An advanced regulatory controller for a converter of a catalytic olefins unit is disclosed. A Fluid Catalytic Cracking (FCC) type converter (i.e., reactor-regenerator) is combined with an ethylene style cold-end for product recovery. The regulatory controller operates using an Advanced Regulatory Control (ARC) application using variables, such as a controlled variable, four disturbance variables, associated variable, and a manipulated variable. The ARC application manipulates fuel oil or tail gas flow to a regenerator in response to an expected future steady state value of a regenerator bed temperature resulting from changes in the values of a selected set of the variables.

A method for producing a low-viscosity high-aromatic non-carcinogenic petroleum-based process oil which can be used as a plasticizer oil or an extender oil in the manufacture of synthetic rubber and tyres is described. The oil is obtained from by-product fractions of secondary petrochemical processes by fractional distillation, wherein the used by-product fractions of secondary petrochemical processes are products of catalytic cracking, or products of catalytic reforming, or aromatic extracts, or mixtures thereof, which have an initial boiling point of no less than 200° C. and above and a final boiling point of no less than 360° C. at atmospheric pressure, and contain no less than 85% of aromatic constituents and no more than 10.0 mg/kg of the sum of the following polycyclic aromatic hydrocarbons: benz[a]anthracene; chrysene; benzo[b]fluoranthene; benzo[i]fluoranthene; benzo[k]fluoranthene; benzo[e]pyrene; benzo[a]pyrene; and dibenzo[a,h]anthracene.

Apparatus for monitoring the erosion of components of industrial plants comprising at least one optical fiber sensor (7′), the optical fibers (7′) not being provided with any Bragg grid, and an analysis unit, wherein the at least one optical fiber sensor (7′) is positioned inside a wall subjected to wear by erosion in such a way as to terminate immediately under the surface of the wall itself belonging to the components (10, 10′, 20, 20′) to be monitored, and the erosion depth is measured by using the light reflected from the eroded end of the optical fiber (7′) itself.

Apparatus for monitoring the erosion of components of industrial plants comprising at least one optical fiber sensor (7′), the optical fibers (7′) not being provided with any Bragg grid, and an analysis unit, wherein the at least one optical fiber sensor (7′) is positioned inside a wall subjected to wear by erosion in such a way as to terminate immediately under the surface of the wall itself belonging to the components (10, 10′, 20, 20′) to be monitored, and the erosion depth is measured by using the light reflected from the eroded end of the optical fiber (7′) itself.

Assemblies and methods to enhance a fluid catalytic cracking (FCC) process associated with a refining operation, during the FCC process, may include supplying a hydrocarbon feedstock to first processing units associated with the refining operation. The assemblies and methods also may include conditioning a hydrocarbon feedstock and unit material samples, and analyzing the samples via one or more spectroscopic analyzers. The assemblies and methods further may include prescriptively controlling, via one or more FCC process controllers, based at least in part on the hydrocarbon feedstock properties and the unit material properties, the FCC processing assembly, so that the prescriptively controlling results in causing the FCC process to produce intermediate materials, the unit materials, and/or the downstream materials having properties within selected ranges of target properties, thereby to cause the FCC process to achieve material outputs that more accurately and responsively converge on one or more of the target properties.

Assemblies and methods to enhance a fluid catalytic cracking (FCC) process associated with a refining operation, during the FCC process, may include supplying a hydrocarbon feedstock to first processing units associated with the refining operation. The assemblies and methods also may include conditioning a hydrocarbon feedstock and unit material samples, and analyzing the samples via one or more spectroscopic analyzers. The assemblies and methods further may include prescriptively controlling, via one or more FCC process controllers, based at least in part on the hydrocarbon feedstock properties and the unit material properties, the FCC processing assembly, so that the prescriptively controlling results in causing the FCC process to produce intermediate materials, the unit materials, and/or the downstream materials having properties within selected ranges of target properties, thereby to cause the FCC process to achieve material outputs that more accurately and responsively converge on one or more of the target properties.

A process increases the concentration of non normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. The non-normal paraffin rich stream is isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins, hydrocrack C5+ hydrocarbon to C2-C4 paraffins and produce an isomerization effluent stream. The isomerization effluent stream is separated into a C3− off gas, C4 rich stream and C5+ stream that is recycled to the naphtha feed stream. A depentanizer column may be positioned to either remove C6+ from the naphtha feed stream or from a bottoms stream from a stabilizer column. The amount of C2-C4 paraffins that are provided is increased from about 55% to as much as 77% and even more with further modifications including operating at higher temperatures or increasing the volume of catalyst.

A process increases the concentration of non normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. The non-normal paraffin rich stream is isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins, hydrocrack C5+ hydrocarbon to C2-C4 paraffins and produce an isomerization effluent stream. The isomerization effluent stream is separated into a C3− off gas, C4 rich stream and C5+ stream that is recycled to the naphtha feed stream. A depentanizer column may be positioned to either remove C6+ from the naphtha feed stream or from a bottoms stream from a stabilizer column. The amount of C2-C4 paraffins that are provided is increased from about 55% to as much as 77% and even more with further modifications including operating at higher temperatures or increasing the volume of catalyst.

The present invention concerns a method for processing a petrol containing sulfur and olefin compounds, comprising the following steps: a) a step of hydrodesulfurisation in the presence of a catalyst comprising an oxide support and an active phase comprising a metal from group VIB and a metal from group VIII, b) a step of separating the H.sub.2S formed, c) a step of hydrodesulfurisation at a higher temperature than that of step a), with a hydrogen/feedstock ratio less than that of step a), and in the presence of a hydrodesulfurisation catalyst comprising an oxide support and an active phase consisting of at least one metal from group VIII, d) a step of separating the H.sub.2S formed.

A method is disclosed of producing hydrocarbons from a recycled or renewable organic material, wherein the recycled or renewable organic material contains from 5 to 30 wt-% oxygen as organic oxy-gen compounds and from 1 to 1000 ppm phosphorous as phosphorous compounds. Exemplary methods include (a) providing the recycled or renewable organic material (c) thermally cracking the recycled or renewable organic material thereby reducing the oxygen and phosphorous content of the recycled or renewable organic material to obtain (i) a vapor fraction containing a major part of volatiles, and (ii) a thermally cracked recycled or renewable organic material fraction containing less oxygen and less phosphorous than the recycled or renewable organic material provided in step (a); and (f) hydrotreating the thermally cracked recycled or renewable organic material fraction in a presence of a hydrotreating catalyst; to obtain hydrocarbons containing less than 1 wt % oxygen and less phosphorous than the recycled or re-newable organic material provided in step (a).