An oxygen fired fluidized bed combustor system (Oxy-FBC) is provided. The system provides means of producing a nearly pure stream of carbon dioxide for storage at high efficiency by controlling the oxygen content within certain regions of the combustor to control the rate of heat release allowing efficient transfer of heat from the combustor to the boiler tubes while avoiding excessively high temperatures that will cause ash melting, and simultaneously remove sulphur from the combustor via sorbents such as limestone and dolomite. The present invention utilizes a coarse oxygen carrier bed material to distribute heat and oxygen throughout an Oxy-FBC, while injecting fine sulphur sorbent that will continuously be removed from the bed.

The present disclosure is directed to an additive mixture and method for controlling nitrogen oxide(s) by adding the additive mixture to a feed material prior to combustion.

The present disclosure is directed to an additive mixture and method for controlling nitrogen oxide(s) by adding the additive mixture to a feed material prior to combustion.

A boiler includes an enclosure having at least a supply for fuel and oxidizer and at least a supply for a SNCR reagent. The supply for the SNCR reagent includes at least a regulation valve for the SNCR reagent. The boiler includes at least a sensor for measuring information indicative of the NO.sub.x concentration over at least one given enclosure cross section. The boiler includes a controller connected to the at least a sensor and to the at least a regulation valve. The controller regulates the SNCR reagent supply according to the measured information indicative of the NO.sub.x concentration.

A boiler includes an enclosure having at least a supply for fuel and oxidizer and at least a supply for a SNCR reagent. The supply for the SNCR reagent includes at least a regulation valve for the SNCR reagent. The boiler includes at least a sensor for measuring information indicative of the NO.sub.x concentration over at least one given enclosure cross section. The boiler includes a controller connected to the at least a sensor and to the at least a regulation valve. The controller regulates the SNCR reagent supply according to the measured information indicative of the NO.sub.x concentration.

Emissions of mercury, NOx, and/or SOx are reduced by enzyme treating coal before combustion, optionally with further treatment of the coal with certain non-bromine containing powder sorbents. y using the steps together, mercury can be reduced by 40% or more, and NOx by 20% or more. Advantageously, no bromine is introduced with the remediation steps.

Emissions of mercury, NOx, and/or SOx are reduced by enzyme treating coal before combustion, optionally with further treatment of the coal with certain non-bromine containing powder sorbents. y using the steps together, mercury can be reduced by 40% or more, and NOx by 20% or more. Advantageously, no bromine is introduced with the remediation steps.

A method of combusting a sulfur-containing carbonaceous material with ash treatment includes: feeding a feed containing the sulfur-containing carbonaceous material and limestone into a furnace; combusting the feed in the furnace so as to generate preliminary fly and bottom ashes; hydrating the preliminary fly and bottom ashes to form a hydrated material; recycling the hydrated materials into the furnace so as to generate secondary fly and bottom ashes; and reacting the secondary fly and bottom ashes with a sulfuric acid solution.

A method of combusting a sulfur-containing carbonaceous material with ash treatment includes: feeding a feed containing the sulfur-containing carbonaceous material and limestone into a furnace; combusting the feed in the furnace so as to generate preliminary fly and bottom ashes; hydrating the preliminary fly and bottom ashes to form a hydrated material; recycling the hydrated materials into the furnace so as to generate secondary fly and bottom ashes; and reacting the secondary fly and bottom ashes with a sulfuric acid solution.

Sorbent components containing halogen, calcium, alumina, and silica are used in combination during coal combustion to produce environmental benefits. Sorbents such as calcium bromide are added to the coal ahead of combustion and other components are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components reduce emissions of elemental and oxidized mercury; increase the level of Hg, As, Pb, and/or Cl in the coal ash; decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and make a highly cementitious ash product.