Grain-oriented electrical steel sheet excellent in magnetic properties and excellent in adhesion of a primary coating to the steel sheet is provided. The grain-oriented electrical steel sheet is provided with a base steel sheet having a chemical composition containing C: 0.005% or less, Si: 2.5 to 4.5%, Mn: 0.050 to 1.000%, a total of S and Se: 0.005% or less, sol. Al: 0.005% or less, and N: 0.005% or less and having a balance of Fe and impurities and a primary coating having Mg.sub.2 SiO.sub.4 as a main constituent formed on a surface of the base steel sheet. A peak position of Al emission intensity obtained when conducting elemental analysis by glow discharge spectrometry from a surface of the primary coating in a thickness direction is present in a range of 2.0 to 12.0 .Math.m from a surface of the primary coating to the thickness direction. A sum of perimeters of the Al oxides at the peak position of Al emission intensity is 0.20 to 1.00 .Math.m/.Math.m.sup.2, and a number density of Al oxides is 0.02 to 0.20 /.Math.m.sup.2.

The stainless steel contains 0.0001 mass % or more and 0.15 mass % or less of C, 0.30 mass % or more and 2.0 mass % or less of Si, 0.1 mass % or more and 15 mass % or less of Mn, 5 mass % or more and 30 mass % or less of Ni, 0.0001 mass % or more and 0.01 mass % or less of S, 16 mass % or more and 25 mass % or less of Cr, 0 mass % or more and 5 mass % or less of Mo, 0 mass % or more and 0.005 mass % or less of Al, 0 mass % or more and 0.0010 mass % or less of Mg, 0.0010 mass % or more and 0.0060 mass % or less of 0, and 0.0001 mass % or more and 0.5 mass % or less of N, and at least includes an inclusion with an equivalent circle diameter of 5 μm or more, having the average composition of 5 mass % or more of MnO, 20 mass % or more of Cr.sub.2O.sub.3+Al.sub.2O.sub.3, 1 mass % or more of Al.sub.2O.sub.3, and 5 mass % or less of Ca0. The number density of the inclusion having the composition is 0.5 inclusions/mm.sup.2 or less.

The stainless steel contains 0.0001 mass % or more and 0.15 mass % or less of C, 0.30 mass % or more and 2.0 mass % or less of Si, 0.1 mass % or more and 15 mass % or less of Mn, 5 mass % or more and 30 mass % or less of Ni, 0.0001 mass % or more and 0.01 mass % or less of S, 16 mass % or more and 25 mass % or less of Cr, 0 mass % or more and 5 mass % or less of Mo, 0 mass % or more and 0.005 mass % or less of Al, 0 mass % or more and 0.0010 mass % or less of Mg, 0.0010 mass % or more and 0.0060 mass % or less of 0, and 0.0001 mass % or more and 0.5 mass % or less of N, and at least includes an inclusion with an equivalent circle diameter of 5 μm or more, having the average composition of 5 mass % or more of MnO, 20 mass % or more of Cr.sub.2O.sub.3+Al.sub.2O.sub.3, 1 mass % or more of Al.sub.2O.sub.3, and 5 mass % or less of Ca0. The number density of the inclusion having the composition is 0.5 inclusions/mm.sup.2 or less.

A grain oriented electrical steel sheet includes: a base steel sheet; a glass film which is arranged in contact with the base steel sheet; and an insulation coating which is arranged in contact with the glass film and which includes a phosphate and a colloidal silica as main components. The base steel sheet includes the predetermined chemical composition. A BN whose average particle size is 50 to 300 nm is included at a predetermined number density in a region which is from an interface between the glass film and the insulation coating till 5 μm toward the base steel sheet in a depth direction. A B emission intensity obtained inside the glass film is more than a B emission intensity obtained inside the base steel sheet, when a B emission intensity is measured from a surface of the insulation coating by a glow discharge emission spectroscopy.

A grain oriented electrical steel sheet includes: a base steel sheet; a glass film which is arranged in contact with the base steel sheet; and an insulation coating which is arranged in contact with the glass film and which includes a phosphate and a colloidal silica as main components. The base steel sheet includes the predetermined chemical composition. A BN whose average particle size is 50 to 300 nm is included at a predetermined number density in a region which is from an interface between the glass film and the insulation coating till 5 μm toward the base steel sheet in a depth direction. A B emission intensity obtained inside the glass film is more than a B emission intensity obtained inside the base steel sheet, when a B emission intensity is measured from a surface of the insulation coating by a glow discharge emission spectroscopy.

Disclosed is a grain-oriented electrical steel sheet capable of obtaining excellent magnetic properties stably over the entire coil length. A grain-oriented electrical steel sheet includes: a chemical composition containing, in mass %, C: 0.005% or less, Si: 2.0% to 4.5%, and Mn: 0.01% to 0.5%, and, in mass ppm, N: 20 ppm or less, each of Se, Te, and O: less than 50 ppm, S: less than 30 ppm, and acid-soluble Al: less than 40 ppm, and Ti: less than 30 ppm, of which 5 ppm or more and 25 ppm or less is acid-soluble Ti, with the balance being Fe and inevitable impurities; and precipitates containing Ti and N with a grain size of 200 nm or more at a frequency of 0.05 grains/mm.sup.2 or more.

A grain oriented electrical steel sheet includes the texture aligned with Goss orientation. In the grain oriented electrical steel sheet, when a grain size RAα.sub.L, a grain size RAβ.sub.L, and a grain size RAγ.sub.L are defined in a rolling direction L, the grain sizes satisfy RAβ.sub.L<RAα.sub.L and RAγ.sub.L<RAα.sub.L.

A grain-oriented electrical steel sheet according to the present invention has a steel sheet surface provided with grooves and includes two or more broken lines including the grooves having a length of 5 to 10 mm on a straight line intersecting a rolling direction on the steel sheet surface. In each of the broken lines including the grooves, the grooves are arranged at equal intervals, and a ratio of the length of the groove to a length of a non-groove is in a range of 1:1 to 1.5:1.

A process for making full dense components of a carbon-containing steel, comprises the steps of: a) making a powder of the carbon-containing steel by gas atomization wherein the carbon content is low, less than 0.15 wt %, b) agglomerating the powder from step a) with at least one hydrocolloid and elemental carbon, c) compacting the agglomerated powder from step b) to a density of at least 80% of theoretical density, with the proviso that the compacted agglomerated powder still is porous allowing transport of gas to and from its interior, and d) sintering the compacted powder to a density of more than 98% of theoretical density, preferably more than 99% of theoretical density, wherein a gas comprising carbon is added during sintering and finally subjecting the component to HVC. Advantages include that it is possible to manufacture a dense component of powders which otherwise are difficult to compact.

A process for making full dense components of a carbon-containing steel, comprises the steps of: a) making a powder of the carbon-containing steel by gas atomization wherein the carbon content is low, less than 0.15 wt %, b) agglomerating the powder from step a) with at least one hydrocolloid and elemental carbon, c) compacting the agglomerated powder from step b) to a density of at least 80% of theoretical density, with the proviso that the compacted agglomerated powder still is porous allowing transport of gas to and from its interior, and d) sintering the compacted powder to a density of more than 98% of theoretical density, preferably more than 99% of theoretical density, wherein a gas comprising carbon is added during sintering and finally subjecting the component to HVC. Advantages include that it is possible to manufacture a dense component of powders which otherwise are difficult to compact.