A membrane roofing system that includes a waterproof layer that protects an insulation layer and a granule coupled to the waterproof layer. The granule has a 60% or greater reflectivity that reduces transmission of ultraviolet light to the waterproof layer. The granule is coated in a fluorinated acrylic copolymer that resists adsorption and absorption of asphaltic chemicals by the granule from the waterproof layer.

A method is provided for forming an adhered membrane roof system that meets Factory Mutual (FM) 4470/4474 standards for wind uplift. The method comprises applying a bond adhesive to a substrate on a roof to form an adhesive layer and applying a membrane directly to the adhesive layer. The bond adhesive includes a moisture-curable polymer.

Photocatalytic roofing granules include a binder and inert mineral particles, with photocatalytic particles dispersed in the binder.

Silicone compositions and methods of using the compositions are provided. The silicone coatings can exhibit improved dirt pick-up resistance and cleanability. The silicone compositions include a polysiloxane, at least one surfactant, and optionally one or more of a pigment, a filler, a crosslinker, an adhesion promoter, a catalyst, additives or solvents.

Silicone compositions and methods of using the compositions are provided. The silicone coatings can exhibit improved dirt pick-up resistance and cleanability. The silicone compositions include a polysiloxane, at least one surfactant, and optionally one or more of a pigment, a filler, a crosslinker, an adhesion promoter, a catalyst, additives or solvents.

A composite material for passive radiative cooling including a base layer, and at least one emissive layer located adjacent to a surface of the base layer, wherein the at least one emissive layer is affixed to the surface of the base layer via a binding agent. Also disclosed are methods of applying passive coolers to articles and surfaces to be adapted for passive radiative cooling.

A composite material for passive radiative cooling including a base layer, and at least one emissive layer located adjacent to a surface of the base layer, wherein the at least one emissive layer is affixed to the surface of the base layer via a binding agent. Also disclosed are methods of applying passive coolers to articles and surfaces to be adapted for passive radiative cooling.

Embodiments may include a coated granule for roofing systems. The coated granule may include an aluminum silicate granule and a coating disposed on the aluminum silicate granule. The coating may include a copolymer and a siloxane-based or a silane-based compound. The copolymer may be a cationic fluorinated (meth)acrylic copolymer. The aluminum silicate granule may have a particle size in a range from 0.2 mm to 2.4 mm. The aluminum silicate granule may have a 65% or greater reflectivity. The coated granule may repel oil and maintain its reflectivity better than with other techniques.

The invention discloses a durable roof structure with frost resistance and high ductility and a construction method thereof, belonging to the technical field of roofing, and comprises a base layer, a leveling layer, a flexible waterproof coating, a thermal insulation layer and a crack-resistant and frost-resistant surface layer arranged in sequence from bottom to top. The invention not only has lower requirements on construction conditions and simple operation, but also reduces the generation of large cracks, effectively improves the crack resistance and frost resistance of the roof, improves the roof structure, and is more suitable for the northern cold region.

Compositions comprising highly reflective microcrystalline/amorphous materials are provided. In some instances, the highly reflective materials are microcrystalline or amorphous carbonate materials, which may include calcium and/or magnesium carbonate. In some instances, the materials are CO.sub.2 sequestering materials. Also provided are methods of making and using the compositions, e.g., to increase the albedo of a surface, to mitigate urban heat island effects, etc.