The present application relates to the electrochemical extraction of lead (Pb) from a lead-containing material using a deep eutectic solvent. This is of particular use in the recycling of the lead-based materials that result from energy generation processes.

Lead is recovered from lead paste of a lead acid battery in a continuous process. The lead paste is contacted with a base to generate a supernatant and a precipitate. The precipitate is separated from the supernatant, and is contacted with an alkane sulfonic acid to generate a mixture of lead ion solution and insoluble lead dioxide. The lead dioxide is reduced with a reducing agent to form lead oxide, and the lead oxide is combined with the lead ion solution to form a combined lead ion solution to so allow a continuous process without lead dioxide accumulation. Lead is recovered from the combined lead ion solution using electrolysis.

Methods for the treatment of metallic particles such as heavy metal particles and objects contaminated with the metallic particles. For the treatment of objects contaminated with the metallic particles, a stabilizing composition may be applied to the object with or without a fixation agent. For the treatment of free-flowing metallic particles, an agglomeration agent may be used with or without a stabilizing agent.

Methods for the treatment of metallic particles such as heavy metal particles and objects contaminated with the metallic particles. For the treatment of objects contaminated with the metallic particles, a stabilizing composition may be applied to the object with or without a fixation agent. For the treatment of free-flowing metallic particles, an agglomeration agent may be used with or without a stabilizing agent.

Methods for the treatment of metallic particles such as heavy metal particles and objects contaminated with the metallic particles. For the treatment of objects contaminated with the metallic particles, a stabilizing composition may be applied to the object with or without a fixation agent. For the treatment of free-flowing metallic particles, an agglomeration agent may be used with or without a stabilizing agent.

The present disclosure relates to methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the construction of new lead-acid batteries. A method includes: (A) forming a mixture including a carboxylate source and a lead-bearing material; (B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material; (C) increasing the pH of the mixture to dissolve the first lead salt precipitate; (D) isolating a liquid component of the mixture from one or more insoluble components of the mixture; (E) decreasing the pH of the liquid component of the mixture to generate a second lead salt precipitate; and (F) isolating the second lead salt precipitate from the liquid component of the mixture. Thereafter, the isolated lead salt precipitate may be converted to leady oxide for use in the manufacture of new lead-acid batteries.

The present disclosure relates to systems and methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the production of new lead-acid batteries. The system includes a first phase separation device configured to: receive the first mixture from the basic lead stream digestion device, isolate a liquid component from one or more insoluble components of the first mixture, and output the liquid component. The system also includes a lead salt precipitation device configured to: receive and mix the liquid component and a carboxylate source to form a second mixture including a lead salt precipitate, and output the second mixture. The system further includes a second phase separation device configured to: receive the second mixture from the lead salt precipitation device, isolate the liquid component from the lead salt precipitate of the second mixture, and output the lead salt precipitate.

The present disclosure relates to systems and methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the production of new lead-acid batteries. The system includes a first phase separation device configured to: receive the first mixture from the basic lead stream digestion device, isolate a liquid component from one or more insoluble components of the first mixture, and output the liquid component. The system also includes a lead salt precipitation device configured to: receive and mix the liquid component and a carboxylate source to form a second mixture including a lead salt precipitate, and output the second mixture. The system further includes a second phase separation device configured to: receive the second mixture from the lead salt precipitation device, isolate the liquid component from the lead salt precipitate of the second mixture, and output the lead salt precipitate.

The present disclosure relates to methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the construction of new lead-acid batteries. A method includes: (A) forming a mixture including a carboxylate source and a lead-bearing material; (B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material; (C) increasing the pH of the mixture to dissolve the first lead salt precipitate; (D) isolating a liquid component of the mixture from one or more insoluble components of the mixture; (E) decreasing the pH of the liquid component of the mixture to generate a second lead salt precipitate; and (F) isolating the second lead salt precipitate from the liquid component of the mixture. Thereafter, the isolated lead salt precipitate may be converted to leady oxide for use in the manufacture of new lead-acid batteries.

The present disclosure relates generally to recycling lead-acid batteries, and more specifically, relates to purifying and recycling the lead content from lead-acid batteries. A method includes reacting a lead-bearing material with a first carboxylate source to generate a first lead carboxylate. The method includes reacting the first lead carboxylate with a second carboxylate source to generate a second lead carboxylate. The method further includes applying an electrical bias to an aqueous solution of the second lead carboxylate to generate metallic lead.