Patent classifications
C25B3/00
Method, device and system for spatially controlling the formation of a hydrogel electrochemically
The invention relates to a method, a device and a system for producing particularly a hydrogel (200) and for controlling an enzymatically catalyzed formation of a covalent bond in a solution, wherein said covalent bond is formed between a first compound (20) comprising a first moiety (21) and a second compound (22) comprising a second moiety (23), wherein the first and the second moiety (21, 23) are a substrate of an enzyme wherein said enzyme catalyzes the formation of a covalent bond between the first and the second moiety (21, 23), and wherein a voltage is applied to the solution for spatially controlling said formation, wherein said voltage is adjusted such that it induces electrolysis of said solution.
Method for producing conductive polymer and method for producing solid electrolyte capacitor
A solid electrolytic capacitor is obtained by a method which includes dissolving a polymerizable material for being converted into a conductive polymer in a water-soluble organic solvent to obtain a solution, adding the solution to water while homogenizing the solution to obtain a sol, immersing an anode body having a dielectric layer in the surface of the anode body in the sol, and applying voltage using the anode body as a positive electrode and a counter electrode as a negative electrode placed in the sol to electropolymerize the polymerizable material. An electropolymerizable liquid for producing a conductive polymer, the liquid composed of a sol comprising water, a water-soluble organic solvent, and a polymerizable material for being converted into the conductive polymer.
Method for producing conductive polymer and method for producing solid electrolyte capacitor
A solid electrolytic capacitor is obtained by a method which includes dissolving a polymerizable material for being converted into a conductive polymer in a water-soluble organic solvent to obtain a solution, adding the solution to water while homogenizing the solution to obtain a sol, immersing an anode body having a dielectric layer in the surface of the anode body in the sol, and applying voltage using the anode body as a positive electrode and a counter electrode as a negative electrode placed in the sol to electropolymerize the polymerizable material. An electropolymerizable liquid for producing a conductive polymer, the liquid composed of a sol comprising water, a water-soluble organic solvent, and a polymerizable material for being converted into the conductive polymer.
MOLTEN CARBOXYLATE ELECTROLYTES FOR ELECTROCHEMICAL DECARBOXYLATION PROCESSES
Molten salt electrolytes are described for use in electrochemical synthesis of hydrocarbons from carboxylic acids. The molten salt electrolyte can be used to synthesize a wide variety of hydrocarbons with and without functional groups that have a broad range of applications. The molten salt can be used to synthesize saturated hydrocarbons, diols, alkylated aromatic compounds, as well as other types of hydrocarbons. The molten salt electrolyte increases the selectivity, yield, the energy efficiency and Coulombic efficiency of the electrochemical conversion of carboxylic acids to hydrocarbons while reducing the cell potential required to perform the oxidation.
MOLTEN CARBOXYLATE ELECTROLYTES FOR ELECTROCHEMICAL DECARBOXYLATION PROCESSES
Molten salt electrolytes are described for use in electrochemical synthesis of hydrocarbons from carboxylic acids. The molten salt electrolyte can be used to synthesize a wide variety of hydrocarbons with and without functional groups that have a broad range of applications. The molten salt can be used to synthesize saturated hydrocarbons, diols, alkylated aromatic compounds, as well as other types of hydrocarbons. The molten salt electrolyte increases the selectivity, yield, the energy efficiency and Coulombic efficiency of the electrochemical conversion of carboxylic acids to hydrocarbons while reducing the cell potential required to perform the oxidation.
Electro-synthetic or electro-energy cell with gas diffusion electrode(s)
There is provided a new type of electro-synthetic (electrochemical) or electro-energy cell, such as a fuel cell. The cell includes a liquid electrolyte and at least one gas diffusion electrode (GDE). The GDE operates as a gas depolarized electrode and includes a gas permeable material that is substantially impermeable to the liquid electrolyte, as well as a porous conductive material provided on a liquid electrolyte facing side of the gas diffusion electrode. The porous conductive material can be attached to the gas permeable material by being laminated. Alternatively, the porous conductive material is deposited or coated on at least part of the gas permeable material. A depolarizing gas can be received by the at least one gas diffusion electrode to gas depolarize the electrode. The depolarizing gas changes a half-reaction that would occur at the gas diffusion electrode to a half-reaction that is energetically more favorable.
Electro-synthetic or electro-energy cell with gas diffusion electrode(s)
There is provided a new type of electro-synthetic (electrochemical) or electro-energy cell, such as a fuel cell. The cell includes a liquid electrolyte and at least one gas diffusion electrode (GDE). The GDE operates as a gas depolarized electrode and includes a gas permeable material that is substantially impermeable to the liquid electrolyte, as well as a porous conductive material provided on a liquid electrolyte facing side of the gas diffusion electrode. The porous conductive material can be attached to the gas permeable material by being laminated. Alternatively, the porous conductive material is deposited or coated on at least part of the gas permeable material. A depolarizing gas can be received by the at least one gas diffusion electrode to gas depolarize the electrode. The depolarizing gas changes a half-reaction that would occur at the gas diffusion electrode to a half-reaction that is energetically more favorable.
ELECTRODES/ELECTROLYTE ASSEMBLY, REACTOR AND METHOD FOR DIRECT AMINATION OF HYDROCARBONS
An electrodes/electrolyte assembly and a method for the direct amination of hydrocarbons, and a method for the preparation of said electrodes/electrolyte assembly is disclosed. The presented Solution allows the increase of conversion of said amination to above 60%, even at low temperatures. The electrodes/electrolyte assembly for direct amination of hydrocarbons has: an anode, electrons and protons conductor, that includes a composite porous matrix, containing a ceramic fraction and a catalyst for the amination at temperatures lower than 450 C.; a porous cathode, electrons and protons conductor, and electrocatalyst; an electrolyte, protons or ions conductor and electrically insulating, located between the anode and the cathode, made of a composite ceramic impermeable to reagents and products of the amination.
ELECTRODES/ELECTROLYTE ASSEMBLY, REACTOR AND METHOD FOR DIRECT AMINATION OF HYDROCARBONS
An electrodes/electrolyte assembly and a method for the direct amination of hydrocarbons, and a method for the preparation of said electrodes/electrolyte assembly is disclosed. The presented Solution allows the increase of conversion of said amination to above 60%, even at low temperatures. The electrodes/electrolyte assembly for direct amination of hydrocarbons has: an anode, electrons and protons conductor, that includes a composite porous matrix, containing a ceramic fraction and a catalyst for the amination at temperatures lower than 450 C.; a porous cathode, electrons and protons conductor, and electrocatalyst; an electrolyte, protons or ions conductor and electrically insulating, located between the anode and the cathode, made of a composite ceramic impermeable to reagents and products of the amination.
Solar hydrogen production from ambient water vapor electrolysis
Hydrogen gas as a power source is obtained from gaseous water, including seawater vapor existing abundantly at near-surface levels of the oceans or humid air over land. An integrated system of photovoltaic cells for capturing and harnessing solar energy is combined with a water vapor electrolysis system comprising an electrolyzer with an anode compartment and a cathode compartment separated by a proton exchange membrane. The photovoltaic aspects of the system convert the energy of the sun to drive electrolysis of gaseous water from the environment. The electrolyzer aspects include an anode, a cathode, and a proton exchange membrane. At the anode, oxygen evolution reaction (OER) catalysts oxidize H.sub.2O to oxygen gas and protons, the latter being diffused through a membrane (e.g., a solid polymer electrolyte membrane such as Nafion). At the cathode, photogenerated electrons are conducted to hydrogen evolution reaction (HER) catalysts to reduce the protons to hydrogen gas, while concentration gradients drive the generated O.sub.2 back to the atmosphere.