A system includes a heat exchange system and a power generation system. The heat exchange system includes first, second, and third heat exchangers each operable as a continuous source of heat from a delayed coking plant. The first and second heat exchangers heat first and second fluid streams to produce heated first and second fluid streams, respectively. The heated second fluid stream has a lower temperature and a greater quantity of heat than the heated first fluid stream. The third heat exchanger heats a third fluid stream to produce a heated third fluid stream that includes the heated first fluid stream and a hot fluid stream. The heated third fluid stream has a lower temperature than the heated first fluid stream. The power generation system generates power using heat from the heated second and third fluid streams.

Systems and methods to provide low carbon intensity (CI) ethanol through one or more targeted reductions of carbon emissions based upon an analysis of carbon emissions associated with a combination of various options for feedstock procurement, feedstock refining, processing, or transformation, and ethanol distribution pathways to end users. Such options are selected to maintain the total CI (carbon emissions per unit energy) of the ethanol below a pre-selected threshold that defines an upper limit of CI for the ethanol.

A molten carbonate fuel cell-powered system for capturing carbon dioxide produced by a steam methane reformer system. Tail gas from a pressure swing adsorption system is mixed with exhaust gas from the fuel cell anode, then pressurized and cooled to extract liquefied carbon dioxide. The residual low-CO.sub.2 gas is directed to an anode gas oxidizer, to the anode, to the reformer to be burned for fuel, and/or to the pressure swing adsorption system. Low-CO.sub.2 flue gas from the reformer can be vented to the atmosphere or directed to the anode gas oxidizer. Reduction in the amount of CO.sub.2 reaching the fuel cell allows the fuel cell to be sized according to the power demands of the system and eliminates the need to export additional power output.

The present invention includes a method for converting renewable energy source electricity and a hydrocarbon feedstock into a liquid fuel by providing a source of renewable electrical energy in communication with a synthesis gas generation unit and an air separation unit. Oxygen from the air separation unit and a hydrocarbon feedstock is provided to the synthesis gas generation unit, thereby causing partial oxidation reactions in the synthesis gas generation unit in a process that converts the hydrocarbon feedstock into synthesis gas. The synthesis gas is then converted into a liquid fuel.

Method and device for biogas upgrading and hydrogen production from anaerobic fermentation of biological material under production of energy rich gases selected among methane and hydrogen or a combination thereof. The method comprises addition of hydrogen gas to a fermentation step to enhance the methane: CO.sub.2 ratio in the raw biogas produced. At least part of the raw biogas is subjected to a step of sorption enhanced reforming without prior separation of CO.sub.2, using CaO as an absorbent to capture CO.sub.2 from the raw biogas as well as CO.sub.2 released in the reforming reaction. CaO is regenerated in an endothermic reaction using heat at least partially provided, directly or indirectly, by the bio-gas to be upgraded, thereby producing substantially pure hydrogen and substantially pure CO.sub.2.

A system has an alkaline capture stream as an input, an alkaline depleted stream as an output, a carbon dioxide removal unit operation having a return stream as an output, and a series of electrolyzers, each electrolyzer to receive a CO.sub.2-rich input stream and produce an acidified output stream that is more acidic than the CO.sub.2-rich input stream, and to receive a return stream and produce a basified output stream that is more alkaline than the input return stream. A method of removing carbon dioxide from an atmosphere and generating hydrogen includes capturing carbon dioxide from an atmosphere in an alkaline capture solution, sending the alkaline solution as a CO.sub.2-rich input solution to a series of electrolyzers in a CO.sub.2-rich path, removing carbon dioxide from the acidified CO.sub.2-rich solution at a removal unit to produce a CO.sub.2-poor solution, sending the CO.sub.2-poor solution to the series of electrolyzers in a return path, and returning the return solution to the alkaline capture stream. An electrolyzer is also discussed.

A solution is provided for CO.sub.2 and other green houses gas reduction at the Coal Fired Power Plants (CFPP). The methods and devices disclosed herein provide an inexpensive source of hydrogen and a hydrogen generating system powered by on-site excess heat generated at the CFPP without producing additional CO.sub.2 emission.

A feedstock delivery system transfers a carbonaceous material, such as municipal solid waste, into a product gas generation system. The feedstock delivery system includes a splitter for splitting bulk carbonaceous material into a plurality of carbonaceous material streams. Each stream is processed using a weighing system for gauging the quantity of carbonaceous material, a densification system for forming plugs of carbonaceous material, a de-densification system for breaking up the plugs of carbonaceous material, and a gas and carbonaceous material mixing system for forming a carbonaceous material and gas mixture. A pressure of the mixing gas is reduced prior to mixing with the carbonaceous material, and the carbonaceous material to gas weight ratio is monitored. A transport assembly conveys the carbonaceous material and gas mixture to a first reactor where at least the carbonaceous material within the mixture is subject to thermochemical reactions to form the product gas.

In various aspects, methods are provided for hydrogen production while reducing and/or mitigating emissions during various refinery processes that produce syngas, such as power generation. Syngas can be effectively separated to generate high purity carbon dioxide and hydrogen streams, while reducing and/or minimizing the energy required for the separation, and without needing to reduce the temperature of the flue gas. In various aspects, the operating conditions, such as high temperature, mixed metal oxide adsorbents, and cycle variations, for a pressure swing adsorption reactor can be selected to minimize energy penalties while still effectively capturing the CO.sub.2 present in syngas.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.