An Fe—Co—Al alloy magnetic thin film contains, in terms of atomic ratio, 20% to 30% Co and 1.5% to 2.5% Al. The Fe—Co—Al alloy magnetic thin film has a crystallographic orientation such that the (100) plane is parallel to a substrate surface and the <100> direction is perpendicular to the substrate surface. The Fe—Co—Al alloy magnetic thin film has good magnetic properties, that is, a magnetization of 1440 emu/cc or more, a coercive force of less than 100 Oe, a damping factor of less than 0.01, and an FMR linewidth ΔH at 30 GHz of less than 70 Oe.

An Fe—Co—Al alloy magnetic thin film contains, in terms of atomic ratio, 20% to 30% Co and 1.5% to 2.5% Al. The Fe—Co—Al alloy magnetic thin film has a crystallographic orientation such that the (100) plane is parallel to a substrate surface and the <100> direction is perpendicular to the substrate surface. The Fe—Co—Al alloy magnetic thin film has good magnetic properties, that is, a magnetization of 1440 emu/cc or more, a coercive force of less than 100 Oe, a damping factor of less than 0.01, and an FMR linewidth ΔH at 30 GHz of less than 70 Oe.

A coating-substrate combination includes: a Ni-based superalloy substrate comprising, by weight percent: 2.0-5.1 Cr; 0.9-3.3 Mo; 3.9-9.8 W; 2.2-6.8 Ta; 5.4-6.5 Al; 1.8-12.8 Co; 2.8-5.8 Re; 2.8-7.2 Ru; and a coating comprising, exclusive of Pt group elements, by weight percent: Ni as a largest content; 5.8-9.3 Al; 4.4-25 Cr; 3.0-13.5 Co; up to 6.0 Ta, if any; up to 6.2 W, if any; up to 2.4 Mo, if any; 0.3-0.6 Hf; 0.1-0.4 Si; up to 0.6 Y, if any; up to 0.4 Zr, if any; up to 1.0 Re, if any.

A coating-substrate combination includes: a Ni-based superalloy substrate comprising, by weight percent: 2.0-5.1 Cr; 0.9-3.3 Mo; 3.9-9.8 W; 2.2-6.8 Ta; 5.4-6.5 Al; 1.8-12.8 Co; 2.8-5.8 Re; 2.8-7.2 Ru; and a coating comprising, exclusive of Pt group elements, by weight percent: Ni as a largest content; 5.8-9.3 Al; 4.4-25 Cr; 3.0-13.5 Co; up to 6.0 Ta, if any; up to 6.2 W, if any; up to 2.4 Mo, if any; 0.3-0.6 Hf; 0.1-0.4 Si; up to 0.6 Y, if any; up to 0.4 Zr, if any; up to 1.0 Re, if any.

Complex concentrated alloys include five or more elements, at least one of which is ruthenium. Example complex concentrated alloys can include nickel and chromium, iron, ruthenium, molybdenum, and/or tungsten. Example complex concentrated alloys have single phase microstructure of face centered cubic (FCC) and can be homogenous. Example complex concentrated alloys can exhibit improved corrosion resistance.

Complex concentrated alloys include five or more elements, at least one of which is ruthenium. Example complex concentrated alloys can include nickel and chromium, iron, ruthenium, molybdenum, and/or tungsten. Example complex concentrated alloys have single phase microstructure of face centered cubic (FCC) and can be homogenous. Example complex concentrated alloys can exhibit improved corrosion resistance.

An austenitic alloy based on nickel and having a high chromium content, intended to be used at a given operating temperature between 900° C. and 1150° C., comprises the following elements by mass percentage: chromium between 40% and 45%; iron between 10% and 14%; carbon between 0.4% and 0.6%; titanium between 0.05% and 0.2%; niobium between 0.5% and 1.5%; at least one reactive element, selected from rare earths or hafnium, between 0.002% and 0.1%; silicon between 0% and 1%; manganese between 0% and 0.5%; nickel to balance the alloy elements. In addition, the alloy has a molar fraction of more than 0.1% of secondary carbo-nitrides rich in niobium and/or titanium, after the operating temperature has been applied thereto. The disclosure also relates to a method for designing such an alloy and to a method for validating such an alloy.

An austenitic alloy based on nickel and having a high chromium content, intended to be used at a given operating temperature between 900° C. and 1150° C., comprises the following elements by mass percentage: chromium between 40% and 45%; iron between 10% and 14%; carbon between 0.4% and 0.6%; titanium between 0.05% and 0.2%; niobium between 0.5% and 1.5%; at least one reactive element, selected from rare earths or hafnium, between 0.002% and 0.1%; silicon between 0% and 1%; manganese between 0% and 0.5%; nickel to balance the alloy elements. In addition, the alloy has a molar fraction of more than 0.1% of secondary carbo-nitrides rich in niobium and/or titanium, after the operating temperature has been applied thereto. The disclosure also relates to a method for designing such an alloy and to a method for validating such an alloy.

A method of manufacturing a steel sheet plated with an Al—Fe alloy for hot forming. The method includes: aluminum-plating and coiling a base steel sheet to obtain an aluminum-plated steel sheet, where an amount of the aluminum-plating is 30 to 200 g/m.sup.2 based on one surface of the base steel sheet, and tension in the coiling is 0.5 to 5 kg/mm.sup.2; after the aluminum-plating, performing cooling to 250° C. at a rate of 20° C./sec or less; annealing the aluminum-plated steel sheet to obtain the steel sheet plated with the Al—Fe alloy; and cooling the steel sheet plated with the Al—Fe alloy. The annealing is carried out for 30 minutes to 50 hours within a heating temperature range of 550 to 750° C. in a batch annealing furnace.

The present invention relates to a 3D-printed cobalt-based alloy product comprising carbon, tungsten and chromium with very good mechanical and thermal properties as well as a method of preparing the 3D-printed product and a powder alloy. The alloy has a high carbon content leading to high carbide content but small and evenly distributed carbides. A method facilitating 3D printing of high carbide content alloys such as the present alloy is also disclosed.