A process and an apparatus are disclosed for a compact processing assembly to remove C.sub.5 and heavier hydrocarbon components from a hydrocarbon gas stream. The hydrocarbon gas stream is expanded to lower pressure and supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a residual vapor stream and a condensed stream. The condensed stream is supplied to the absorbing means at its top feed point. A distillation liquid stream is collected from the lower region of the mass transfer means and directed into a second heat and mass transfer means inside the processing assembly to heat it and strip out its volatile components.

The invention relates to CeO.sub.2 and La.sub.2O.sub.3 for catalyzing Fe.sub.2O.sub.3Al.sub.2O.sub.3 based chemical-looping reforming of CH.sub.4 with CO.sub.2 (CL-DRM). The reaction performance of all the composite oxygen carriers was evaluated in a fixed-bed reactor at atmospheric pressure condition. The influencing factors, including temperature and time-on-stream (TOS) were investigated. The characteristics of the oxygen carriers were checked with Brunauer-Emmett-Teller (BET) analysis and X-ray diffraction (XRD). The reducibility of the composite materials was elucidated with temperature-programmed reduction by CH.sub.4 (CH.sub.4-TPR). Preliminary experimental observations suggest that the simultaneous presence of CeO.sub.2 and La.sub.2O.sub.3 can not only enhance the reactivity of Fe.sub.2O.sub.3Al.sub.2O.sub.3 toward CH.sub.4 oxidation and its oxygen releasing rate for fast reaction kinetics, but also improve the reactivity of its reduced form toward CO.sub.2 splitting.

A system includes a heat exchange system and a power generation system. The heat exchange system includes first, second, and third heat exchangers each operable as a continuous source of heat from a delayed coking plant. The first and second heat exchangers heat first and second fluid streams to produce heated first and second fluid streams, respectively. The heated second fluid stream has a lower temperature and a greater quantity of heat than the heated first fluid stream. The third heat exchanger heats a third fluid stream to produce a heated third fluid stream that includes the heated first fluid stream and a hot fluid stream. The heated third fluid stream has a lower temperature than the heated first fluid stream. The power generation system generates power using heat from the heated second and third fluid streams.

A power generation system includes four heating fluid circuits thermally coupled to heat sources from sub-units of a petrochemical refining system. The sub-units include a hydrocracking plant, an aromatics plant, and a diesel hydro-treating plant. Subsets of the heat sources includes hydrocracking plant heat exchangers coupled to streams in the hydrocracking plant, aromatics plant heat exchangers coupled to streams in the aromatics plant, and diesel hydro-treating plant heat exchangers coupled to streams in the diesel hydro-treating plant. A power generation system includes three organic Rankine cycles, each including a working fluid that is thermally coupled to at least one heating fluid circuit to heat the working fluid, and an expander to generate electrical power from the heated working fluid. The system includes a control system to activate a set of control valves to selectively thermally couple each heating fluid circuit to at least a portion of the heat sources.

Disclosed are processes for producing a transportation fuel from a high quality oil sands-derived crude oil. The oil sands-derived crude oil is provided as a feed source for a catalytic conversion reaction, which produces the product useful as the transportation fuel. The oil sands-derived crude oil has an ASTM D7169 5% distillation point of from 400 F. to 700 F. Transportation fuel is produced from the provided oil sands-derived crude oil by treating the oil sands-derived crude oil through at least one catalytic cracking process and mild hydrotreating process.

Methods and apparatuses for separating CO.sub.2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sulfur removal unit. The SPSA system includes multiple pressure equalization steps and a rinse step using a rinse gas that is supplied from a source other than directly from one of the adsorber beds of the SPSA system.

This disclosure relates to a method that includes (1) contacting a solvent with a porous cyclodextrin-based metal organic framework (CD-MOF) adsorbed with CO.sub.2 to release CO.sub.2, and (2) collecting the released CO.sub.2. The CD-MOF includes at least a metal cation and a plurality of cyclodextrin components.

Optimizing power generation from waste heat in large industrial facilities such as petroleum refineries by utilizing a subset of all available hot source streams selected based, in part, on considerations for example, capital cost, ease of operation, economics of scale power generation, a number of ORC machines to be operated, operating conditions of each ORC machine, combinations of them, or other considerations are described. Subsets of hot sources that are optimized to provide waste heat to one or more ORC machines for power generation are also described. Further, recognizing that the utilization of waste heat from all available hot sources in a mega-site such as a petroleum refinery and aromatics complex is not necessarily or not always the best option, hot source units in petroleum refineries from which waste heat can be consolidated to power the one or more ORC machines are identified.

Optimizing power generation from waste heat in large industrial facilities such as petroleum refineries by utilizing a subset of all available hot source streams selected based, in part, on considerations for example, capital cost, ease of operation, economics of scale power generation, a number of ORC machines to be operated, operating conditions of each ORC machine, combinations of them, or other considerations are described. Subsets of hot sources that are optimized to provide waste heat to one or more ORC machines for power generation are also described. Further, recognizing that the utilization of waste heat from all available hot sources in a mega-site such as a petroleum refinery and aromatics complex is not necessarily or not always the best option, hot source units in petroleum refineries from which waste heat can be consolidated to power the one or more ORC machines are identified.

A power generation system includes a heating fluid circuit thermally coupled to multiple heat sources from at least an integrated hydrocracking plant and diesel hydro-treating plant of a petrochemical refining system. A first subset of the heat sources includes diesel hydro-treating plant heat exchangers coupled to streams in the diesel hydro-treating plant. A second subset of the heat sources includes hydrocracking plant heat exchangers coupled to streams in the hydrocracking plant. The heat exchangers are connected to a power generation system that includes an organic Rankine cycle (ORC) including a working fluid that is thermally coupled to the heating fluid circuit to heat the working fluid, an expander configured to generate electrical power from the heated first working fluid, and a control system configured to activate a set of control valves to selectively thermally couple the heating fluid circuit to at least a portion of the heat sources.