An electrochemical device of an embodiment includes: an electrochemical cell including a first electrode having a first flow path, a second electrode having a second flow path, and a separating membrane sandwiched between the first electrode and the second electrode; a gas-liquid separation tank which is connected to the first flow path of the first electrode and to which a product produced at the first electrode and water permeating from the second electrode to the first electrode are sent at an operation time; and a water sealing pipe which is connected to a liquid portion of the gas-liquid separation tank, and to send water in the gas-liquid separation tank to the first flow path of the first electrode at a stop time.

A thermo-electrochemical reactive capture apparatus includes an anode and a cathode, wherein the anode includes a first catalyst, wherein the cathode includes a second catalyst, a porous ceramic support positioned between the anode and the cathode, an electrolyte mixture in pores of the ceramic support, and a steam flow system on an outer side of the cathode. The outer side of the cathode is opposite an inner side of the cathode and the inner side of the cathode is adjacent to the ceramic support. In addition, the electrolyte mixture is configured to be molten at a temperature below about 600? C.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

In this disclosure, a process of recycling acid, base and the salt reagents required in the Li recovery process is introduced. A membrane electrolysis cell which incorporates an oxygen depolarized cathode is implemented to generate the required chemicals onsite. The system can utilize a portion of the salar brine or other lithium-containing brine or solid waste to generate hydrochloric or sulfuric acid, sodium hydroxide and carbonate salts. Simultaneous generation of acid and base allows for taking advantage of both chemicals during the conventional Li recovery from brines and mineral rocks. The desalinated water can also be used for the washing steps on the recovery process or returned into the evaporation ponds. The method also can be used for the direct conversion of lithium salts to the high value LiOH product. The method does not produce any solid effluent which makes it easy-to-adopt for use in existing industrial Li recovery plants.

Various CO.sub.x electrolyzer multi-cell architectures are provided, including various frame, flow field, gas diffusion layer, and repeat unit designs that may be particularly useful in the context of multi-cell CO.sub.x electrolyzer cells.

Various CO.sub.x electrolyzer multi-cell architectures are provided, including various frame, flow field, gas diffusion layer, and repeat unit designs that may be particularly useful in the context of multi-cell CO.sub.x electrolyzer cells.

The present invention is directed to an apparatus for producing hydrogen peroxide, comprising one or more electrochemical cells, the apparatus further comprising at least one electrically conductive porous gas transport layer disposed next to a cathode gas diffusion layer, the gas transport layer being configured to deliver a flow of oxygen-containing gas towards the cathode gas diffusion layer and being configured to collect current, further including water which is configured to flow through the porous gas transport layer.

The present invention is directed to an apparatus for producing hydrogen peroxide, comprising one or more electrochemical cells, the apparatus further comprising at least one electrically conductive porous gas transport layer disposed next to a cathode gas diffusion layer, the gas transport layer being configured to deliver a flow of oxygen-containing gas towards the cathode gas diffusion layer and being configured to collect current, further including water which is configured to flow through the porous gas transport layer.