A hybrid power plant system including a gas turbine system and a coal fired boiler system inputs high oxygen content gas turbine flue gas into the coal fired boiler system, said gas turbine flue gas also including carbon dioxide that is desired to be captured rather than released to the atmosphere. Oxygen in the gas turbine flue gas is consumed in the coal fired boiler, resulting in relatively low oxygen content boiler flue gas stream to be processed. Carbon dioxide, originally included in the gas turbine flue gas, is subsequently captured by the post combustion capture apparatus of the coal fired boiler system, along with carbon diode generated by the burning of coal. The supply of gas turbine flue gas which is input into the boiler system is controlled using dampers and/or fans by a controller based on an oxygen sensor measurement and one or more flow rate measurements.

Methods, apparatuses, and systems related to electrochemical capture of Lewis acid gases from fluid mixtures are generally described. Certain embodiments are related to electrochemical methods involving selectively removing a first Lewis acid gas from a fluid mixture containing multiple types of Lewis acid gases (e.g., a first Lewis acid gas and a second Lewis acid gas). Certain embodiments are related to electrochemical systems comprising certain types of electroactive species having certain redox states in which the species is capable of binding a first Lewis acid gas but for which binding with a second Lewis acid gas is thermodynamically and/or kinetically unfavorable. The methods, apparatuses, and systems described herein may be useful in carbon capture and pollution mitigation applications.

The present invention relates to a furnace black having a STSA surface area of at 130 m.sup.2/g to 350 m.sup.2/g wherein the ratio of BET surface area to STSA surface area is less than 1.1 if the STSA surface area is in the range of 130 m.sup.2/g to 150 m.sup.2/g, the ratio of BET surface area to STSA surface area is less than 1.2 if the STSA surface area is greater than 150 m.sup.2/g to 180 m.sup.2/g, the ratio of BET surface area to STSA surface area is less than 1.3 if the STSA surface area is greater than 180 m.sup.2/g, and
the STSA surface area and the BET surface area are measured according to ASTM D 6556 and to a furnace process wherein the stoichiometric ratio of combustible material to O.sub.2 when forming a combustion gas stream is adjusted to obtain a k factor of less than 1.2 and the inert gas concentration in the reactor is increased while limiting the CO.sub.2 amount fed to the reactor. Also provided is an apparatus for conducting the process according to the present invention.

The present invention relates to a furnace black having a STSA surface area of at 130 m.sup.2/g to 350 m.sup.2/g wherein the ratio of BET surface area to STSA surface area is less than 1.1 if the STSA surface area is in the range of 130 m.sup.2/g to 150 m.sup.2/g, the ratio of BET surface area to STSA surface area is less than 1.2 if the STSA surface area is greater than 150 m.sup.2/g to 180 m.sup.2/g, the ratio of BET surface area to STSA surface area is less than 1.3 if the STSA surface area is greater than 180 m.sup.2/g, and
the STSA surface area and the BET surface area are measured according to ASTM D 6556 and to a furnace process wherein the stoichiometric ratio of combustible material to O.sub.2 when forming a combustion gas stream is adjusted to obtain a k factor of less than 1.2 and the inert gas concentration in the reactor is increased while limiting the CO.sub.2 amount fed to the reactor. Also provided is an apparatus for conducting the process according to the present invention.

A gas combustion treatment device that subjects an ammonia-containing gas, a hydrogen cyanide-containing gas, and a hydrogen sulfide-containing gas to combustion treatment includes: a first combustion unit configured to introduce therein fuel, the ammonia-containing gas, the hydrogen cyanide-containing gas, and air and burn and reduce the fuel and the gases at an air ratio lower than 1; a second combustion unit provided downstream of the first combustion unit and configured to burn and reduce, in a reducing atmosphere, nitrogen oxide in a first combustion gas sent from the first combustion unit; and a third combustion unit provided downstream of the second combustion unit and configured to introduce therein hydrogen sulfide-containing gas with air in addition to a second combustion gas sent from the second combustion unit.

Several embodiments of the present technology are directed to the removal of one or more air pollutants using cooling and/or calcium-containing particles. In some embodiments, a method for removing air pollutants comprises flowing a gas stream having calcium-containing particles and one or more of mercury or hydrochloric acid molecules, and cooling the gas stream, thereby causing at least a portion of the calcium-containing particles to adsorb to the mercury and/or hydrochloric acid molecules in the gas stream. The method can further comprise, after cooling the gas stream, filtering the gas stream to remove at least a portion of the calcium-containing particles having adsorbed mercury and hydrochloric acid.

Disclosed herein are particulate sorbents, such as sorbents that can be used for mercury removal applications. The absorbent can comprise at least one ammonium phosphate and at least one activated carbon selected from unhalogenated activated carbon and halogenated activated carbon, wherein the halogenated activated carbon contains at least one halogen impregnant on its surface. Also disclosed are methods of making sorbents, and methods of mercury removal, e.g., from flue gas generated by coal combustion.

Systems and/or methods are provided for the capture of carbon dioxide from flue gas generated within a building.

A flue gas additive is provided that includes both a nitrogenous component to reduce gas phase nitrogen oxides and a halogen-containing component to oxidize gas phase elemental mercury.

A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas streams, particularly at above average flue stream temperatures of about 340 F. or higher. The multi-functional composition of matter may include a fixed carbon content of at least about 20 wt. %, a mineral content of from about 20 wt. % to about 50 wt. %, a sum of micropore plus mesopore volume of at least about 0.20 cc/g, a micropore volume to mesopore volume ratio of at least about 0.7, and a tapped density of not greater than about 0.575 g/ml. These compositions may be further characterized by number of particles per gram of the composition of matter such that the composition may have at least about 0.8 billion particles per gram, or even as many as 1.5 billion particles per gram. These physical and chemical properties may enhance (1) the oxidation reaction kinetics for the oxidation of mercury species, (2) frequency of contact events, and (3) capture and sequestration of mercury, to achieve efficient mercury capture by the composition even in high temperature flue gas streams.