A surface treatment agent capable of forming a hexavalent chromium-free chemical conversion coating that can provide an excellent corrosion-resistant coating on various metallic materials; a metallic material having a surface treatment coating obtained therefrom; and a method of producing the same. A free fluorine ion-containing surface treatment agent for surface-treating a metallic material, which is obtained by mixing at least one supply source (A) of trivalent chromium-containing ions A; a supply source (B) of ions B that are at least one selected from titanium-containing ions and zirconium-containing ions; a water-soluble or water-dispersible compound (C) containing an alkoxysilyl group, an aromatic ring, a hydroxy group directly bonded to the aromatic ring, and at least one of primary, secondary, tertiary and quaternary amino groups, wherein the alkoxysilyl group is bonded to the nitrogen atom of the amino group directly or via an alkylene group; and a fluorine-containing compound (D) providing fluorine-containing ions.

This austenitic stainless steel contains, in terms of % by mass: C: 0.100% or less, Si: 3.00% or less, Mn: 0.01% or more and 5.00% or less, P: 0.100% or less, S: 0.0050% or less, Ni: 7.00% or more and 38.00% or less, Cr: 17.00% or more and 28.00% or less, Mo: 10.00% or less, and N: more than 0.100% and 0.400% or less, with a remainder being Fe and impurities, and a brightness difference ΔL of a surface of a stainless steel is 5 or less.

The present invention relates to a flat steel product which has good deep-drawing ability, low edge-crack sensitivity and good bending behaviour. To this end, the flat steel product contains a steel which consists of (in wt %) 0.1-0.5% C, 1.0-3.0% Mn, 0.9-1.5% Si, up to 1.5% Al, up to 0.008% N, up to 0.020% P, up to 0.005% S, 0.01-1% Cr and optionally one or more of the following elements: up to 0.2% Mo, up to 0.01% B, up to 0.5% Cu, up to 0.5% Ni and optionally a total of 0.005-0.2% microalloying elements, the remainder being iron and unavoidable impurities, wherein 75<(Mn2+55*Cr)/Cr<3000 where Mn is the Mn content of the steel in wt % and Cr is the Cr content of the steel in wt %. The steel has a structure which consists of at least 80 area % martensite, of which at least 75 area % is tempered martensite and at most 25 area % is non-tempered martensite, at least 5 volume % residual austenite, 0.5 to 10 area % ferrite and at most 5 area % bainite, wherein in the region of the phase boundary between tempered martensite and residual austenite there is a low-Mn ferrite seam which has a width of at least 4 nm and at most 12 nm and the Mn content of which is at most 50% of the average Mn content of the flat steel product. The flat steel product contains carbides with a length of less than or equal to 250 nm. The invention also relates to a method for producing a flat steel product according to the invention, in which method the structural characteristics of the flat steel product according to the invention are set by suitable heat treatment.

The present invention relates to a flat steel product which has good deep-drawing ability, low edge-crack sensitivity and good bending behaviour. To this end, the flat steel product contains a steel which consists of (in wt %) 0.1-0.5% C, 1.0-3.0% Mn, 0.9-1.5% Si, up to 1.5% Al, up to 0.008% N, up to 0.020% P, up to 0.005% S, 0.01-1% Cr and optionally one or more of the following elements: up to 0.2% Mo, up to 0.01% B, up to 0.5% Cu, up to 0.5% Ni and optionally a total of 0.005-0.2% microalloying elements, the remainder being iron and unavoidable impurities, wherein 75<(Mn2+55*Cr)/Cr<3000 where Mn is the Mn content of the steel in wt % and Cr is the Cr content of the steel in wt %. The steel has a structure which consists of at least 80 area % martensite, of which at least 75 area % is tempered martensite and at most 25 area % is non-tempered martensite, at least 5 volume % residual austenite, 0.5 to 10 area % ferrite and at most 5 area % bainite, wherein in the region of the phase boundary between tempered martensite and residual austenite there is a low-Mn ferrite seam which has a width of at least 4 nm and at most 12 nm and the Mn content of which is at most 50% of the average Mn content of the flat steel product. The flat steel product contains carbides with a length of less than or equal to 250 nm. The invention also relates to a method for producing a flat steel product according to the invention, in which method the structural characteristics of the flat steel product according to the invention are set by suitable heat treatment.

A magnesium alloy/resin composite structure (106) including a magnesium alloy member (103) and a resin member (105) integrated to the magnesium alloy member (103) and made of a thermoplastic resin composition, in which the magnesium alloy member (103) surface to which the resin member (105) is not integrated is coated with a layer including a manganese atom, an oxygen atom, and a sulfur atom.

A method for manufacturing a grain-oriented electrical steel sheet according to an aspect of the present invention includes a step of obtaining a hot-rolled steel sheet by carrying out hot rolling on a slab containing a predetermined component composition with a remainder including Fe and impurities, a step of obtaining a hot-rolled annealed sheet by carrying out hot-rolled sheet annealing as necessary, a step of carrying out pickling to obtain a pickled sheet, a step of carrying out cold rolling to obtain a cold-rolled steel sheet, a step of carrying out primary recrystallization annealing, a step of applying an annealing separating agent including MgO to a surface and then carrying out final annealing to obtain a final-annealed sheet, and a step of applying an insulating coating and then carrying out flattening annealing.

A method for manufacturing a grain-oriented electrical steel sheet according to an aspect of the present invention includes a step of obtaining a hot-rolled steel sheet by carrying out hot rolling on a slab containing a predetermined component composition with a remainder including Fe and impurities, a step of obtaining a hot-rolled annealed sheet by carrying out hot-rolled sheet annealing as necessary, a step of carrying out pickling to obtain a pickled sheet, a step of carrying out cold rolling to obtain a cold-rolled steel sheet, a step of carrying out primary recrystallization annealing, a step of applying an annealing separating agent including MgO to a surface and then carrying out final annealing to obtain a final-annealed sheet, and a step of applying an insulating coating and then carrying out flattening annealing.

A medical product and a method of surface treatment and/or manufacture of the medical product. The method includes the step of electrochemically etching the medical product. The medical product can include a metal or alloy and have one or more of the following features: a pitting corrosion potential of 100 mV to 1200 mV, a contact angle of 90° to 140°, and a passive layer having a thickness of 1 nm to 10 nm that coats at least sections of the surface of the medical product.

A ferritic stainless steel sheet is provided that has a chemical composition consisting of, in mass %, C: 0.001 to 0.020%, Si: 0.02 to 1.50%, Mn: 0.02 to 1.50%, P: 0.01 to 0.05%, S: 0.0001 to 0.01%, Cr: 10.0 to 25.0%, Ti: 0.01 to 0.30%, N: 0.001 to 0.030%, and optional elements, with the balance being Fe and unavoidable impurities, wherein: a grain size number is 6 or more; the ferritic stainless steel sheet satisfies the formulas [A+B≥12.0/t], [X+Y≥12.0/(t−0.3)] and [(X+Y)−(A+B)≤5.0] with respect to crystal orientation intensities of a ferrite phase obtained by X-ray diffraction; and the sheet thickness is 1.0 mm or more.

A ferritic stainless steel sheet is provided that has a chemical composition consisting of, in mass %, C: 0.001 to 0.020%, Si: 0.02 to 1.50%, Mn: 0.02 to 1.50%, P: 0.01 to 0.05%, S: 0.0001 to 0.01%, Cr: 10.0 to 25.0%, Ti: 0.01 to 0.30%, N: 0.001 to 0.030%, and optional elements, with the balance being Fe and unavoidable impurities, wherein: a grain size number is 6 or more; the ferritic stainless steel sheet satisfies the formulas [A+B≥12.0/t], [X+Y≥12.0/(t−0.3)] and [(X+Y)−(A+B)≤5.0] with respect to crystal orientation intensities of a ferrite phase obtained by X-ray diffraction; and the sheet thickness is 1.0 mm or more.