A method for electroless coating of substrates by applying an activating coat of polyelectrolyte or salt with a first aqueous composition; rinsing the activating coat such that the activating coat not being entirely removed; contacting and coating of the activated surfaces that have remained after rinsing with an aqueous composition in the form of a solution, emulsion or suspension, to form an organic secondary coat; and drying. The activating coat is a solution, emulsion or suspension containing a anionic polyelectrolyte or at least one anionic salt in solution in water. The aqueous composition forming the secondary coat has constituents which can be precipitated, deposited or salted out and which are anionically, zwitterionically, sterically or cationically stabilized. The dry film formed in the process, comprising the activating coat and the secondary coat, has a thickness of at least 1 m.

A method for electroless coating of substrates by applying an activating coat of polyelectrolyte or salt with a first aqueous composition; rinsing the activating coat such that the activating coat not being entirely removed; contacting and coating of the activated surfaces that have remained after rinsing with an aqueous composition in the form of a solution, emulsion or suspension, to form an organic secondary coat; and drying. The activating coat is a solution, emulsion or suspension containing a anionic polyelectrolyte or at least one anionic salt in solution in water. The aqueous composition forming the secondary coat has constituents which can be precipitated, deposited or salted out and which are anionically, zwitterionically, sterically or cationically stabilized. The dry film formed in the process, comprising the activating coat and the secondary coat, has a thickness of at least 1 m.

Provided is a method for forming a multi-layer coating film which makes it possible to form a multi-layer coating film which exhibits excellent smoothness and luster. The present invention forms, on a cured electrodeposited coating film formed on a stell plate, a first colored coating film comprising a first coloring coating material (P1), a second coating film comprising a second aqueous coating material (P2) having specific viscometric properties, a third colored coating film comprising a third aqueous color coating material (P3) which has a specific coating material solid content concentration (NVP3) and contains a lustrous pigment (BP3), and a clearcoat film comprising a clearcoat material (P4). The present invention simultaneously cures the formed multi-layer coating film by heating.

Provided is a method for forming a multi-layer coating film which makes it possible to form a multi-layer coating film which exhibits excellent smoothness and luster. The present invention forms, on a cured electrodeposited coating film formed on a stell plate, a first colored coating film comprising a first coloring coating material (P1), a second coating film comprising a second aqueous coating material (P2) having specific viscometric properties, a third colored coating film comprising a third aqueous color coating material (P3) which has a specific coating material solid content concentration (NVP3) and contains a lustrous pigment (BP3), and a clearcoat film comprising a clearcoat material (P4). The present invention simultaneously cures the formed multi-layer coating film by heating.