The present invention relates to a protective layer against CMAS, to a CMAS-resistant article comprising the protective layer according to the invention, and to a process for preparing a corresponding article.

Disclosed are a BCC dual phase refractory superalloy with high phase stability and a manufacturing method therefor, the alloy comprising one or more of Ti, Zr, and Hf as Group 4 transition metals, one or more of Na and Ta as Group 5 transition metals, and Al, and having a structure of a BCC phase, wherein the BCC phase is composed of a disordered BCC phase and an ordered BCC phase, and wherein the ordered BCC phase is formed by allowing Al, which is a BCC phase forming element, to be soluted in an area of the BCC phase where the contents of the Group 5 transition metals are more than those of the Group 4 transition metals, so that the present disclosure provides a BCC dual phase refractory superalloy with high phase stability, characterized in that when a BCC dual phase with the ordered BCC phase and the disordered BCC phase separated from each other is formed by aging, the aging condition is precisely controlled through the apex temperature (T.sub.c) of the BCC phase miscibility gap, expressed by (Equation 1) below.
T.sub.c(K)=881.4+331.7*x+546.7*y+893.0*x*z (provided that, 0≤x≤1, 0≤y≤0.2, 0≤x+y≤1, and 0≤z≤1)  (Equation 1)

Disclosed are a BCC dual phase refractory superalloy with high phase stability and a manufacturing method therefor, the alloy comprising one or more of Ti, Zr, and Hf as Group 4 transition metals, one or more of Na and Ta as Group 5 transition metals, and Al, and having a structure of a BCC phase, wherein the BCC phase is composed of a disordered BCC phase and an ordered BCC phase, and wherein the ordered BCC phase is formed by allowing Al, which is a BCC phase forming element, to be soluted in an area of the BCC phase where the contents of the Group 5 transition metals are more than those of the Group 4 transition metals, so that the present disclosure provides a BCC dual phase refractory superalloy with high phase stability, characterized in that when a BCC dual phase with the ordered BCC phase and the disordered BCC phase separated from each other is formed by aging, the aging condition is precisely controlled through the apex temperature (T.sub.c) of the BCC phase miscibility gap, expressed by (Equation 1) below.
T.sub.c(K)=881.4+331.7*x+546.7*y+893.0*x*z (provided that, 0≤x≤1, 0≤y≤0.2, 0≤x+y≤1, and 0≤z≤1)  (Equation 1)

A medical device that is at least partially formed of a refractory metal alloy, and a method for inserting the medical device in a patient.

A medical device that is at least partially formed of a refractory metal alloy, and a method for inserting the medical device in a patient.

A mechanical watch or measurement instrument having metallic parts, wherein each part of the mechanical watch mechanism has a relative magnetic permeability of less than 1.01.

A mechanical watch or measurement instrument having metallic parts, wherein each part of the mechanical watch mechanism has a relative magnetic permeability of less than 1.01.

Disclosed are a BCC dual phase refractory superalloy with high phase stability and a manufacturing method therefor, the alloy comprising one or more of Ti, Zr, and Hf as Group 4 transition metals, one or more of Na and Ta as Group 5 transition metals, and Al, and having a structure of a BCC phase, wherein the BCC phase is composed of a disordered BCC phase and an ordered BCC phase, and wherein the ordered BCC phase is formed by allowing Al, which is a BCC phase forming element, to be soluted in an area of the BCC phase where the contents of the Group 5 transition metals are more than those of the Group 4 transition metals, so that the present disclosure provides a BCC dual phase refractory superalloy with high phase stability, characterized in that when a BCC dual phase with the ordered BCC phase and the disordered BCC phase separated from each other is formed by aging, the aging condition is precisely controlled through the apex temperature (T.sub.c) of the BCC phase miscibility gap, expressed by (Equation 1) below.

T.sub.c(K)=881.4+331.7*x+546.7*y+893.0*x*z  (Equation 1)

(provided that, 0≤x≤1, 0≤y≤0.2, 0≤x+y≤1, and 0≤z≤1)

Disclosed are a BCC dual phase refractory superalloy with high phase stability and a manufacturing method therefor, the alloy comprising one or more of Ti, Zr, and Hf as Group 4 transition metals, one or more of Na and Ta as Group 5 transition metals, and Al, and having a structure of a BCC phase, wherein the BCC phase is composed of a disordered BCC phase and an ordered BCC phase, and wherein the ordered BCC phase is formed by allowing Al, which is a BCC phase forming element, to be soluted in an area of the BCC phase where the contents of the Group 5 transition metals are more than those of the Group 4 transition metals, so that the present disclosure provides a BCC dual phase refractory superalloy with high phase stability, characterized in that when a BCC dual phase with the ordered BCC phase and the disordered BCC phase separated from each other is formed by aging, the aging condition is precisely controlled through the apex temperature (T.sub.c) of the BCC phase miscibility gap, expressed by (Equation 1) below.

T.sub.c(K)=881.4+331.7*x+546.7*y+893.0*x*z  (Equation 1)

(provided that, 0≤x≤1, 0≤y≤0.2, 0≤x+y≤1, and 0≤z≤1)

The present invention provides an alloy, an alloy powder, an alloy member, and a composite member which are excellent in corrosion resistance and wear resistance, have crack resistance, and are suitable for an additive manufacturing method and the like. An alloy and an alloy powder include, by mass %, Cr: 18 to 22%, Mo: 18 to 28%, Ta: 1.5 to 57%, C: 1.0 to 2.5%, Nb: 0 to 42%, Ti: 0 to 15%, V: 0 to 27%, Zr: 0 to 29%, and a remainder consisting of Ni and unavoidable impurities, where a molar ratio of (Ta+0.7Nb+Ti+0.6V+Zr)/C=0.5 to 1.5 is satisfied. An alloy member is an additively manufactured product or a cast having such a solidification structure, and the solidification structure is a dendrite-like crystal structure having a metal phase having a face-centered cubic structure and carbides.