Patent classifications
C08G2290/00
METHODS FOR REDUCING ALDEHYDE EMISSIONS IN POLYURETHANE FOAMS
Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, at least one acetoacetate ester or amide and at least one aminoalcohol or alkylhydroxylamine. Foams so produced emit low levels of formaldehyde, acetaldehyde and propionaldehyde.
POLYURETHANE FOAMS HAVING REDUCED ALDEHYDE EMISSIONS
Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, at least one aminoalcohol compound and least one antioxidant. Foams so produced emit low levels of both formaldehyde and acetaldehyde.
HIGH-DURABILITY ANTIFOGGING COATING FILM AND COATING COMPOSITION
The problem addressed by the present invention is to provide an antifogging coating film having excellent antifogging property, antifogging persistence, persistence of appearance, and elution resistance. The coating film according to the present invention contains a metal oxide (A) and a hydrophilic compound (B); the height of the eluate by a coating film surface elution test is 1.0 m or less; this test is carried out by placing 10 L of deionized water on the coating film, allowing the film to stand for 24 hours in a 23 C., 50% RH environment, measuring the eluate height of 20 locations selected randomly within a 10 cm.sup.2 range on the coating film surface, and determining the maximum height; and the water contact angle measured after subjecting the coating film to a moisture resistance test by exposure for 24 hours in an 85 C., 85% RH environment followed by standing for one hour in a 23 C., 50% RH environment, is less than 40. Preferably, the elution level per coating film unit volume by a coating film total elution test is 40 mg/cm.sup.3 or less, and this test is carried out by immersing the coating film in 23 C. deionized water for 24 hours, then measuring the weight of the coating film eluate recovered from the deionized water.
Aldehyde scavengers for polyurethane foams
A polyurethane composition comprising an aldehyde scavenger, a polyurethane product, and a process for making polyurethane foam are disclosed. The scavenger compounds can reduce, if not eliminate, the emissions of aldehydes from polyurethane foams. The scavenger compounds comprise at least one member selected from the group consisting of: phenol or substituted phenol, a 1,3-dicarbonyl compound, a polyamine bearing a 1,3-propanediamino function, melamine, a 1,2-diaminocycloalkane, an ammonium salt; a compound containing the bisulfite anion, titanium dioxide and aminosiloxane.
LAMINATING ADHESIVES BASED ON PRIMARY HYDROXYL-CONTAINING CURATIVES
A curative containing two or more primary hydroxyl groups per molecule and one or more moieties derived from a secondary hydroxyl-containing polyol such as polypropylene glycol is prepared in a multistage process wherein the secondary hydroxyl-containing polyol is end-capped with an excess of a reactant such as a polybasic acid and the resulting functionalized intermediate is then reacted with a polyol such as glycerin or diethylene glycol containing primary hydroxyl groups. Such curatives may be used in combination with isocyanate-functionalized polyurethane prepolymers to provide two component adhesives useful for laminating thin films and/or foils.
METHOD FOR PRODUCING TDI-BASED FLEXIBLE POLYURETHANE FOAMS CONTAINING ORGANIC ACID ANHYDRIDES AND/OR ORGANIC ACID CHLORIDES
The present invention relates to a method for producing TDI-based flexible polyurethane foams, particularly molded foams, using organic acid anhydrides and chlorides. The invention also relates to the flexible polyurethane foams produced by the method according to the invention.
POLYMERIC AMINE ANTIOXIDANTS
An amine compound comprises a nitrogen atom, a hydrogen atom directly bonded to the nitrogen atom, and two aromatic groups directly bonded to the nitrogen atom. At least one of the aromatic groups comprises at least one polymeric substituent bound thereto, the polymeric substituent comprising three or more monomers units. A method for producing a polyurethane polymer comprises the steps of (a) providing a polyol; (b) providing a polyisocyanate compound; (c) providing the amine compound described above; (d) combining the polyol, the polyisocyanate compound, and the amine compound to produce a reaction mixture; and (e) allowing the polyol and the polyisocyanate compound to react to produce a polyurethane polymer.
POLYMERIC PHENOLIC ANTIOXIDANTS
A phenol compound comprises a phenyl group, a hydroxy group directly bonded to the phenyl group, and at least one polymeric substituent bound to the phenyl group. The polymeric substituent comprises three or more monomers units. A method for producing a polyurethane polymer comprises the steps of (a) providing a polyol; (b) providing a polyisocyanate compound; (c) providing the phenol compound described above; (d) combining the polyol, the polyisocyanate compound, and the phenol compound to produce a reaction mixture; and (e) allowing the polyol and the polyisocyanate compound to react to produce a polyurethane polymer.
Vehicle antifogging system
An antifogging system of a vehicle includes a windshield provided between a space inside a vehicle cabin and a space outside the vehicle cabin, an antifogging coating provided on a surface of the windshield facing the vehicle cabin and configured to absorb water adhering to a surface the coating into the coating, an air conditioner configured to vaporize water absorbed in the antifogging coating, a humidity sensor configured to detect a humidity in a temperature boundary layer formed along a surface of the antifogging coating facing the vehicle cabin, and a control unit configured to operate the air conditioner when the humidity is equal to or higher than a predetermined threshold.
ANTIFOG SEALANT COMPOSITION AND COEXTRUDED MULTILAYER POLYESTER FILM INCLUDING THE SAME
The invention relates to a sealant antifog composition for polyester films comprising anionic and non-ionic surfactants in a mixture of amorphous and (semi)crystalline polyesters. The invention also relates to a multi-layer film comprising a sealant layer having the above composition, to the use of said films in food packaging and to the packages obtained therefrom.