Lead is recycled from lead paste of lead acid batteries in a process that employs alkaline desulfurization followed by formation of plumbite that is then electrolytically converted to pure lead. Remaining insoluble lead dioxide is removed from the lead plumbite solution and reduced to produce lead oxide that can be fed back to the recovery system. Sulfate is recovered as sodium sulfate, while the so produced lead oxide can be added to lead paste for recovery.

The present disclosure relates generally to systems and methods for recycling lead-acid batteries, and more specifically, relates to purifying and recycling the lead content from lead-acid batteries. A system includes a reactor that receives and mixes a lead-bearing material waste, a carboxylate source, and a recycled liquid component to form a leaching mixture yielding a lead carboxylate precipitate. The system also includes a phase separation device coupled to the reactor, wherein the phase separation device isolates the lead carboxylate precipitate from a liquid component of the leaching mixture. The system further includes a closed-loop liquid recycling system coupled to the phase separation device and to the reactor, wherein the closed-loop liquid recycling system receives the liquid component isolated by the phase separation device and recycles a substantial portion of the received liquid component back to the reactor as the recycled liquid component.

Disclosed are methods and systems for processing clinker containing iron and non-ferrous metals for extraction of those metals. The processing comprises pretreatment of clinker resulting in a removable carbon-containing foam phase, forming a metal-containing cake. Melting of the cake is then performed in the absence of air delivery and in the presence of carbon, resulting in phases of slag, metal, and matte. Melting may occur while maintaining a mass ratio of iron to carbon of no greater than 14:1, such that cast iron forms instead of sponge iron. The metal and matte phases, containing non-ferrous metals and iron, are then exposed to further dissolution, filtration, and salting out to extract the non-ferrous metals and iron. Byproducts of various stages of the process are also recycled into earlier stages or further processed to extract additional copper, iron, and other non-ferrous metals.

Exemplary methods provide for recovery of valuable industrial metals in connection with recycling of silicon solar cells and modules. Silicon, copper, silver, and the like may be recovered separately, allowing for cost-effective recycling for silicon solar cells and modules.

A method for the treatment of jarosite and other residues of the zinc and lead production industry, including the following steps: thermal treatment of the residues, at a temperature between 500? C. and 700? C., to obtain the evaporation of the imbibition water and the demolition of the jarosite molecule, resulting in the development of SO3 and in the removal of OH.sup.? groups to give additional water in the gaseous phase, and resulting in the obtainment, from the recondensation of these components, of an aqueous solution of diluted sulfuric acid, and with the simultaneous formation of a solid fraction composed of iron(III) oxide, zinc, lead, silver, copper sulphates and other minor elements; and then steps for acid leaching, a refining treatment; and purification to obtain solubilization of iron(III); separation of the solubilized iron(III) from the silica, which remains insolubilized; precipitation of iron(III) to obtain iron oxide pigment.

A process for recycling glass from screens deriving from the disposal of cathode-ray tube television sets with quantitative recovery of the lead in metal form, is described.

Lead is recycled from lead paste of lead acid batteries in a process that employs alkaline desulfurization followed by formation of plumbite that is then electrolytically converted to pure lead. Remaining insoluble lead dioxide is removed from the lead plumbite solution and reduced to produce lead oxide that can be fed back to the recovery system. Sulfate is recovered as sodium sulfate, while the so produced lead oxide can be added to lead paste for recovery.

The present disclosure relates generally to systems and methods for recycling lead-acid batteries, and more specifically, relates to purifying and recycling the lead content from lead-acid batteries. A system includes a reactor that receives and mixes a lead-bearing material waste, a carboxylate source, and a recycled liquid component to form a leaching mixture yielding a lead carboxylate precipitate. The system also includes a phase separation device coupled to the reactor, wherein the phase separation device isolates the lead carboxylate precipitate from a liquid component of the leaching mixture. The system further includes a closed-loop liquid recycling system coupled to the phase separation device and to the reactor, wherein the closed-loop liquid recycling system receives the liquid component isolated by the phase separation device and recycles a substantial portion of the received liquid component back to the reactor as the recycled liquid component.

Systems and processes for producing ammonium sulfate that include providing an industrial waste material that includes at least lead sulfate and sulfuric acid. Ammonium hydroxide is added to the industrial waste material to raise the pH thereof and react the sulfuric acid to produce ammonium sulfate, and the lead sulfate is reacted with ammonium carbonate to produce lead carbonate.

The present disclosure provides systems and methods for dismantling and/or recycling liquid metal batteries. Such methods can include cryogenically freezing liquid metal battery components, melting and separating liquid metal battery components, and/or treating liquid metal battery components with water.