Provided are a high-carbon steel sheet having good surface quality and a manufacturing method therefor. The present invention provides a high-carbon pickled steel sheet having good surface quality, the steel sheet containing, in weight %, 0.4% or more and less than 1.2% of carbon (C), 0.5% or less (excluding 0%) of silicon (Si), 0.05% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.1 to 2.5% of at least one of manganese (Mn) and chromium (Cr), and the balance of iron (Fe) and inevitable impurities, wherein the average thickness of an internal oxide layer and/or a decarburized layer formed in a surface layer portion of the steel sheet is 1 to 10 μm and the standard deviation of the thickness of the internal oxide layer and/or the decarburized layer in the length direction of the steel sheet is 2 μm or less.

The present invention provides steel sheet having both bendability and hydrogen embrittlement resistance. The steel sheet of the present invention includes a central part of sheet thickness and a surface sort part formed at one side or both sides of the central part of sheet thickness. The microstructure of the central part of sheet thickness comprises, by volume ratio, 60% or more of tempered martensite, respectively less than 30% of ferrite, bainite, pearlite, and retained austenite, and less than 5% of as-quenched martensite. A thickness of the surface soft part is more than 10 μm per side and 15% or less of a thickness of the central part of sheet thickness, an average hardness of the surface soft part is 0.90 time or less of an average hardness of the central part of sheet thickness, the surface soft part includes carbides in a number density of 1×10.sup.4/mm.sup.2 or more, an average particle size of the carbides is 0.250 μm or less, and a standard deviation of a log of a particle size is 0.05 or less.

A hot-dip zinc-plated steel sheet includes a steel sheet, a boundary layer that is provided on a surface of the steel sheet, and a hot-dip zinc-plated layer that is provided on a surface of the boundary layer. In a surface layer region of the steel sheet, an average grain size is 4.0 μm or less and a standard deviation of grain sizes is 2.0 μm or less. In the boundary layer, a maximum Al concentration is 0.30 mass % or more.

This steel sheet for hot stamping includes a base material, an Al-Si alloy plating layer in which the Al content is 75 mass% or more, the Si content is 3 mass% or more and the total of the Al content and the Si content is 95 mass% or more and a Ni plating layer in which the Ni content is more than 90 mass% in this order, the chemical composition of the base material is, by mass%, C: 0.01% or more and less than 0.70%, Si: 0.005% to 1.000%, Mn: 0.40% to 3.00%, Nb: 0.010% to 0.200%, a solid solution of Nb: 0.010% to 0.150%, sol. A1: 0.00020% to 0.50000%, P: 0.100% or less, S: 0.1000% or less, N: 0.0100% or less, Cu: 0% to 1.00%, Ni: 0% to 1.00%, V: 0% to 1.00%, Ti: 0% to 0.150%, Mo: 0% to 1.000%, Cr: 0% to 1.000%, B: 0% to 0.0100%, Ca: 0% to 0.010%. REM: 0% to 0.300%, and a remainder: Fe and an impurity, the Al-Si alloy plating layer has a thickness of 7 to 148 .Math.m, and the Ni plating layer has a thickness of more than 200 nm and 2500 nm or less.

A heat treated cold rolled steel sheet having a composition comprising of the following elements, 0.1%≤Carbon≤0.25, 2.15%≤Manganese≤3.0%, 1%≤Silicon≤0.8%, 0.1%≤Aluminum≤0.9%, 0.05%≤Chromium≤0.5%, 0%≤, Phosphorus≤0.09%, 0%≤Sulfur≤0.09%, 0%≤Nitrogen≤0.09%, 2.4%≤C+Mn≤3%, 0%≤Niobium≤0.1%, 0% ≤Titanium≤0.1%, 0%≤Vanadium≤0.1%, 0%≤Molybdenum≤1%, 0%≤Nickel≤1%, 0%≤Calcium≤0.005%, 0%≤Boron≤0.01%, 0%≤Cerium≤0.1%, 0%≤Magnesium≤0.05%, 0%≤Zirconium≤0.05% the remainder being composed of iron and unavoidable impurities, the microstructure of said steel sheet including, 20% to 70% Martensite, 5 to 60% of Inter-critical Ferrite, 5 to 30% of Transformed Ferrite, 8% to 20% of Residual Austenite and 1 to 20% Bainite, wherein the cumulated amount of Inter-critical and Transformed Ferrite is between 15% and 65%.

Disclosed in the present invention is complex-phase steel having high hole expansibility. The complex-phase steel has a microstructure of ferrite and bainite. The complex-phase steel having high hole expansibility comprises the following chemical elements in percentage by mass: C: 0.06-0.09%, Si: 0.05-0.5%, Al: 0.02-0.1%, Mn: 1.5-1.8%, Cr: 0.3-0.6%, Nb≤0.03%, Ti: 0.05-0.12%, and the balance of Fe and inevitable impurities. In addition, also disclosed in the present invention is a manufacturing method for the foregoing complex-phase steel having high hole expansibility. The method comprises the following steps: (1) smelting and casting; (2) heating; (3) hot-rolling; (4) phosphorous removal; (5) laminar cooling: a relaxation time period is controlled to be 0-8 s, and a laminar cooling rate is 40-70° C./s; (6) coiling; (7) leveling; and (8) pickling. The complex-phase steel having high hole expansibility can simultaneously satisfy the requirements for hole expansibility and good plasticity.

This austenitic stainless steel contains, in terms of % by mass: C: 0.100% or less, Si: 3.00% or less, Mn: 0.01% or more and 5.00% or less, P: 0.100% or less, S: 0.0050% or less, Ni: 7.00% or more and 38.00% or less, Cr: 17.00% or more and 28.00% or less, Mo: 10.00% or less, and N: more than 0.100% and 0.400% or less, with a remainder being Fe and impurities, and a brightness difference ΔL of a surface of a stainless steel is 5 or less.

A steel sheet having a tensile strength (TS) of 1180 MPa or more, high LME resistance, and good weld fatigue properties. The steel sheet has a specific chemical composition and a specific steel microstructure. Crystal grains containing an oxide of Si and/or Mn in a region within 4.9 μm in a thickness direction from a surface of the steel sheet have an average grain size in the range of 3 to 10 μm, the lowest Si concentration L.sub.Si and the lowest Mn concentration L.sub.Mn in the region within 4.9 μm in the thickness direction from the surface of the steel sheet and a Si concentration T.sub.Si and a Mn concentration T.sub.Mn at a quarter thickness position of the steel sheet satisfy a specified formula.

Disclosed is a stainless steel having excellent surface electrical conductivity for a fuel cell separator. According to an embodiment of the disclosed stainless steel having excellent surface electrical conductivity for a fuel cell separator, a value of the following surface oxide atomic ratio (1) may be 0.08 or more, as measured on the surface of a stainless steel containing 15 wt % or more of Cr by X-ray angle-resolved photoemission spectroscopy using an Al-Kα X-ray source under the condition where a take-off angle of photoelectrons is from 12° to 85°.

[00001]$\begin{array}{cc}\frac{\mathrm{sum}\mathrm{of}\mathrm{atomic}\mathrm{concentrations}\left(\mathrm{at}\%\right)\mathrm{of}\mathrm{Cr}\mathrm{in}\mathrm{Cr}\mathrm{hydroxide}}{\begin{array}{c}\mathrm{sum}\mathrm{of}\mathrm{atomic}\mathrm{concentrations}\left(\mathrm{at}\%\right)\mathrm{of}\mathrm{metal}\mathrm{elements}\\ \mathrm{in}\mathrm{total}\mathrm{oxides}\mathrm{and}\mathrm{hydroxides}\end{array}}& \left(1\right)\end{array}$

The Cr hydroxide represents CrOOH, Cr(OH).sub.2, or Cr(OH).sub.3. The total oxides and hydroxides include a Cr oxide, the Cr hydroxide, an Fe oxide, an Fe hydroxide, and a metal oxide (MO), and the metal oxide (MO) includes a mixed oxide, wherein M represents an alloying element other than Cr and Fe or a combination thereof in a matrix, and O represents oxygen.

A steel sheet for the manufacture of a press hardened part is provided, having a composition of: 0.15%≤C≤0.22%, 3.5%≤Mn<4.2%, 0.001%≤Si≤1.5%, 0.020%≤Al≤0.9%, 0.001%≤Cr≤1%, 0.001%≤Mo≤0.3%, 0.001%≤Ti≤0.040%, 0.0003%≤B≤0.004%, 0.001%≤Nb≤0.060%, 0.001%≤N≤0.009%, 0.0005%≤S≤0.003%, 0.001%≤P≤0.020%. A microstructure has less than 50% ferrite, 1% to 20% retained austenite, cementite, such that the surface density of cementite particles larger than 60 nm is lower than 10{circumflex over ( )}7/mm.sup.2, and a complement of bainite and/or martensite, the retained austenite having an average Mn content of at least 1.1*Mn %. Press-hardened steel part obtained by hot forming the steel sheet, and manufacturing methods thereof.