A method for operating a metallurgical furnace and a simplified way of providing synthesis gas for a metallurgical furnace, includes the following steps performing a combustion process outside the metallurgical furnace by combusting a carbon-containing material with an oxygen-rich gas to produce an offgas, which offgas is a CO.sub.2 containing gas; and combining the offgas, while having an elevated combustion-induced temperature due to the combustion process, with a hydrocarbon-containing fuel gas to obtain a first gas mixture having a temperature above a reforming temperature necessary for a reforming process, preferably a dry reforming process; the first gas mixture undergoing the reforming process, thereby producing a synthesis gas containing CO and H.sub.2, the reforming process being performed non-catalytically; and feeding the synthesis gas into the metallurgical furnace.

A method for operating a blast furnace, including collecting a blast furnace gas from the blast furnace, the blast furnace gas being a CO.sub.2 containing gas, combining the blast furnace gas with a fuel gas to obtain a gas mixture, the fuel gas being a hydrocarbon containing gas, subjecting the gas mixture to a reforming process, thereby producing a synthesis gas containing CO and H.sub.2; and feeding at least a portion of the synthesis gas and an oxygen-rich gas into the blast furnace, where the blast furnace gas is combined with the fuel gas while containing substantially the same amount of CO.sub.2 as when exiting the blast furnace and wherein the blast furnace gas is combined with the fuel gas in an over-stoichiometric ratio, so that the synthesis gas contains a surplus portion of the blast furnace gas.

The present invention provides a reduction system and method that can be operated with any proportion of gaseous hydrogen-containing gases and gaseous hydrocarbon-containing gases having the possibility of continuing its operation, ensuring an high process availability and negligible loss of production, when the gaseous hydrogen-containing gas for any reason is not available and allow the substitution of the gaseous hydrogen-containing gas with a gaseous hydrocarbon-containing gas with minor adjustments in the plant operation. The reduction system of the invention is designed to be implemented in new and already built direct reduction plants to operate efficiently and has lower capital and operation costs.

A coupling system of copper slag recycling and CO.sub.2 mineralization process based on industrial solid waste includes the following steps: obtaining copper slags, performing a slag forming treatment, obtaining reforming slags, obtaining sponge iron, coupling the reforming slag with a CO.sub.2 mineralization process based on industrial solid waste, and coupling the CO.sub.2 generated in the process of obtaining sponge iron with the CO.sub.2 mineralization process based on industrial solid waste. The system includes a slag forming treatment device, a secondary treatment device, a first coupling device, and a second coupling device. The coupling system couples the recycling of copper slag with the existing CO.sub.2 mineralization process based on industrial solid waste. Various production lines can be organically integrated in a green and clean manner for both reforming slag and flue gas.

According to embodiments, disclosed is a method and system to maintain the soft and sparse slag characteristic favorable for an electric arc to efficiently transfer the energy to molten iron with the power input per furnace area higher than 600 KW/m2 while keeping FeO amount less than 5% in the slag and carbon amount higher than 2.5% in the product hot metal at a DRI melting furnace.

A method for operating a blast furnace for producing of pig iron, includes the following steps heating a first stream of steam in a first heater, before or after having been mixed with an oxygen source selected from oxygen and oxygen-enriched air, to provide a first heated stream of oxygen-enriched steam; heating a first stream of blast furnace gas from the blast furnace and a first stream of natural gas in a second heater, before or after being mixed together, to provide a heated carbon feed stream; feeding the first heated stream of oxygen-enriched steam and the heated carbon feed stream either as a combined stream or separately to a catalytic partial oxidation reactor to produce a stream of syngas; and feeding the stream of syngas to the shaft of the blast furnace.

A cooperative emission reduction method for sintering using an energy-carrying composite gas is disclosed. A surface of a sintered material is divided into an ignition section, a heat preservation section, a middle section, a flue gas heating section, and a machine tail section from a machine head to a machine tail of a sintering machine; according to flue gas components, temperature characteristics, and heat requirements of different sections, a hot exhaust gas is introduced to the ignition section for ignition, a hot exhaust gas is introduced to the heat preservation section and a hydrogen-rich gas is cascadingly sprayed synchronously, cascaded spraying of water vapor is coupled based on spraying of a hydrogen-rich gas in the middle section, and the high-temperature flue gas in the machine tail section and the flue gas in the ignition section and/or the heat preservation section are circulated to the heating section.

A method of direct reduction of iron (DRI) is disclosed, the method comprising generating metallic iron by removing oxygen from iron ore using a reducing gaseous mixture with excess carbon monoxide that produces an excess CO.sub.2 by-product is provided. CO.sub.2 by-product is optionally sequestered. A system for carrying out the method is also disclosed.

Provided herein are novel devices, systems, and methods of using the same, that enable plasma-enhanced gasification of biogenic hydrocarbon waste material comprising: a geometrically designed reactor having a biochar carbon catalyst bed, together with a gas inlet system disposed around a lower section of the apparatus to supply oxidant gas generated by an integrated oxygen absorber system; to enhance the partial oxidation of biogenic hydrocarbon waste materials using exothermic heat generated by an oxidation reaction created in part by the integrated oxygen absorber system into the apparatus, in order to optimize the quantity and quality of hydrogen production in the synthetic gas produced therein.

The invention relates to a process for producing carburized directly reduced iron sponge from iron oxide material. Firstly, direct reduction is carried out by means of a reduction gas consisting at least predominantly of H.sub.2 and the carbon content in the iron sponge is then increased by means of a carburizing gas which is fed in, after which used carburizing gas is at least partly taken off while largely avoiding mixing with the reduction gas. The plant for producing carburized directly reduced iron sponge from iron oxide material comprises a reduction zone for directly reducing introduced iron oxide material to directly reduced product by means of reduction gas consisting predominantly of H.sub.2 and a reduction gas feed conduit opening into the reduction zone. It also comprises a carburization zone having a carburizing gas feed conduit opening into the carburization zone and a carburization offgas conduit.