Provided is a method for separating lithium from a lithium solution containing lithium by 200 mg/L or more and fluorine by 20 mg/L or more, the method including: a first removal step of adding a first component, which solidifies the fluorine contained in the lithium solution, to the lithium solution and removing the fluorine solidified to obtain a F-removed liquid; and a second removal step of adding a second component, which solidifies the first component remaining in the F-removed liquid, to the F-removed liquid and removing the first component solidified to obtain a first component-removed liquid.

A method for preparing lead directly from a lead-containing material by a solid phase reaction, includes: step 1, adding the lead-containing material to be processed to the grinder, and adding a metal substance and water to the grinder, wherein an activity of the metal substance is larger than that of lead; the solid phase reaction between the lead-containing material and the metal substance is caused directly by the grinder through a mechanical force to obtain a reaction product; step 2, washing and filtering the reaction product to obtain the lead and a metal salt solution corresponding to the metal substance; step 3, performing a melt casting on the lead to obtain a crude lead, crystallizing the metal salt solution to obtain a metal salt corresponding to the metal substance.

A method for preparing lead directly from a lead-containing material by a solid phase reaction, includes: step 1, adding the lead-containing material to be processed to the grinder, and adding a metal substance and water to the grinder, wherein an activity of the metal substance is larger than that of lead; the solid phase reaction between the lead-containing material and the metal substance is caused directly by the grinder through a mechanical force to obtain a reaction product; step 2, washing and filtering the reaction product to obtain the lead and a metal salt solution corresponding to the metal substance; step 3, performing a melt casting on the lead to obtain a crude lead, crystallizing the metal salt solution to obtain a metal salt corresponding to the metal substance.

In a first embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture, isolating a residue from the first mixture, forming a second mixture comprising the residue, and electrospinning the second mixture to form a carbon fiber precursor material. In a second embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a mixture comprising solids and a liquid fraction, separating and filtering the liquid fraction from the mixture, and isolating one or more compounds from the liquid fraction. In a third embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture comprising residues, exposing the first mixture to (a) an acid, (b) a solvent, or (c) both to form a second mixture, and isolating rare earth elements and rare earth element compounds.

In a first embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture, isolating a residue from the first mixture, forming a second mixture comprising the residue, and electrospinning the second mixture to form a carbon fiber precursor material. In a second embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a mixture comprising solids and a liquid fraction, separating and filtering the liquid fraction from the mixture, and isolating one or more compounds from the liquid fraction. In a third embodiment, a coal treatment process includes exposing a material comprising coal to ionic liquid(s) to form a first mixture comprising residues, exposing the first mixture to (a) an acid, (b) a solvent, or (c) both to form a second mixture, and isolating rare earth elements and rare earth element compounds.

The present invention relates to a method for recovering lithium from brine, and provides a method for recovering lithium from brine, the method comprising: (a) an impurity removal step of adding a carbonate supply source to brine including lithium, magnesium and calcium to precipitate and remove magnesium and calcium impurities; (b) a pH adjusting step of adding an acid to the brine from which the impurities have been removed, to adjust the pH of the brine; (c) a lithium-aluminum compound recovery step of adding an aluminum supply source to the pH-adjusted brine to recover a lithium-aluminum compound; (d) a lithium sulfate and aluminum oxide formation step of adding the lithium-aluminum compound to a sulfur supply source and calcining same to form lithium sulfate and aluminum oxide; and (e) a lithium sulfate solution yield step of selectively dissolving lithium sulfate from among the formed lithium sulfate and aluminum oxide to yield a lithium sulfate solution.

The present invention relates to a method for recovering lithium from brine, and provides a method for recovering lithium from brine, the method comprising: (a) an impurity removal step of adding a carbonate supply source to brine including lithium, magnesium and calcium to precipitate and remove magnesium and calcium impurities; (b) a pH adjusting step of adding an acid to the brine from which the impurities have been removed, to adjust the pH of the brine; (c) a lithium-aluminum compound recovery step of adding an aluminum supply source to the pH-adjusted brine to recover a lithium-aluminum compound; (d) a lithium sulfate and aluminum oxide formation step of adding the lithium-aluminum compound to a sulfur supply source and calcining same to form lithium sulfate and aluminum oxide; and (e) a lithium sulfate solution yield step of selectively dissolving lithium sulfate from among the formed lithium sulfate and aluminum oxide to yield a lithium sulfate solution.

A system and process for concentrating a lithium stream is disclosed. The lithium stream is directed to a reverse osmosis unit which produces a concentrate containing lithium compounds. The RO concentrate is directed through two pressure retarded osmosis (PRO) modules connected in series. The two PRO modules further concentrate the RO concentrate and at the same time yield a diluted brine that is effective to drive an energy recovery device. The RO concentrate leaving the PRO modules is directed to an osmotically assisted reverse osmosis (OARO) module which also further concentrates the RO concentrate.

A system and process for concentrating a lithium stream is disclosed. The lithium stream is directed to a reverse osmosis unit which produces a concentrate containing lithium compounds. The RO concentrate is directed through two pressure retarded osmosis (PRO) modules connected in series. The two PRO modules further concentrate the RO concentrate and at the same time yield a diluted brine that is effective to drive an energy recovery device. The RO concentrate leaving the PRO modules is directed to an osmotically assisted reverse osmosis (OARO) module which also further concentrates the RO concentrate.

One or more embodiments relates to a process for extracting Rare Earth Elements (REEs) from REE-bearing underclays, claystones, shales, coal-mining waste, and waste coal. In at least one embodiment the process includes contacting the REE-bearing underclays, claystones, shales, coal-mining waste, and waste coal with an Organic Acid Solution (OAS) comprising at least one organic acid and at least one ionic salt at a predetermined ambient temperature and predetermined pH; and separating the REE from the REE-bearing underclays, claystones, shales, coal-mining waste, and waste coal, forming REE+Yttrium (REY) concentrate.