Described are solid agglomerates of fine metal particles and methods for manufacturing same. A liquid oily lubricant is used in the manufacture of the solid agglomerates. The manufacturing comprises blending fine metal particles with the liquid oily lubricant and compacting the oily metallic mixture obtained to desired solid form. Advantageously, the solid agglomerates possess a desirable density, a suitable resistance to crumbling and dusting during handling, and they can resist to high temperature and to humidity. Solid agglomerated metal products, according to the invention, may be useful for different purposes such as quality charge material for steel plants, blast furnaces and foundries.

Described are solid agglomerates of fine metal particles and methods for manufacturing same. A liquid oily lubricant is used in the manufacture of the solid agglomerates. The manufacturing comprises blending fine metal particles with the liquid oily lubricant and compacting the oily metallic mixture obtained to desired solid form. Advantageously, the solid agglomerates possess a desirable density, a suitable resistance to crumbling and dusting during handling, and they can resist to high temperature and to humidity. Solid agglomerated metal products, according to the invention, may be useful for different purposes such as quality charge material for steel plants, blast furnaces and foundries.

Methods for recovering a metal value from a metal-bearing material are provided. The method comprises agglomerating the metal-bearing material with an agglomeration solution comprising a raffinate, an oxidant, and citric acid or salts thereof to form an agglomerated metal-bearing material; leaching the agglomerated metal-bearing material with a leaching solution comprising the raffinate and the citric acid or salts thereof to produce a pregnant leaching solution and a leached material; re-oxidizing the leached material with a curing solution comprising the raffinate and the oxidant; and recovering the metal value from the pregnant leach solution to produce the raffinate.

Methods for recovering a metal value from a metal-bearing material are provided. The method comprises agglomerating the metal-bearing material with an agglomeration solution comprising a raffinate, an oxidant, and citric acid or salts thereof to form an agglomerated metal-bearing material; leaching the agglomerated metal-bearing material with a leaching solution comprising the raffinate and the citric acid or salts thereof to produce a pregnant leaching solution and a leached material; re-oxidizing the leached material with a curing solution comprising the raffinate and the oxidant; and recovering the metal value from the pregnant leach solution to produce the raffinate.

Provided is a smelting method whereby a reaction for reducing pellets, said pellet being formed by using a saprolite ore as a starting material, can be effectively conducted and thus an iron/nickel alloy having a nickel grade of, for example, 16% or greater can be obtained. The method comprises: a pellet production step (S1) for producing the pellets from the saprolite ore; and a reduction step (S2) for heating and reducing the obtained pellets in a smelting furnace. In the pellet production step (S1), at least the saprolite ore and a preset amount of a carbonaceous reducing agent are mixed together to produce the pellets. In the reduction step (S2), a hearth carbonaceous reducing agent is preliminarily spread on the hearth of the smelting furnace and the pellets produced above are placed on the hearth carbonaceous reducing agent and then subjected to a heat reduction treatment.

Provided is a smelting method whereby a reaction for reducing pellets, said pellet being formed by using a saprolite ore as a starting material, can be effectively conducted and thus an iron/nickel alloy having a nickel grade of, for example, 16% or greater can be obtained. The method comprises: a pellet production step (S1) for producing the pellets from the saprolite ore; and a reduction step (S2) for heating and reducing the obtained pellets in a smelting furnace. In the pellet production step (S1), at least the saprolite ore and a preset amount of a carbonaceous reducing agent are mixed together to produce the pellets. In the reduction step (S2), a hearth carbonaceous reducing agent is preliminarily spread on the hearth of the smelting furnace and the pellets produced above are placed on the hearth carbonaceous reducing agent and then subjected to a heat reduction treatment.

A method for charging pallet cars of a traveling grate for the thermal treatment of bulk material includes in a first step a first layer is applied as a hearth layer on a grate surface of the pallet car. In at least one second step a second layer at the same time or successively is applied as a side layer on two opposed side walls of the pallet car and a third layer is applied as green pellet layer between the side layers and on the hearth layer. The pellets used for the grate and the side layer differ in terms of their diameter and size distribution.

An object of the present invention is to provide a method for recovering a heavy rare earth element from a workpiece containing at least a heavy rare earth element and an iron group element, which can be put into practical use as a low-cost, simple recycling system. The method for recovering a heavy rare earth element from a workpiece containing at least a heavy rare earth element and an iron group element of the present invention as a means for resolution is characterized by including at least the following step: a workpiece is subjected to an oxidation treatment or mixed with an oxidation-treated RFeB based magnet alloy, and then subjected to a heat treatment in the presence of carbon at a temperature of 1000 C. or more, thereby separating a heavy rare earth element in the form of an oxide from an iron group element.

An object of the present invention is to provide a method for recovering a heavy rare earth element from a workpiece containing at least a heavy rare earth element and an iron group element, which can be put into practical use as a low-cost, simple recycling system. The method for recovering a heavy rare earth element from a workpiece containing at least a heavy rare earth element and an iron group element of the present invention as a means for resolution is characterized by including at least the following step: a workpiece is subjected to an oxidation treatment or mixed with an oxidation-treated RFeB based magnet alloy, and then subjected to a heat treatment in the presence of carbon at a temperature of 1000 C. or more, thereby separating a heavy rare earth element in the form of an oxide from an iron group element.

The present invention provides a method for selective recovery of a valuable metal from a waste denitrification catalyst through alkali fusion, the method comprising the steps of: (a) adding an alkali metal to a waste denitrification catalyst, followed by mixing and alkali fusion, to generate a calcination product; (b) subjecting the calcination product to water-leaching to recover an alkali leachate and a residue; (c) adding a precipitator to the alkali leachate, followed by stirring, to recover calcium metavanadate (Ca(VO.sub.3).sub.2) or calcium tungstate (CaWO.sub.4) through precipitation; and (d) subjecting the recovered calcium tungstate to acid decomposition to prepare tungstic acid. Therefore, vanadium and tungsten can be recovered at high efficiency by a method in which a precipitator is added to a leachate, which is obtained by adding an excess amount of an alkali metal to a waste denitrification catalyst and carrying out calcination and water-leaching, and then a reaction rate is controlled.