Patent classifications
C21D8/0205
Cold-rolled steel sheet having excellent high-temperature properties and room-temperature workability
The present disclosure provides a cold-rolled steel sheet having excellent high-temperature properties and room-temperature workability, including, by weight: carbon (C): 0.0005 to 0.003%, manganese (Mn): 0.20 to 0.50%, aluminum (Al): 0.01 to 0.10%, phosphorus (P): 0.003 to 0.020%, nitrogen (N): 0.0005 to 0.004%, sulfur (S): 0.015% or less, niobium (Nb): 0.005 to 0.040%, chromium (Cr): 0.10 to 0.50%, tungsten (W): 0.02 to 0.07%, and a balance of iron (Fe) and other inevitable impurities, wherein C, Nb, and W satisfy the following relationship 1, a microstructure comprises 95 area % or more of polygonal ferrite and 5 area % or less of acicular ferrite, and the cold-rolled steel sheet comprises (Nb,W)C-based precipitates having an average size of 0.005 to 0.10 μm and a method for manufacturing the same:
0.00025≤(2×Nb/93)×(W/184)/(C/12)≤0.0015 [Relationship 1]
where, C, Nb, and W are in weight %.
Nickel-containing steel for low temperature
A Ni steel has a chemical composition within a predetermined range, in which a metallographic structure of a thickness middle portion contains 2.0 vol % to 20.0 vol % of an austenite phase, an average grain size of prior austenite grains is 3.0 μm to 12.0 μm, an average aspect ratio of the prior austenite grains is 2.6 to 10.0, a plate thickness is 4.5 mm to 20 mm, a yield stress at room temperature is 590 MPa to 710 MPa, and a tensile strength at the room temperature is 690 MPa to 810 MPa, when the plate thickness is more than 16 mm, the Ni steel contains Ni: 11.5% or more, and when the plate thickness is 16 mm or less and the Ni steel contains Ni: less than 11.5%, the average grain size of the prior austenite grains is 6.0 μm or less.
Steel for pressure vessels having excellent resistance to hydrogen induced cracking and manufacturing method thereof
The present disclosure relates to a steel for pressure vessels used in a hydrogen sulfide atmosphere, and relates to a steel material for pressure vessels having excellent resistance to hydrogen induced cracking (HIC) and a manufacturing method thereof.
Ultrahigh-strength hot-rolled steel sheet and steel strip having good fatigue and reaming properties and manufacturing method therefor
An ultra-high-strength hot-rolled steel plate and steel strip having good fatigue and reaming properties and a manufacturing method therefor. The weight percentages of the components of the steel plate and the steel strip are: C: 0.07-0.14%, Si: 0.1-0.4%, Mn: 1.55-2.00%, P≤0.015%, S≤0.004%, Al: 0.01-0.05%, N≤0.005%, Cr: 0.15-0.50%, V: 0.1-0.35%, Nb: 0.01%-0.06%, Mo: 0.15-0.50%, Ti≤0.02%, and the balance of Fe and unavoidable impurities. Such components need to meet: 1.0≤[(Cr/52)/(C/4)+(Nb/93+Ti/48+V/51+Mo/96)/(C/12)]≤1.6. The tensile strength of the ultrahigh-strength hot-rolled steel plate and steel strip is ≥780 MPa, the yield strength thereof is ≥660 MPa, the tensile fatigue limit (10 million cycles) FL thereof is ≥570 MPa, or the fatigue limit to tensile strength FL/Rm thereof is ≥0.72. The reaming rate meets: if an original hole is a punched hole, the reaming rate thereof is >85%; and if the original hole is a reamed hole, the reaming rate thereof is >120%.
Production method for high-strength steel sheet
A production method for a high-strength steel sheet having a tensile strength TS of 780 MPa or more is provided. The production method comprises: heating a steel slab having a predetermined chemical composition; hotrolling the steel slab; coiling the hot-rolled sheet; subjecting the hot-rolled sheet to pickling treatment; holding the hot-rolled sheet in a pre-determined temperature range for predetermined time; cold rolling the hot-rolled sheet to obtain a cold-rolled sheet; subjecting the cold-rolled sheet to first annealing treatment; cooling the cold-rolled sheet at a pre-determined average cooling rate; cooling the cold-rolled sheet to room temperature; reheating the clod-rolled sheet to perform second annealing treatment; cooling the cold-rolled sheet at a first average cooling rate; cooling the cold-rolled sheet at a second average cooling rate; reheating the cold-rolled sheet to a predetermined reheating temperature range; and holding the cold-rolled sheet in the reheating temperature range.
High-strength high-toughness hot-rolled steel sheet and manufacturing method therefor
A preferable aspect of the present invention provides a high-strength high-toughness hot-rolled steel sheet and a manufacturing method therefor, wherein the hot-rolled steel sheet contains, by weight, 0.07-0.13% C, 0.20-0.50% Si, 0.5-0.9% Mn, 0.03% or less P, 0.02% or less S, 0.005-0.03% Nb, 0.3-0.6% Cr, 0.005-0.03% Ti, 0.1-0.35% Cu, 0.05-0.3% Ni, 0.01-0.15% Mo, 0.007% or less N, 0.001-0.006% Ca, 0.01-0.05% Al, and the balance Fe and other unavoidable impurities, the alloy elements satisfying the following relational formulas [Relational formula 1] 1.6≤(Mo/96)/(P/31)≤6, [Relational formula 2] 1.6≤(Ca/S)≤3, and [Relational formula 3] 3.5≤(3*C/12+Mn/55)*100≤5; wherein a microstructure comprises, by area fraction, 85% or more of polygonal ferrite and 15% or less of pearlite, the crystal grain size of the polygonal ferrite being 10 μm or less; and wherein a variation in yield strength in a width direction is 35 MPa or lower.
HOT-STAMPING FORMED BODY
A hot-stamping formed body has a predetermined chemical composition and includes microstructure which includes residual austenite of which an area ratio is in a range of 20% to 30%. Among grain boundaries of crystal grains of bainite and tempered martensite in the microstructure, a ratio of a length of a grain boundary having a rotation angle in a range of 55° to 75° to a total length of a grain boundary having a rotation angle in a range of 4° to 12°, a grain boundary having a rotation angle in a range of 49° to 54°, and a grain boundary having a rotation angle in a range of 55° to 75° to the <011> direction as a rotation axis is 30% or more.
STEEL SHEET FOR CAN AND MANUFACTURING METHOD THEREOF
This steel sheet for a can is a steel sheet for a can containing, by mass %, C: 0.010% to 0.050%, Si: 0.020% or less, Mn: 0.10% to 0.60%, P: 0.020% or less, S: 0.020% or less, Al: 0.050% or less, N: 0.0100% or less, Nb: 0% to 0.03%, Ti: 0% to 0.03%, B: 0% to 0.0020%, and a remainder including Fe and an impurity, in which, when the number of carbides having an equivalent circle diameter of 2 μm or more and 5 μm or less is indicated by a, and the number of carbides having an equivalent circle diameter of 0.1 μm or more and less than 2 μm is indicated by b, a/b satisfies a range of the following formula (1), a fracture strain is 1.6 or more, and a sheet thickness is 0.10 to 0.30 mm.
a/b<0.12 (1)
HOT-ROLLED STEEL SHEET AND METHOD FOR MANUFACTURING SAME
A hot-rolled steel sheet has, as a chemical composition, by mass %: C: 0.01% to 0.30%; Si: 0.01% to 3.00%; Mn: 0.20% to 3.00%; P: 0.030% or less; S: 0.030% or less; Al: 0.001% to 2.000%; N: 0.0100% or less; and Ni: 0.02% to 0.50%, in which among measurement points at which elemental analysis is performed at a measurement pitch of 1 μm using an EPMA in a region of 250 μm×250 μm on a surface, the percentage of measurement points having a Ni content of 0.5 mass % or more is 10% to 70%.
STEEL SHEET AND METHOD OF MANUFACTURING THE SAME
A steel sheet includes a predetermined composition, in which a microstructure at a ¼ thickness position from a surface in a sheet thickness direction includes, by vol %, ferrite: 80% or more, martensite: 2% or less, and residual austenite: 2% or less, a proportion of unrecrystallized ferrite in the ferrite of 5% or less, and in the microstructure of the steel sheet stretched by 10% at the ¼ thickness position from the surface in the sheet thickness direction, a number density of voids having a maximum diameter of 1.0 μm or more is 1.0×10.sup.9 pieces/m.sup.2 or less.