provided to a downstream recycling process. When the plurality of fragments is rejected, they may not be provided to the downstream recycling process without further cleaning.