A manufacture method disclosed herein includes: a preparation step S11 of preparing a recovery object; a measurement step S12 of measuring a quantity of oxygen element and a reducing component contained in the recovery object; a determination step S13 of determining whether or not a quantity ratio of the reducing component relative to oxygen element is higher than or equal to a threshold value based on a stoichiometric ratio of an oxide of the reducing component; a reducing component addition step S14 of adding the reducing component to the recovery object when a determined result value in the determination step is lower than the threshold value; and a heating step S15 of heating the recovery object under an inert atmosphere. This method makes it possible to reduce the valuable metal into an elemental metal, and therefore a valuable metal recovery efficiency can be improved.

The invention related to the recycling field of waste printed circuit boards (WPCB), and especially involved a complete non-cyanogens wet process for green recycling of WPCB, which belonged to the field of recycle economy. In the invention, the process included that WPCB were broken by the jaw crusher, and then mixed copper powders and nonmetallic powders were separated by the method of air classification, the mixed copper powders were smelted and casted to get copper anode plates, the copper was purified by electrolytion, the valuable metals (such as copper, gold, silver, platinum and palladium, lead and tin) were recycled from the copper anode slime, and the waste water was recycled. The recovery ratio of all-metal was above 98%. The purity of the cathode copper was up to 4N level. The ratio of de-coppering was above 96%. The recovery ratio of gold was above 98.

The exemplary embodiments relate to a valuable metal recovery alloy, a valuable metal recovery composition, and a valuable metal recovery method.

According to an exemplary embodiment, the valuable metal recovery alloy may include, based on 100 wt % of the total composition of an alloy, a valuable metal of 45 wt % and a remainder which is impurities, and the valuable metal recovery alloy may satisfy Equation 1 below.

[00001]$\begin{array}{cc}0.02\left[C\right]/\left[\mathrm{Ni}\right]7& .Math.\mathrm{Equation}1.Math.\end{array}$

([C] and [Ni] mean wt % of C and wt % of Ni, respectively)

Provided is a method for producing cathode copper. The method comprises a smelting step including feeding sulfidic copper bearing material and oxygen-bearing reaction gas into a suspension smelting furnace, to produce blister copper, a fire refining step including feeding blister copper into an anode furnace to produce molten anode copper, an anode casting step to produce cast anodes, a quality checking step for dividing cast anodes into accepted cast anodes and rejected cast anodes, an electrolytic refining step including subjecting accepted cast anodes to electrolytic refining in an electrolytic cell to produce cathode copper and as a by-product, spent cast anodes, and a recycling step for recycling anode copper of rejected cast anodes and anode copper of spent cast anodes.

Provided is a method for recovering valuable metals that makes it possible to efficiently recover valuable metals at a high recovery rate. The present invention is a method for recovering the valuable metal from a raw material that contains the valuable metal. This method comprises: a preparation step for preparing a raw material; a melting step for introducing the raw material into a melting furnace and heating and melting the raw material to yield an alloy and a slag; and a slag separation step for separating the slag and recovering a valuable metal-containing alloy. The redox degree is adjusted in the melting step by introducing, as a reducing agent, scrap of a wound body, the wound body being an electrode assembly in which a positive electrode and a negative electrode are wound insulated from each other by a separator and carbon is used in the negative electrode.

Disclosed is a process for recovering copper from secondary raw materials including in a feed batch smelting in a furnace a feedstock including copper oxide and elemental iron for forming a concentrated copper intermediate, whereby heat is generated by the redox reactions converting iron to oxide and copper oxide to copper, whereby copper collects in a molten liquid metal phase and iron oxides collect in a supernatant liquid slag phase, whereby at the end of the batch the liquid phases separate and may be removed from the furnace as smelter slag and as the concentrated copper intermediate, wherein during the smelting step an excess of elemental iron is maintained in the furnace relative to the amount required for completing the redox reactions, and further heat input is provided by the injection of an oxygen containing gas for oxidizing the excess iron.

The present invention concerns a process for the recovery of metals and of heat from spent rechargeable batteries, in particular from spent Li-ion batteries containing relatively low amounts of cobalt. It has in particular been found that such cobalt-depleted Li-ion batteries can be processed on a copper smelter by: feeding a useful charge and slag formers to the smelter; adding heating and reducing agents; whereby at least part of the heating and/or reducing agents is replaced by Li-ion batteries containing one or more of metallic Fe, metallic Al, and carbon. Using spent LFP or LMO batteries as a feed on the Cu smelter, the production rate of Cu blister is increased, while the energy consumption from fossil sources is decreased.

The invention provides a method for producing valuable metals from raw material containing the valuable metals containing Cu, Ni, and Co, the method including: a preparation step of preparing a raw material containing at least Li, Al, and the valuable metals; a reductive melting step; and a slag separation step of separating slag from the reduced product to recover an alloy, wherein in any one or both of the preparation step and the reductive melting step, a flux containing calcium (Ca) is added to the raw material, and in the reductive melting step, while cooling the furnace wall of the melting furnace by the cooling means, the thickness of the slag layer is adjusted so that the temperature of the interface between a layer of the alloy and a layer of the slag is higher than the temperature of the refractory surface of the furnace wall in the melting furnace.

A process for recovering a metal in the form of a metal halide from a metal-containing source is described, the process comprising the steps of: (i) forming a solid metal halide containing product by contacting the metal-containing source with a gaseous halide in an oxidising environment and at a temperature below the vaporisation temperature of the metal halide of interest; (ii) heating the metal halide containing product formed in step (i) to a temperature at or above the vaporisation temperature of the metal halide to form a gaseous metal halide containing product; and (iii) condensing the gaseous metal halide containing product of step (ii) to recover the metal halide of interest.

A method for obtaining metals of the 8th to 14th groups, in particular raw copper, comprises the following steps: i) providing and melting down a mixed feed comprising electronic waste in a smelting reactor, so that a first melt with a first metallic phase and a first slag phase is formed; ii) separating out the first slag phase from the smelting reactor; iii) refining the remaining first metallic phase by means of an oxygen-containing gas, possibly with the addition of copper-containing residual materials, so that a second, copper-enriched slag phase is formed; iv) possibly separating off the second slag phase and repeating the step; v) separating off the refined first metallic phase from the smelting reactor; and vi) adding a further mixed feed comprising electronic waste to the remaining second, copper-enriched slag phase and repeating process steps i) to vi).