C22B3/00

Method of inhibiting degradation of DSX extractant by auxiliary means

A method of inhibiting degradation of an extractant by utilizing several auxiliary means in the DSX process: includes (a) preparing adjustment of the concentration of an extractant of a DSX solvent to a certain range; (b) extracting a metal contained in a pregnant leached solution by adjusting the ratio of the extractant and the diluent in the DSX solvent to a certain range; (c) measuring the pH of the aqueous phase solution by separating mixture into the aqueous phase solution and the organic phase solvent using a settler after step of extracting; (d) controlling the pH by adding soda ash (Na.sub.2CO.sub.3) so as to maintain the pH of the aqueous phase solution to be 3 to 7; and (e) scrubbing with scrubbing solution having a zinc concentration of 2 to 20 g/L by zinc sulfate (ZnSO.sub.4) to remove the manganese from the organic phase solvent containing the extracted metal.

Method of inhibiting degradation of extractant by anhydrous environment avoiding and metal stripping

Provided is a method of inhibiting degradation of an extractant by an anhydrous environment avoiding and metal stripping, the method including the steps of: (a) stopping the addition of soda ash (Na.sub.2CO.sub.3) to an extracting reaction tank; (b) starting solution recirculation and stopping solvent recirculation of a settler; (c) supplying a solvent from a loaded organic tank to a scrubbing reaction tank, in which the scrubbing reaction tank, stripping reaction tank and extracting reaction tank are connected for circulation and operating stirrers of the scrubbing reaction tank, stripping reaction tank and extracting reaction tank; (d) supplying a sulfuric acid solution having a controlled concentration with a diluting solution to the stripping reaction tank; (e) transferring the solvents of the settler, the loaded organic tank and all the pipes to the scrubbing reaction tank; and (f) stopping the step (e) and initiating solvent recirculation.

Process for Gold and/or Platinum Group Metals Heap Leaching with Lime

Process for gold and/or platinum group metals heap leaching comprising irrigating a heap with an irrigation solution containing sodium cyanide for leaching gold and/or platinum group metals from a gold and/or platinum group metals containing ore. A lime reagent is added by feeding a fine particle lime suspension containing lime particles in an aqueous phase in an irrigation solution.

Method for comprehensive recovery of silver-containing lead slag

The main steps are as follows: purification, de-leading, recovery and filtration, dissolving lead, hot filtration, cooling filtration, washing and hot decomposition, silver is recycled as silver powder, lead was recovered in the form of red lead, yellow lead and chlorinated lead respectively. Compared to existing technologies, the invention adopts a wet process, the amount of waste gas and dust produced in the process of fire treatment is reduced; silver powder, red (yellow) lead and chloride lead were obtained, it can be sold as final product with high value-added features. The tail liquid produced by the process returns to the corresponding process respectively, and the tailless liquid is discharged. The pyrolysis flue gas returns to the lead removal process, flue gas treatment process is reduced, lead smoke pollution is avoided. This method has the characteristics of simple technics and pollution-free process.

METHOD FOR RECYCLING BATTERY BY INCOMPLETE EXTRACTION
20230272503 · 2023-08-31 ·

Disclosed is an incomplete extraction method for recycling batteries, which may include: introducing a pretreatment gas into a device loaded with a waste battery powder, and bringing a gas outlet into communication with absorption liquid A and absorption liquid B in order; raising the temperature and introducing the pretreatment gas; reducing the temperature and introducing a reaction gas; raising the temperature, introducing the reaction gas, and then introducing the pretreatment gas; and reducing the temperature, and turning off the pretreatment gas; adding an extractant to absorption liquid A, mixing the mixture, taking organic phase A, adding a stripping agent, and taking aqueous phase A; and adjusting the pH to acidity, then adding an extractant, taking organic phase B, adding a stripping agent to obtain a stock solution enriched in Li, Mn, Ni and Co.

MANGANESE-LITHIUM SEPARATION PROCESS AND PRE-EXTRACTION SOLUTION PREPARATION PROCESS IN COMPREHENSIVE RECOVERY OF TERNARY BATTERY WASTES, AND METHOD FOR COMPREHENSIVE RECOVERY OF COBALT, NICKEL, MANGANESE AND LITHIUM ELEMENTS FROM TERNARY BATTERY WASTES

A manganese-lithium separation process and a pre-extraction solution preparation process in comprehensive recovery of ternary battery wastes, and a method for comprehensive recovery of cobalt, nickel, manganese and lithium elements from the ternary battery wastes, relates to a method for recycling battery wastes. According to the present disclosure, cobalt and nickel ions are separated from an impurity-removed solution by a hydrolysis method; manganese, lithium and other ions in the impurity-removed solution are free from an extraction procedure, so that most manganese ions are separated and removed by a wet method before extraction, to prevent the manganese ions from entering the extraction system; nickel ions are free from an extraction procedure of full extraction and full back-extraction; and nickel hydroxide is directly precipitated after related impurities are removed by extraction.

SYSTEMS AND METHODS FOR GENERATING HYDROGEN AND MAGNETITE FROM ROCK
20230271827 · 2023-08-31 ·

Systems and methods for sequestering carbon, evolving hydrogen gas, producing iron oxide as magnetite, and producing magnesium carbonate as magnesite through sequential carbonation and serpentinization/hydration reactions involving processed olivine- and/or pyroxene-rich ores, as typically found in mafic and ultramafic igneous rock. Precious or scarce metals, such nickel, cobalt, chromium, rare earth elements, and others, may be concentrated in the remaining ore to facilitate their recovery from any gangue material.

PROCESS, APPARATUS, AND SYSTEM FOR RECOVERING MATERIALS FROM BATTERIES
20220152626 · 2022-05-19 ·

A process for recovering materials from a black mass material obtained from lithium-ion batteries can include: i) conveying a black mass material as a black mass solid stream; ii) leaching the black mass solid stream to form a pregnant leach solution and residual solids; iii) separating the pregnant leach solution from the residual solids; iv) isolating a copper product from the pregnant leach solution; v) isolating an aluminum (Al) and/or iron (Fe) product from the pregnant leach solution; vi) isolating a manganese (Mn) product from the from the pregnant leach solution; vii) isolating a cobalt (Co) product from the from the pregnant leach solution; viii) isolating a nickel (Ni) product from the from the pregnant leach solution; ix) isolating a salt by-product from the pregnant leach solution; and x) isolating a lithium product the pregnant leach solution.

METHOD FOR MANUFACTURING NICKEL AND COBALT-CONTAINING SOLUTION FROM HYDROXIDE CONTAINING NICKEL AND COBALT

A method of manufacturing a cobalt-nickel-containing solution including: preparing a crude nickel hydroxide and/or a crude cobalt hydroxide as a starting material, the crude nickel or cobalt hydroxide containing cobalt and nickel and elements except the cobalt and nickel as impurities, the crude nickel hydroxide containing the nickel more than the cobalt, and the crude cobalt hydroxide containing the cobalt more than the nickel; a water-washing process for obtaining a post-water-washing crude hydroxide from the starting material; a leaching process for obtaining a post-leaching solution from the post-water-washing crude hydroxide; a neutralization process of subjecting the post-leaching solution to neutralization and solid-liquid-separation to remove the impurities as a post-neutralization residue containing one or more of iron, silicon, aluminum, and chromium, thereby obtaining a post-neutralization solution; and an extraction process of subjecting the post-neutralization solution to solvent extraction to obtain a post-extraction solution containing cobalt and nickel with the impurities reduced.

EXTRACTION METHOD FOR REMOVING ALUMINUM FROM TERNARY BATTERY MATERIAL LEACHATE
20230265540 · 2023-08-24 ·

Disclosed is a method for removing aluminum in a ternary battery material leachate by adopting an extraction method, which comprises the following steps: (1) saponification: mixing an extraction solvent with a saponifying agent to obtain a saponified extraction solvent; (2) extraction: mixing the ternary battery material leachate with the saponified extraction solvent to obtain a loaded organic phase and a raffinate; (3) back extraction: mixing the loaded organic phase with a back-extraction agent, followed by performing a back-extraction to obtain an organic phase and a back-extraction solution; the extraction solvent comprises an extracting agent and a diluent. The extraction method is adopted to separate nickel, cobalt, manganese and aluminum, having the advantages of less heavy metal entrainment, short process flow, and high metal recovery rate. The extraction rate of the aluminum can reach 97.42 percent.