Herein discussed is a method of producing hydrogen comprising introducing a metal smelter effluent gas or a basic oxygen furnace (BOF) effluent gas or a mixture thereof into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane. In an embodiment, the method comprises introducing steam into the EC reactor on one side of the membrane, wherein the effluent gas is on the opposite side of the membrane, wherein the effluent gas and the steam are separated by the membrane and do not come in contact with each other.

Described is a device for recovering heat and fumes from slag resulting from the steel production cycle which allows the heat emitted by the slag during the cooling to be used without the need to collect the slag in tubs which must then be transported to the cooling surface and tipped in order to discharge the slag; at the same time, this device allows the fumes and consequently the heat and the pollutants which the slag emits during the tipping and the time on the cooling surface to be conveyed and treated.

Described is a device for recovering heat and fumes from slag resulting from the steel production cycle which allows the heat emitted by the slag during the cooling to be used without the need to collect the slag in tubs which must then be transported to the cooling surface and tipped in order to discharge the slag; at the same time, this device allows the fumes and consequently the heat and the pollutants which the slag emits during the tipping and the time on the cooling surface to be conveyed and treated.

A thermally efficiency regenerative air preheater 250 extracts more thermal energy from the flue gas exiting a solid fuel fired furnace 26 by employing an alkaline injection system 276. This mitigates acid fouling by selectively injecting different sized alkaline particles 275 into the air preheater 250. Small particles provide nucleation sites for condensation and neutralization of acid vapors. Large particles are injected to contact and selectively adhere to the heat exchange elements 542 and neutralize liquid acid that condenses there. When the deposit accumulation exceeds a threshold, the apparatus generates and utilizes a higher relative percentage of large particles. Similarly, a larger relative percentage of small particles are used in other cases. Mitigation of the fouling conditions permits the redesign of the air preheater 250 to achieve the transfer of more heat from the flue resulting in a lower flue gas outlet temperature without excessive fouling.

A thermally efficiency regenerative air preheater 250 extracts more thermal energy from the flue gas exiting a solid fuel fired furnace 26 by employing an alkaline injection system 276. This mitigates acid fouling by selectively injecting different sized alkaline particles 275 into the air preheater 250. Small particles provide nucleation sites for condensation and neutralization of acid vapors. Large particles are injected to contact and selectively adhere to the heat exchange elements 542 and neutralize liquid acid that condenses there. When the deposit accumulation exceeds a threshold, the apparatus generates and utilizes a higher relative percentage of large particles. Similarly, a larger relative percentage of small particles are used in other cases. Mitigation of the fouling conditions permits the redesign of the air preheater 250 to achieve the transfer of more heat from the flue resulting in a lower flue gas outlet temperature without excessive fouling.

A method for recycling processing of dust generated in a converter furnace, includes: crushing and drying a cake formed by adding a binder to a slurry containing iron powder-containing dust that is generated at the time of converter blowing and wet-collected to produce a mixed slurry and subjecting the produced mixed slurry to a dehydration treatment in a filter press; accumulating the cake in an accumulation tank; and charging the cake into a converter furnace 10, the crushed product in the accumulation tank 25 is kept at a temperature of less than 90 C. by forcibly passing air into the accumulation tank 25 and charged into a converter furnace according to the converter operation.

A method for recycling processing of dust generated in a converter furnace, includes: crushing and drying a cake formed by adding a binder to a slurry containing iron powder-containing dust that is generated at the time of converter blowing and wet-collected to produce a mixed slurry and subjecting the produced mixed slurry to a dehydration treatment in a filter press; accumulating the cake in an accumulation tank; and charging the cake into a converter furnace 10, the crushed product in the accumulation tank 25 is kept at a temperature of less than 90 C. by forcibly passing air into the accumulation tank 25 and charged into a converter furnace according to the converter operation.

A method for venting a spray-cooled roof of a ladle metallurgical furnace is provided herein. The method begins by processing molten metal materials in a ladle metallurgical furnace having a spray-cooled roof with an opening configured for one or more electrodes to pass there through and an integrated hood. Process gases and fumes are extracted through a channel having walls disposed within an enclosed space of the spray-cooled roof. The walls of the channel are cooled with a spray-cool system extends between the walls of the channel and a top of the spray-cooled roof.

A method for venting a spray-cooled roof of a ladle metallurgical furnace is provided herein. The method begins by processing molten metal materials in a ladle metallurgical furnace having a spray-cooled roof with an opening configured for one or more electrodes to pass there through and an integrated hood. Process gases and fumes are extracted through a channel having walls disposed within an enclosed space of the spray-cooled roof. The walls of the channel are cooled with a spray-cool system extends between the walls of the channel and a top of the spray-cooled roof.

Provided are a joint regulation method of material flow, energy flow, and carbon emission flow in a long-process steel enterprise, which belongs to a field of intelligent regulation and control technology of electric power system in the steel industry. The method includes: coupling a material-energy characteristic model of each production process of a steel enterprise and a carbon emission model of the steel enterprise, constructing a material flow-energy flow-carbon emission flow coupling model of the long-process steel enterprise, establishing an objective function using a minimize sum of an electricity purchase cost from a superior grid, a park carbon emission cost, and a production raw material cost as an object, and solving and obtaining an optimal operation mode of a joint regulation of the material flow-energy flow-carbon emission flow in the steel enterprise.