An agent for selective antimony and arsenic removal and tin retaining includes 10-30 wt % of aluminum, 65-85 wt % of calcium, 1-10 wt % of coke powder, and 1-5 wt % of lead powder. According to the content of antimony in lead, the antimony and arsenic removal and tin retaining agent is added to a molten lead which is at a temperature of about 550-650° C. at a certain proportion so as to carry out an antimony and arsenic removal reaction; after the reaction is completed, cooling is carried out, and antimony and arsenic scum is fished out to obtain a molten lead with antimony and arsenic removed; the content of antimony and arsenic is reduced to 0.0005 wt % or less, and the content of tin is substantially unchanged. The production costs for lead alloy preparation are reduced, and no smoke and odor appear in an antimony and arsenic removal reaction process.

A process for producing a solder product and a copper product from a first lead-tin based metal composition having at least 40% wt of copper and at least 5.0% wt together of tin and lead. The process includes the steps of partially oxidizing a first liquid bath having the first lead-tin based metal composition, thereby forming a first dilute copper metal composition and a first solder refining slag, followed by separating the slag from the metal composition, and partially oxidizing a second liquid bath having the first dilute copper metal composition, thereby forming a first high-copper metal composition and a third solder refining slag, followed by separating the third solder refining slag from the first high-copper metal composition,
whereby the solder product is derived from the first solder refining slag.

A disclosed process produces at least one concentrated copper product together with at least one crude solder product, starting from a black copper composition with at least 50% of copper together with at least 1.0% wt of tin and at least 1.0% wt of lead The process includes the step of partially oxidizing the black copper thereby forming a first copper refining slag, followed by partially reducing the first copper refining slag to form a first lead-tin based metal composition and a first spent slag. The total feed to the reducing step includes an amount of copper that is at least 1.5 times as high as the sum of the amounts of Sn plus Pb present, and the first spent slag includes at most 20% wt total of copper, tin and lead together.

Methods for the treatment of metallic particles such as heavy metal particles and objects contaminated with the metallic particles. For the treatment of objects contaminated with the metallic particles, a stabilizing composition may be applied to the object with or without a fixation agent. For the treatment of free-flowing metallic particles, an agglomeration agent may be used with or without a stabilizing agent.

Methods for the treatment of metallic particles such as heavy metal particles and objects contaminated with the metallic particles. For the treatment of objects contaminated with the metallic particles, a stabilizing composition may be applied to the object with or without a fixation agent. For the treatment of free-flowing metallic particles, an agglomeration agent may be used with or without a stabilizing agent.

Methods for the treatment of metallic particles such as heavy metal particles and objects contaminated with the metallic particles. For the treatment of objects contaminated with the metallic particles, a stabilizing composition may be applied to the object with or without a fixation agent. For the treatment of free-flowing metallic particles, an agglomeration agent may be used with or without a stabilizing agent.

An apparatus and process for melting and using scrap pieces of lead or lead alloy from making a web of connected grids for a lead acid battery by forming holes through a solid strip of lead or lead alloy. The scrap pieces may be compacted into briquettes which are submerged in a pool of liquid lead or lead alloy below the top surface of the pool and melt in the pool. Liquid lead from the pool may be cast into solid strips from which webs of grids are made.

The present application relates to a process for the purification of waste materials or industrial by-products, the process comprising the steps of: a) Preparing a composition (C) by blending or mixing waste materials or industrial by-products comprising chlorine (B) with one or more materials comprising heavy metals (HM) b) Reacting (B) and (HM) by thermal treatment of (C) c) Separating evaporated heavy metal chloride compounds (HMCC) d) Obtaining a solid material after the thermal treatment step.

A method and apparatus for step-by-step retrieving valuable metals from waste printed circuit board particles. Many kinds of metals, most existing in form of elementary substance or alloy, are contained in the waste printed circuit boards. Molten metals are separated selectively by supergravity separation at different temperatures to achieve the step-by-step recovery. Tin-based alloys, lead-based alloy, zinc aluminum alloy, crude copper and precious-metal-enriched residues with different metal contents are separated out and collected on the condition of different temperatures (T=200300 C., 330430 C., 700900 C., 11001300 C.) and controlling the gravity coefficient (G=501000) and separation time (t=220 min) etc. Different metals or alloys can be separated quickly and efficiently and the residue concentration of precious metals can be obtained. The process is simple and low cost to provide an efficient way to recovery the enrichment of valuable metals from electronic wastes.

A method for extracting and separating Gold, Silver, Copper, Zinc and/or Lead from an Arsenic-containing ore, concentrate or tailings characterized in that the extraction is carried by roasting in the presence of a calcium-containing material and at least one of an alkali metal halide and alkaline metal halide. In the method, Arsenic remains immobilized in the extraction residue.