Optimizing power generation from waste heat in large industrial facilities such as petroleum refineries by utilizing a subset of all available hot source streams selected based, in part, on considerations for example, capital cost, ease of operation, economics of scale power generation, a number of ORC machines to be operated, operating conditions of each ORC machine, combinations of them, or other considerations are described. Recognizing that several subsets of hot sources can be identified from among the available hot sources in a large petroleum refinery, subsets of hot sources that are optimized to provide waste heat to one or more ORC machines for power generation are also described. Further, recognizing that the utilization of waste heat from all available hot sources in a mega-site such as a petroleum refinery and aromatics complex is not necessarily or not always the best option, hot source units in petroleum refineries from which waste heat can be consolidated to power the one or more ORC machines are identified.

Methods and systems for converting a biomass and biogenic wastes to hydrogen with integrated carbon dioxide capture and storage are disclosed. In some embodiments, the methods include the following: mixing at least one of a dry solid or liquid or liquid hydroxide and catalysts with a biomass to form a biomass mixture; heating the biomass mixture until the hydroxide and the biomass react to produce hydrogen, carbonate, biochar, and potentially fertilizer; calcining the carbonate or performing double replacement reactions of the carbonate to produce sequestration-ready carbon dioxide and a hydroxide; storing the carbon dioxide produced; transferring the hydrogen produced to a fuel cell; and generating electricity with the fuel cell.

According to the present invention, organic material is converted to biogas through anaerobic digestion and the biogas is purified to yield a combustible fluid feedstock comprising methane. A fuel production facility utilizes or arranges to utilize combustible fluid feedstock to generate renewable hydrogen that is used to hydrogenate crude oil derived hydrocarbons in a process to make transportation or heating fuel. The renewable hydrogen is combined with crude oil derived hydrocarbons that have been desulfurized under conditions to hydrogenate the liquid hydrocarbon with the renewable hydrogen or alternatively, the renewable hydrogen can be added to a reactor operated so as to simultaneously desulfurize and hydrogenate the hydrocarbons. The present invention enables a party to receive a renewable fuel credit for the transportation or heating fuel.

The present invention provides a process for the manufacture of a synthetic fuel comprising gasifying a carbonaceous feedstock comprising waste materials and/or biomass to generate a raw synthesis gas; supplying the raw synthesis gas to a primary clean-up zone to wash particulates and ammonia or HCl out of the raw synthesis gas; contacting the synthesis gas in a secondary clean-up zone with a physical solvent for sulphurous materials; contacting the desulphurised raw synthesis gas in a tertiary clean-up zone with a physical solvent for CO.sub.2 effective to absorb CO.sub.2; removing at least part of the absorbed CO.sub.2 in a solvent regeneration stage to recover CO.sub.2 in a form sufficiently pure for sequestration or other use; and supplying the clean synthesis gas to a further reaction train to generate a synthetic fuel.

A process for capturing carbon dioxide includes the steps of mixing a hydrogen stream and a feedstock stream to produce a mixed stream, wherein the feedstock stream includes hydrocarbons, reacting the hydrocarbons and the hydrogen in the primary reactor of the hydroprocessing unit to produce a hydroprocessing product stream and a carbon dioxide stream, wherein the hydroprocessing product stream includes light products, wherein the hydroprocessing unit is further configured to produce ammonium bisulfide, collecting the ammonium bisulfide in the water to produce a sour water, processing the sour water in the waste water unit to produce an ammonia stream, a hydrogen sulfide stream, and a stripped water stream, introducing the ammonia stream to a carbon dioxide recovery system, and separating carbon dioxide from the carbon dioxide stream using the ammonia in the ammonia stream to produce a carbon dioxide product.

Processes for producing high biogenic concentration Fischer-Tropsch liquids derived from the organic fraction of municipal solid wastes (MSW) feedstock that contains a relatively high concentration of biogenic carbon (derived from plants) and a relatively low concentration of non-biogenic carbon (derived from fossil sources) wherein the biogenic content of the Fischer-Tropsch liquids is the same as the biogenic content of the feedstock.

Configurations and related processing schemes of direct or indirect inter-plants (or both) heating systems synthesized for grassroots medium grade crude oil semi-conversion refineries to increase energy efficiency from specific portions of low grade waste heat sources are described. Configurations and related processing schemes of direct or indirect inter-plants (or both) heating systems synthesized for integrated medium grade crude oil semi-conversion refineries and aromatics complex for increasing energy efficiency from specific portions of low grade waste sources are also described.

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

Configurations and related processing schemes of direct or indirect (or both) intra-plants and thermally coupled heating systems synthesized for grassroots medium grade crude oil semi-conversion refineries to increase energy efficiency from specific portions of low grade waste heat sources are described. Configurations and related processing schemes of direct or indirect (or both) intra-plants and thermally coupled heating systems synthesized for integrated medium grade crude oil semi-conversion refineries and aromatics complex for increasing energy efficiency from specific portions of low grade waste sources are also described.

Configurations and related processing schemes of inter-plants and hybrid, intra- and inter-plants' direct or indirect heating systems synthesized for grassroots medium grade crude oil semi-conversion refineries to increase energy efficiency from specific portions of low grade waste heat sources are described. Configurations and related processing schemes of inter-plants and hybrid, intra- and inter-plants' direct or indirect heating systems synthesized for integrated medium grade crude oil semi-conversion refineries and aromatics complex for increasing energy efficiency from specific portions of low grade waste sources are also described.