Patent classifications
C01F5/00
Method for separation and enrichment of lithium
A method for separation and enrichment of lithium includes the following steps: pretreatment: carrying out at least two dilutions and at least two filtrations on salina aged brine to obtain pretreated brine; separation: separating the pretreated brine via a nanofiltration separation system to obtain nanofiltration permeate and nanofiltration concentrate; first concentration: carrying out first concentration on the nanofiltration permeate via a reverse osmosis system to obtain reverse osmosis concentrate and reverse osmosis permeate; second concentration: carrying out second concentration on the reverse osmosis concentrate via an electrodialysis system to obtain electrodialysis concentrate and electrodialysis permeate, and the electrodialysis concentrate is solution enriching lithium ions. The present application couples several different membrane separation technologies and dilutes the salina aged brine for many times, thereby realizing the purposes of improving separation efficiency of magnesium and lithium and improving the enrichment efficiency of lithium.
Carbon dioxide sequestration with magnesium hydroxide and regeneration of magnesium hydroxide
Embodiments of the present disclosure are directed to systems and methods of removing carbon dioxide from a gaseous stream using magnesium hydroxide and then regenerating the magnesium hydroxide. In some embodiments, the systems and methods can further comprise using the waste heat from one or more gas streams to provide some or all of the heat needed to drive the reactions. In some embodiments, magnesium chloride is primarily in the form of magnesium chloride dihydrate and is fed to a decomposition reactor to generate magnesium hydroxychloride, which is in turn fed to a second decomposition reactor to generate magnesium hydroxide.
Carbon dioxide sequestration with magnesium hydroxide and regeneration of magnesium hydroxide
Embodiments of the present disclosure are directed to systems and methods of removing carbon dioxide from a gaseous stream using magnesium hydroxide and then regenerating the magnesium hydroxide. In some embodiments, the systems and methods can further comprise using the waste heat from one or more gas streams to provide some or all of the heat needed to drive the reactions. In some embodiments, magnesium chloride is primarily in the form of magnesium chloride dihydrate and is fed to a decomposition reactor to generate magnesium hydroxychloride, which is in turn fed to a second decomposition reactor to generate magnesium hydroxide.
Olefin polymerization catalyst carrier, solid catalyst component and use thereof
A method of making an olefin polymerization catalyst carrier with a general structure formula of Mg(OR.sup.I).sub.n(OR.sup.II).sub.2-n, wherein: 0≤n≤2, and R.sup.I and R.sup.II can be the same or different and are each independently selected from a C.sub.1-C.sub.20 hydrocarbon group by reacting an alcohol with a metal magnesium powder under the protection of nitrogen in the presence of a halogen or a halogen-containing compound to obtain a first product, and subjecting the product to a treatment pressure of from 0.2 to 5.0 MPa at a treatment temperature of from 80 to 200° C. for a duration of between 2 minutes and 6 hours. Also provided is a method of making an olefin polymerization solid catalyst component which includes the catalyst carrier, a titanium compound, and at least one electron donor compound.
ELECTROCHEMICAL CELL HAVING SOLID IONICALLY CONDUCTING POLYMER MATERIAL
The invention features an electrochemical cell having an anode and a cathode; wherein at least one of the anode and cathode includes a solid ionically conducting polymer material that can ionically conduct hydroxyl ions.
A Lithium-Rich Layered Oxide Material With Phase Structure Gradient And Its Preparation Method
A lithium-rich layered oxide material with a phase structure gradient and method for making the same are disclosed, used as cathode material for lithium ion battery. The invention has the following technical features: the spherical granule-shaped lithium-rich layered oxide material contains two types of structural units whose ratio gradually changes from the center to the surface of the spherical granule, wherein the monoclinic Li.sub.2MnO.sub.3 structural unit is gradually reduced, and the rhombohedral LiTMO.sub.2 structural unit is gradually increased from the center to the surface of the spherical granule. By controlling the ratio of the monoclinic Li.sub.2MnO.sub.3 structural unit versus the rhombohedral LiTMO.sub.2 structural unit along from the center to the surface the spherical granule, the performance of the Lithium-rich layered oxide materials as cathode for lithium ion battery, such as cyclic stability, specific discharge capacity, safety and other properties, is improved. The preparation process is simple and easy to control, the cost of raw materials is low and the environment is friendly. It can be industrialized on a large scale and has a good prospect of application.
A Lithium-Rich Layered Oxide Material With Phase Structure Gradient And Its Preparation Method
A lithium-rich layered oxide material with a phase structure gradient and method for making the same are disclosed, used as cathode material for lithium ion battery. The invention has the following technical features: the spherical granule-shaped lithium-rich layered oxide material contains two types of structural units whose ratio gradually changes from the center to the surface of the spherical granule, wherein the monoclinic Li.sub.2MnO.sub.3 structural unit is gradually reduced, and the rhombohedral LiTMO.sub.2 structural unit is gradually increased from the center to the surface of the spherical granule. By controlling the ratio of the monoclinic Li.sub.2MnO.sub.3 structural unit versus the rhombohedral LiTMO.sub.2 structural unit along from the center to the surface the spherical granule, the performance of the Lithium-rich layered oxide materials as cathode for lithium ion battery, such as cyclic stability, specific discharge capacity, safety and other properties, is improved. The preparation process is simple and easy to control, the cost of raw materials is low and the environment is friendly. It can be industrialized on a large scale and has a good prospect of application.
Green-emitting phosphors and devices thereof
A device including an LED light source optically coupled to a phosphor selected from [Y,Gd,Tb,La,Sm,Pr,Lu].sub.3[Al,Ga].sub.5−aO.sub.12−3/2a:Ce.sup.3+ (wherein 0<a<0.5), beta-SiAlON:Eu.sup.2+, [Sr,Ca,Ba][Al,Ga,In].sub.2S.sub.4:Eu.sup.2+, alpha-SiAlON doped with Eu.sup.2+ and/or Ce.sup.3+, Ca.sub.1−h−rCe.sub.hEu.sub.rAl.sub.1−h[Mg,Zn].sub.hSiN.sub.3, (where 0<h<0.2, 0<r<0.2), Sr(LiAl.sub.3N.sub.4):Eu.sup.2+, [Ca,Sr]S:Eu.sup.2+ or Ce.sup.3+, [Ba,Sr,Ca].sub.bSi.sub.gN.sub.m:Eu.sup.2+ (wherein 2b+4g=3m), quantum dot materials, and combinations thereof; and a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented.
Green-emitting phosphors and devices thereof
A device including an LED light source optically coupled to a phosphor selected from [Y,Gd,Tb,La,Sm,Pr,Lu].sub.3[Al,Ga].sub.5−aO.sub.12−3/2a:Ce.sup.3+ (wherein 0<a<0.5), beta-SiAlON:Eu.sup.2+, [Sr,Ca,Ba][Al,Ga,In].sub.2S.sub.4:Eu.sup.2+, alpha-SiAlON doped with Eu.sup.2+ and/or Ce.sup.3+, Ca.sub.1−h−rCe.sub.hEu.sub.rAl.sub.1−h[Mg,Zn].sub.hSiN.sub.3, (where 0<h<0.2, 0<r<0.2), Sr(LiAl.sub.3N.sub.4):Eu.sup.2+, [Ca,Sr]S:Eu.sup.2+ or Ce.sup.3+, [Ba,Sr,Ca].sub.bSi.sub.gN.sub.m:Eu.sup.2+ (wherein 2b+4g=3m), quantum dot materials, and combinations thereof; and a green-emitting U.sup.6+-doped phosphor having a composition selected from the group consisting of U.sup.6+-doped phosphate-vanadate phosphors, U.sup.6+-doped halide phosphors, U.sup.6+-doped oxyhalide phosphors, U.sup.6+-doped silicate-germanate phosphors, U.sup.6+-doped alkali earth oxide phosphors, and combinations thereof, is presented.
ANTIFREEZING COOLANT COMPOSITION NOT INCLUDING GLYCOL
Disclosed is an antifreezing coolant composition, which does not include glycol but includes environmentally friendly materials, such as a carboxylic acid salt, an anthranilamide compound, a corrosion inhibitor and a triazole compound. The antifreezing coolant composition may form a thin film on the metal surface in cooling systems for vehicles to thereby exhibit high corrosion resistance at low and high temperatures, superior antifreezing performance at low temperatures, and superior cooling performance at high temperatures.