Despite the abundance of scandium, its commercial applications continue to be limited by the absence of reliable, secure, stable and long-term production. The subject-matter disclosed herein provides for a method for extracting Rare Earth Elements (REE), scandium and/or Rare-Earth Oxides (REO) from ore and mineral concentrates, the method comprising: providing Rare Earth Elements (REE) and/or scandium bearing feedstock; a high-pressure caustic (HPC) leaching step, comprising leaching the feedstock in an alkali solution at a first temperature for a target period of time and at a given pressure to produce a leachate slurry; extracting a solid residue from the leachate slurry; leaching of the solid residue in a mineral acid to form a primary leach solution; extracting scandium and/or REE from the primary leach solution; and/or precipitating REE remaining in the raffinate to form a mixed REE-carbonate to thereby facilitate the extraction of REO.

A system for recovering rare earth elements from coal ash includes a leaching reactor, an ash dryer downstream of the leaching reactor, and a roaster downstream of the ash dryer that is cooperatively connected to both the leaching reactor and the ash dryer. Coal ash is mixed with an acid stream such that rare earth elements present in the coal ash are dissolved in the acid stream, thereby creating (i) a leachate containing the rare earth elements and (ii) leached ash. The leachate is heated to obtain acid vapor and an acid-soluble rare earth concentrate. Mixing of the coal ash with the acid stream can occur in a leaching reactor and heating of the leachate can occur in a roaster. The acid-soluble rare earth concentrate can be fed to a hydrometallurgical process to separate and purify the rare earth elements.

A system for recovering rare earth elements from coal ash includes a leaching reactor, an ash dryer downstream of the leaching reactor, and a roaster downstream of the ash dryer that is cooperatively connected to both the leaching reactor and the ash dryer. Coal ash is mixed with an acid stream such that rare earth elements present in the coal ash are dissolved in the acid stream, thereby creating (i) a leachate containing the rare earth elements and (ii) leached ash. The leachate is heated to obtain acid vapor and an acid-soluble rare earth concentrate. Mixing of the coal ash with the acid stream can occur in a leaching reactor and heating of the leachate can occur in a roaster. The acid-soluble rare earth concentrate can be fed to a hydrometallurgical process to separate and purify the rare earth elements.

A process for recovering a rare earth element. The process includes adding water and a nonaqueous acid to an ionic liquid, and dissolving an oxide of a first rare earth element directly into the ionic liquid to form an ionic solution comprising at least about 0.1 weight percent water, the acid and an ion of the first rare earth element. The process further includes applying a potential to the ionic solution to deposit the first rare earth element onto an electrode as a metal.

A process for recovering a rare earth element. The process includes adding water and a nonaqueous acid to an ionic liquid, and dissolving an oxide of a first rare earth element directly into the ionic liquid to form an ionic solution comprising at least about 0.1 weight percent water, the acid and an ion of the first rare earth element. The process further includes applying a potential to the ionic solution to deposit the first rare earth element onto an electrode as a metal.

A method for extracting a rare earth element from a rare earth-containing substance, the method comprising mixing the rare earth-containing substance with a protic ionic liquid, such as:

##STR00001##

wherein R.sup.1 is selected from hydrogen atom and hydrocarbon groups containing 1 to 6 carbon atoms; R.sup.2 and R.sup.3 are independently selected from hydrocarbon groups containing 1 to 12 carbon atoms; and X.sup.− is an anionic species; to produce a composition of the formula (RE)(amide).sub.yX.sub.z at least partially dissolved in the protic ionic liquid, wherein RE is at least one rare earth element having an atomic number selected from 39, 57-71, and 90-103; y is 2-6; z is a number that charge balances the total positive charge of RE; and the amide is the conjugate base of the cationic portion of the protic ionic liquid of Formula (1) and has the following formula:

##STR00002##

A method for extracting a rare earth element from a rare earth-containing substance, the method comprising mixing the rare earth-containing substance with a protic ionic liquid, such as:

##STR00001##

wherein R.sup.1 is selected from hydrogen atom and hydrocarbon groups containing 1 to 6 carbon atoms; R.sup.2 and R.sup.3 are independently selected from hydrocarbon groups containing 1 to 12 carbon atoms; and X.sup.− is an anionic species; to produce a composition of the formula (RE)(amide).sub.yX.sub.z at least partially dissolved in the protic ionic liquid, wherein RE is at least one rare earth element having an atomic number selected from 39, 57-71, and 90-103; y is 2-6; z is a number that charge balances the total positive charge of RE; and the amide is the conjugate base of the cationic portion of the protic ionic liquid of Formula (1) and has the following formula:

##STR00002##

An object of the present invention is to provide a novel method for extracting ultra high purity alumina from wastewater. Wastewater is recycled, filtered, concentrated and pretreated in order to mix with alkali solution and extraction agent PX-17, undergoing 2 times of purification, adding control agent SX-1 and high temperature heat treatment to finally obtain ultra high purity nano-alumina particles which purity reaches as 99.999% and particle size reaches as 20-200 nm.

A system and method for reclaiming select components containing rare earth metals of electronic media electronic storage devices such as hard disk drives, solid state drives and hybrid hard drives and destroying the data containing components thereof comprising first devices to loosen various components of the storage device, the components including the components containing the rare earth elements and the data containing portions. Second devices are provided for removing components from the storage device. A holding chassis receives the storage device, and moves the storage device for engagement with the first and second devices. A section is provided for destroying the data containing portion of the electric storage device when it is removed from the storage device.

An object of the present invention is to provide a method for separating Dy and Tb from an alloy containing Dy and Tb as constitutional metals without using a solvent extraction method. The method of the present invention as a means for resolution is characterized by comprising vaporizing Dy by subjecting the alloy to a heat treatment in an atmosphere of a pressure Pt(Pa) that, when a Dy—Tb composition in the alloy is Dy.sub.xTb.sub.y (atomic composition ratio) and a heat treatment temperature is t, satisfies formula 1: Pt.sub.Tb<Pt<Pt.sub.Dy×(x/(x+y)), wherein Pt.sub.Dy is a vapor pressure (Pa) of Dy alone at the temperature t and Pt.sub.Tb is a vapor pressure (Pa) of Tb alone at the temperature t.