The invention relates to a method for operating a fluidized bed boiler, comprising carrying out the combustion process with a fluidized bed comprising ilmenite particles, wherein the average residence time of the ilmenite particles in the boiler is at least 75 hours. The invention further relates to ilmenite particles obtainable by a corresponding method and the use of said ilmenite particles as oxygen-carrying material.

The present invention relates to a CLC and operation method thereof equipped with a loop seal separator using magnetic oxygen carrier particles and a magnetic separator. And more particularly, the present invention relates to a loop seal separator using magnetic oxygen carrier particles and a magnetic separator, wherein the loop seal separator comprises a duct into which the ash and magnetic oxygen carrier particles, discharged from a reducer, flow; a magnetic separator to separate the ash from the magnetic oxygen carrier particles, flowing into the duct, by magnetic material; an ash discharge pipe to discharge the ash, separated by the magnetic separator; and an oxygen-carrier-particle discharge pipe to encourage the magnetic oxygen carrier particles, separated by the magnetic separator, to flow into an oxidizer.

A carbonaceous feed pyrolysis apparatus is provided including two or more hot particle fluidised beds, one of which contains a combustion zone, and one or more positive displacement apparatus for the transfer of hot particles beds. Also provided is a bio-oil production process including two or more fluidised beds, a first combustion zone carried out in one or more combustion fluidised beds in which a particulate material is fluidised and heated, and a second pyrolysis zone carried out in one or more pyrolysis fluidised beds in which hot particles heated in the combustion zone are used for pyrolysis of bio-mass, the combustion zone being operated at or about atmospheric pressure at a temperature of from 400 C. to 1100 C., and the pyrolysis zone being operated at a pressure of from atmospheric to 100 Barg at a temperature of from 400 C. to 900 C.

A method and apparatus for heating a furnace using a burner system having first and second burner assemblies, each including a burner and a regenerative media bed, the method including operating the first burner assembly in a firing mode and the second burner assembly in a regeneration mode, switching the first burner assembly from the firing mode to the regeneration mode and the second burner assembly from the regeneration mode to the firing mode, and operating the second burner assembly in the firing mode and the first burner assembly in the regeneration mode. The burner assembly in the firing mode may be fired in either a first operating mode where the burner is supplied with preheated low calorific fuel and the burner is supplied with oxidizing gas or a second operating mode where the burner is supplied with preheated oxidizing gas and the burner is supplied with high calorific fuel.

The invention provides an apparatus which consists of two fluidized beds 1 and 2 separated by a vertical divides' 5. A positive displacement device such as an auger 3 moves the bed material from the reduction side to the combustion side of the device below the fluidization zone. The height of the two fluidized beds is equalized by movement of the bed material through a hole 4 In the vertical divider, from the high temperature side 1 (zone 1) to the tow temperature side 2 (zone 2). The bed material that moves through the hole 4 provides energy to drive reactions that may occur on the reduction side. Energy may also be provided to zone 2 by means of conductive and radiative heat transfer through the dividing wall 5. Energy is provided to zone 1 by means of an exothermic reaction, typically combustion of a fuel 13 using air 12.

The invention concerns a CLC process, and its installation, producing high purity dinitrogen, comprising:

(a) the combustion of a hydrocarbon feed by reduction of a redox active mass brought into contact with the feed,
(b) a first step for oxidation of the reduced active mass (25) obtained from step (a) in contact with a fraction of a depleted air stream (21b), in order to produce a high purity stream of dinitrogen (28) and a stream of partially re-oxidized active mass (26);
(c) a second step for oxidation of the stream of active mass (26) in contact with air (20) in order to produce a stream of depleted air and a stream of re-oxidized active mass (24) for use in step (a);
(d) dividing the stream of depleted air obtained at the end of step (c) in order to form the fraction of depleted air used in step (b) and a fraction complementary to the depleted air extracted from the CLC.

A fluid distribution apparatus is disposed in a fluidized bed reactor and includes a distributor pipe configured to carry a fluid and a centerpipe fluidly connected to the distributor pipe and enclosing a conical distributor for receiving the fluid from the distributor pipe. The conical distributor is defined by an exterior radius including the centerpipe, an upper end including an upper angled circular plate, and a lower end including a lower circular plate. The fluid distribution apparatus further includes a plurality of inlet nozzles fluidly connected to the conical distributor and disposed through the centerpipe for distributing the fluid from the conical distributor to a bed of the fluidized bed reactor.

A counter-current catalyst regenerator with at least two stages of counter-current contact along with a regenerator riser is proposed. Each stage may comprise a permeable barrier that allows upward passage of oxygen-containing gas and downward passage of coked catalyst into each stage, but inhibits upward movement of catalyst to mitigate back mixing and approximate true counter-current contact and efficient combustion of coke from catalyst. The regenerator riser may provide a passage to transport the catalyst and may serve as a secondary stage for coke combustion to provide the regenerated catalyst.

A method and apparatus for treatment of unburnts utilizing oxygen carrier particles, which may be CLOU particles, oxidized in an air reactor and transmitted to a post oxidation reactor as shown in FIG. 2. A flue gas stream containing unburnts is injected into post oxidation reactor wherein unburnts are oxidized by oxygen supplied by oxygen carriers. Reduced oxygen carriers are separated from post oxidation reactor and transmitted back to air reactor for re-oxidation. An embodiment may include a post oxidation chamber, which may be catalytic, receiving a portion of flue gas stream and oxygen from a flue gas stream of post oxidation reactor.

A method for efficiently conveying impurities in a pressurized fluidized incinerator system is provided. Cleaning gas is supplied to an upper valve, and thereafter, the upper valve is driven so as to communicate an upper discharge device and a tank. The upper discharge device is driven so as to convey the impurities from the dust collector to the tank, and thereafter, the upper discharge device is stopped and the upper valve is driven so as not to communicate the upper discharge device and the tank. Thereafter, the supply of the cleaning gas to the upper valve is stopped.