Patent classifications
C08B3/00
Method for preparing cellulose nanofiber capable of being stably dispersed
A method for preparing stably dispersed cellulose nanofibers comprises the following steps: 1) mixing cellulose and an organic solvent, the percentage of the cellulose being 1% to 15% in weight; 2) adding an esterification agent into the resultant mixture of step 1), the molar ratio of the esterification agent to the cellulose being from 1:0.1 to 4; and 3) physically breaking the resultant mixture of step 2) until a suspension liquid with stably dispersed cellulose nanofibers of 2-1000 nm in diameter and 10-100 μm in length is obtained, an esterification reaction of hydroxyl group(s) on the surface of cellulose fibers occurring at the time of the breaking. Also disclosed are dispersed cellulose nanofibers with improved compatibility to the matrix than the untreated cellulose and an improved strength of the composite materials.
POLYSACCHARIDE DERIVATIVE PRODUCTION METHOD AND LIGNIN DERIVATIVE PRODUCTION METHOD
An object of the present invention is to provide a method for producing a polysaccharide derivative in which the use of a reagent such as an acid catalyst is not needed and a reaction can be smoothly progressed without causing any side reactions. A method for producing a polysaccharide derivative of the present invention includes a step of dissolving a raw material including a polysaccharide in at least one ionic liquid having an anion which is a non-carboxylate anion and reacting the raw material with an acyl group donor, a conjugate acid of the anion having a pKa of 4 or higher in vacuum.
VARIABLE-SIZE HYDROPHOBICALLY-MODIFIED POLYMERS
In various aspects, the invention provides compositions of variable-length hydrophobically-modified polymers. These variable-length hydrophobes decorated along the hydrophilic polymer backbone provide advanced properties and allow for precise control over the behavior of the resulting amphiphilic polymer, including in aqueous solution. Such control allows for enhanced functionality of the amphiphilic polymer relative to standard single-length hydrophobe grafting designs, including for hemostasis.
CELLULOSE ESTER COMPOSITIONS DERIVED FROM RECYCLED CELLULOSE ESTER CONTENT SYNGAS
A process for preparing a recycle cellulose ester and a recycle cellulose ester composition and articles made with such recycle cellulose esters comprising at least one cellulose ester having at least one substituent on an anhydroglucose unit (AU) derived from recycled cellulose ester content syngas are provided. The recycled cellulose ester content syngas can be obtained by gasifying feedstocks containing a solid fossil fuel such as coal, a cellulose ester, and water. The cellulose ester can be post-consumer or post-industrial cellulose ester.
VARIABLE-SIZE HYDROPHOBICALLY-MODIFIED POLYMERS
In various aspects, the invention provides compositions of variable-length hydrophobically-modified polymers. These variable-length hydrophobes decorated along the hydrophilic polymer backbone provide advanced properties and allow for precise control over the behavior of the resulting amphiphilic polymer, including in aqueous solution. Such control allows for enhanced functionality of the amphiphilic polymer relative to standard single-length hydrophobe grafting designs, including for hemostasis.
HYDROPHOBICALLY MODIFIED CHITOSAN COMPOSITIONS
Disclosed herein is a polymer composition comprising an effective amount of a hydrophobically-modified polymer having functional groups along the backbone occupied by a fatty anhydride moiety. The polymer composition has a potent hemostatic action by gelling blood upon contact, and is suitable for treating internal and external bleeds. As disclosed herein, the modified polymer can be generated without the use of toxic reagents that would require removal from the product. Further, compositions are shelf stable even in a flowable form. That is, the hydrophobic grafts are not lost under product storage conditions (e.g., room temperature storage).
Hydrophobically modified chitosan compositions
Disclosed herein is a polymer composition comprising an effective amount of a hydrophobically-modified polymer having functional groups along the backbone occupied by a fatty anhydride moiety. The polymer composition has a potent hemostatic action by gelling blood upon contact, and is suitable for treating internal and external bleeds. As disclosed herein, the modified polymer can be generated without the use of toxic reagents that would require removal from the product. Further, compositions are shelf stable even in a flowable form. That is, the hydrophobic grafts are not lost under product storage conditions (e.g., room temperature storage).
Heteropolysaccharides
The present invention relates a heteropolysaccharide characterized in that it is substantially composed of the monosaccharides glucose and galactose and rhamnose and N-acetylgalactosamine and a process for the production thereof. The invention further relates to a bacterium capable of producing said heteropolysaccharide and to the use of the heteropolysaccharide and the bacterium for improving the texture of fermented milk products.
MANUFACTURE OF NANOCELLULOSE AND INTERMEDIATES THEREOF
The present invention relates to a method for manufacturing nanocellulose comprising the steps of: a) providing a cellulose-containing material wherein the cellulose-containing material contains less than 20 wt. % water, b) contacting the cellulose-containing material with oxalic acid dihydrate, and heating above the melting point of the oxalic acid dihydrate, to obtain cellulose oxalates, c) washing the mixture, d) preparing a suspension comprising the washed material from step c) and e) recovering nanocellulose from the suspension. The present invention relates also to a method of manufacturing nanocellulose intermediate which comprises the above described steps a)-c). The methods disclosed in the present invention are quick, simple, and direct. Pulp can be used as raw material. A considerable amount of free carboxyl groups are introduced. A high yield can be obtained. The methods are inexpensive.
MANUFACTURE OF NANOCELLULOSE AND INTERMEDIATES THEREOF
The present invention relates to a method for manufacturing nanocellulose comprising the steps of: a) providing a cellulose-containing material wherein the cellulose-containing material contains less than 20 wt. % water, b) contacting the cellulose-containing material with oxalic acid dihydrate, and heating above the melting point of the oxalic acid dihydrate, to obtain cellulose oxalates, c) washing the mixture, d) preparing a suspension comprising the washed material from step c) and e) recovering nanocellulose from the suspension. The present invention relates also to a method of manufacturing nanocellulose intermediate which comprises the above described steps a)-c). The methods disclosed in the present invention are quick, simple, and direct. Pulp can be used as raw material. A considerable amount of free carboxyl groups are introduced. A high yield can be obtained. The methods are inexpensive.