Process to decarburize steel are described. A process can include contacting carbon dioxide with molten steel in an electric arc furnace, a ladle furnace, or a vacuum degassing unit, or a combination thereof.

Disclosed is a slag discharging method in a process of producing ultra-low phosphorus steel, which relates to the technical field of iron and steel smelting, and in which molten steel is mixed with lime first to produce basic slag; then converting is performed with oxygen to increase the oxidizability of the basic slag; and a carbon-containing reducing agent is finally added, so that in the process that the carbon is oxidized to release a large amount of carbon monoxide gas, phosphates are captured, and the basic slag is rapidly foamed and overflows from the opening of the steel ladle, so that conditions are no longer available for rephosphorization. Also disclosed is a method for producing ultra-low phosphorus steel, which includes the above-described slag discharging method in a process of producing ultra-low phosphorus steel, and refining and ingotting after slag discharge.

Disclosed is a slag discharging method in a process of producing ultra-low phosphorus steel, which relates to the technical field of iron and steel smelting, and in which molten steel is mixed with lime first to produce basic slag; then converting is performed with oxygen to increase the oxidizability of the basic slag; and a carbon-containing reducing agent is finally added, so that in the process that the carbon is oxidized to release a large amount of carbon monoxide gas, phosphates are captured, and the basic slag is rapidly foamed and overflows from the opening of the steel ladle, so that conditions are no longer available for rephosphorization. Also disclosed is a method for producing ultra-low phosphorus steel, which includes the above-described slag discharging method in a process of producing ultra-low phosphorus steel, and refining and ingotting after slag discharge.

Disclosed is a method for smelting low nitrogen steel by using an electric furnace. The smelting is performed using a dual-shell electric furnace, The dual-shell electric furnace has two furnace shells. An arc power system of the dual-shell electric furnace is used for alternatively electric heating on the two furnace shells, wherein when one of the two furnace shells is subjected to electric heating, feeding, sealing of a molten pool and blowing of a combustion medium and oxygen are sequentially carried out in the other furnace shell to start smelting. When the temperature of molten steel in the furnace shell subjected to electric heating reaches a target temperature, electric heating starts to be carried out on the other furnace shell. The method for efficiently smelting the low nitrogen steel by using the electric furnace of the disclosure, not only can shorten the smelting period and improve the throughput of a production line of an electric furnace, but also smelt low nitrogen steel to satisfy the requirements of the market on high-end steel. in addition, the method for efficiently smelting the low nitrogen steel by using the electric furnace of the disclosure can reduce the discharge of dust and smoke, thereby protecting the environment.

Disclosed is a method for smelting low nitrogen steel by using an electric furnace. The smelting is performed using a dual-shell electric furnace, The dual-shell electric furnace has two furnace shells. An arc power system of the dual-shell electric furnace is used for alternatively electric heating on the two furnace shells, wherein when one of the two furnace shells is subjected to electric heating, feeding, sealing of a molten pool and blowing of a combustion medium and oxygen are sequentially carried out in the other furnace shell to start smelting. When the temperature of molten steel in the furnace shell subjected to electric heating reaches a target temperature, electric heating starts to be carried out on the other furnace shell. The method for efficiently smelting the low nitrogen steel by using the electric furnace of the disclosure, not only can shorten the smelting period and improve the throughput of a production line of an electric furnace, but also smelt low nitrogen steel to satisfy the requirements of the market on high-end steel. in addition, the method for efficiently smelting the low nitrogen steel by using the electric furnace of the disclosure can reduce the discharge of dust and smoke, thereby protecting the environment.

A gas injection nozzle refractory with one or more gas injection small metal tubes buried therein has improved durability. The gas injection nozzle refractory includes a MgO-C central refractory with a small metal tube buried therein, and a MgO-C peripheral refractory surrounding the central refractory. The central refractory on a plane of the gas injection nozzle refractory has an external shape of a circle with a radius in the range of R+10 to R+150 mm concentric with a virtual circle with a minimum radius surrounding all buried small metal tubes, R mm being a radius of the virtual circle.

A socket installation structure of a refractory article is designed to prevent gas leakage therein. A first flange is provided between an outward end and an inward end of a socket, and a face of the first flange on the side of an inward end thereof is bonded to an article body of the refractory article through a sealing material. Further, a face of the first flange on the side of an outward end thereof faces a metal plate disposed around the outward end or a second flange provided on the side of the outward end, through a low thermally-conductive material layer made of a low thermally-conductive material having a thermal conductivity at room temperature of 40 (W/(m.Math.K)) or less.

The invention relates to a process for producing low-nitrogen crude steel. This process includes melting directly reduced iron and/or scrap in a melting furnace with arc resistance heating to give a metallic melt and a slag. The metallic melt is removed from the melting furnace and used to charge a converter. The metallic melt is refined in the converter to give liquid crude steel. The liquid crude steel is tapped having a nitrogen content [N] of not more than 50 ppm, especially of not more than 30 ppm.

The present disclosure provides a method of making non-grain oriented (NGO) electrical steel. The method includes tapping the liquid steel out of a primary steelmaking furnace. Deoxidizing the liquid steel before or after transferring the deoxidized liquid steel to a ladle metallurgy furnace. Removing sulfur at the ladle metallurgy furnace (LMF). Adding fluxes and deoxidizer to the ladle slag and/or skimming off ladle slag to prevent sulfur reversion. Transferring the liquid steel from the ladle metallurgy furnace to an RH degasser for carbon removal by blowing oxygen. Adding fluxes at the RH before oxygen blowing to fortify the bottom layer of the ladle slag to prevent sulfur reversion. The removal of oxygen and sulfur prior to transferring the liquid steel to the RH degasser facilitates nitrogen removal and prevents carbon pick up during the step of adding fluxes and arcing for sulfur removal if sulfur removal is carried out at the LMF after carbon removal at the RH degasser in the conventional process. Oxygen blowing at the RH also lowered the titanium pickup from the earlier desulfurization process. The ultra low levels of carbon, nitrogen, sulfur, and titanium in the NGO steel made using this method enabled the excellent magnetic properties achieved in the finishing NGO products.

Fe—Ni—Cr alloy contains, in mass, from 0.001% to 0.050% of C, from 0.18% to 1.00% of Si, from 0.20% to 0.80% of Mn, 0.030% or less of P, 0.0001% to 0.0020% of S, from 12% to 21% of Ni, from 18% to 24% of Cr, from 0.20% to 1.50% of Mo, 0.30% or less of Cu, from 0.10% to 0.70% of Al, from 0.10% to 0.70% of Ti, from 0.002% to 0.015% of N, from 0.0001% to 0.0010% of B, from 0.0002% to 0.0030% of O, 0.002% or less of Ca, and from 0.0010% to 0.0150% of REM in total, said REM being composed of one or more elements selected from among La, Ce and Y, with the balance being made up of Fe and unavoidable impurities, and which satisfies formulae 1 and 2. Formula 1: 0.575xNi+1.25xCr+3.43xMo-39xP-5.3xAl-641xREM-1018xO≥20.0 Formula 2: 1.5xMn+41.3xSi+1469xS-1.67xAl-1.34xTi-150xO-620xREM≥5.0.