Patent classifications
C22B26/22
EXTRACTION SYSTEM, EXTRACTION METHOD FOR SEPARATING MAGNESIUM AND EXTRACTING LITHIUM FROM MAGNESIUM-CONTAINING BRINE WITH SECONDARY AMIDE-TYPE SOLVENT AS WELL AS APPLICATIONS THEREOF
The secondary amide contained in the extraction system consists of a single compound or a mixture of two or more compounds, wherein R.sub.1 is selected from a C2˜C12 alkyl, or a C3˜C12 cycloalkyl containing a single-ring structure, R.sub.2 is selected from a C1˜C11 alkyl, or a C3˜C11 cycloalkyl containing a single-ring structure; the total number of carbon atoms in the molecule is 12˜18. With a volume ratio of an organic phase and a brine phase being 1˜10:1, at a brine density of 1.25˜1.38 g/cm.sup.3 and at a temperature of 0˜50° C., a single-stage or multi-stage countercurrent extraction and a stripping are conducted to obtain a water phase with a low magnesium-lithium ratio, which is subjected to concentration, impurity removal and preparation to get lithium chloride, lithium carbonate and lithium hydroxide respectively. Water is used for stripping, greatly reducing the consumption of acid and base, and the separation process is shortened.
EXTRACTION SYSTEM, EXTRACTION METHOD FOR SEPARATING MAGNESIUM AND EXTRACTING LITHIUM AND BORON FROM MAGNESIUM-CONTAINING BRINE WITH COMPLEX SOLVENT OF SECONDARY AMIDE/ALKYL ALCOHOL AS WELL AS APPLICATIONS THEREOF
The extraction system contains secondary amides and alkyl alcohols which are separately used as the extractants for extracting lithium and boron and consist of a single compound or a mixture of two or more compounds, and the total number of carbon atoms in their molecules are 12˜18 and 8˜20 respectively; the extraction system has a freezing point less than 0° C. With a volume ratio of an organic phase and a brine phase being 1˜10:1, at a brine density of 1.25˜1.38 g/cm.sup.3, at a brine pH value of 0˜7 and at a temperature of 0˜50° C., a single-stage or multi-stage countercurrent extraction and a stripping are conducted to obtain a water phase with a low magnesium-lithium ratio, which is subjected to concentration, impurity removal and preparation to get lithium chloride, lithium carbonate, lithium hydroxide and boric acid respectively. Water is used for stripping, greatly reducing the consumption of acid and base.
EXTRACTION SYSTEM, EXTRACTION METHOD FOR SEPARATING MAGNESIUM AND EXTRACTING LITHIUM AND BORON FROM MAGNESIUM-CONTAINING BRINE WITH COMPLEX SOLVENT OF SECONDARY AMIDE/ALKYL ALCOHOL AS WELL AS APPLICATIONS THEREOF
The extraction system contains secondary amides and alkyl alcohols which are separately used as the extractants for extracting lithium and boron and consist of a single compound or a mixture of two or more compounds, and the total number of carbon atoms in their molecules are 12˜18 and 8˜20 respectively; the extraction system has a freezing point less than 0° C. With a volume ratio of an organic phase and a brine phase being 1˜10:1, at a brine density of 1.25˜1.38 g/cm.sup.3, at a brine pH value of 0˜7 and at a temperature of 0˜50° C., a single-stage or multi-stage countercurrent extraction and a stripping are conducted to obtain a water phase with a low magnesium-lithium ratio, which is subjected to concentration, impurity removal and preparation to get lithium chloride, lithium carbonate, lithium hydroxide and boric acid respectively. Water is used for stripping, greatly reducing the consumption of acid and base.
METHODS OF EXTRACTION OF PRODUCTS FROM TITANIUM-BEARING MATERIALS
The invention relates to processes for the extraction of products from titanium-bearing materials or a composition produced in a process for the production of titanium dioxide, and more particularly, although not exclusively, extracting titanium dioxide and/or one or more other products from iron making slag.
METHOD AND APPARATUS FOR RECYCLING LITHIUM-ION BATTERIES
Cathode material from exhausted lithium ion batteries are dissolved in a solution for extracting the useful elements Co (cobalt), Ni (nickel), Al (Aluminum) and Mn (manganese) to produce active cathode materials for new batteries. The solution includes compounds of desirable materials such as cobalt, nickel, aluminum and manganese dissolved as compounds from the exhausted cathode material of spent cells. Depending on a desired proportion, or ratio, of the desired materials, raw materials are added to the solution to achieve the desired ratio of the commingled compounds for the recycled cathode material for new cells. The desired materials precipitate out of solution without extensive heating or separation of the desired materials into individual compounds or elements. The resulting active cathode material has the predetermined ratio for use in new cells, and avoids high heat typically required to separate the useful elements because the desired materials remain commingled in solution.
METHOD AND APPARATUS FOR RECYCLING LITHIUM-ION BATTERIES
Cathode material from exhausted lithium ion batteries are dissolved in a solution for extracting the useful elements Co (cobalt), Ni (nickel), Al (Aluminum) and Mn (manganese) to produce active cathode materials for new batteries. The solution includes compounds of desirable materials such as cobalt, nickel, aluminum and manganese dissolved as compounds from the exhausted cathode material of spent cells. Depending on a desired proportion, or ratio, of the desired materials, raw materials are added to the solution to achieve the desired ratio of the commingled compounds for the recycled cathode material for new cells. The desired materials precipitate out of solution without extensive heating or separation of the desired materials into individual compounds or elements. The resulting active cathode material has the predetermined ratio for use in new cells, and avoids high heat typically required to separate the useful elements because the desired materials remain commingled in solution.
Method and apparatus for recycling lithium-ion batteries
Cathode material from exhausted lithium ion batteries are dissolved in a solution for extracting the useful elements Co (cobalt), Ni (nickel), Al (Aluminum) and Mn (manganese) to produce active cathode materials for new batteries. The solution includes compounds of desirable materials such as cobalt, nickel, aluminum and manganese dissolved as compounds from the exhausted cathode material of spent cells. Depending on a desired proportion, or ratio, of the desired materials, raw materials are added to the solution to achieve the desired ratio of the commingled compounds for the recycled cathode material for new cells. The desired materials precipitate out of solution without extensive heating or separation of the desired materials into individual compounds or elements. The resulting active cathode material has the predetermined ratio for use in new cells, and avoids high heat typically required to separate the useful elements because the desired materials remain commingled in solution.
Method and apparatus for recycling lithium-ion batteries
Cathode material from exhausted lithium ion batteries are dissolved in a solution for extracting the useful elements Co (cobalt), Ni (nickel), Al (Aluminum) and Mn (manganese) to produce active cathode materials for new batteries. The solution includes compounds of desirable materials such as cobalt, nickel, aluminum and manganese dissolved as compounds from the exhausted cathode material of spent cells. Depending on a desired proportion, or ratio, of the desired materials, raw materials are added to the solution to achieve the desired ratio of the commingled compounds for the recycled cathode material for new cells. The desired materials precipitate out of solution without extensive heating or separation of the desired materials into individual compounds or elements. The resulting active cathode material has the predetermined ratio for use in new cells, and avoids high heat typically required to separate the useful elements because the desired materials remain commingled in solution.
PRODUCTION OF FINE GRAIN MAGNESIUM OXIDE AND FIBROUS AMORPHOUS SILICA FROM SERPENTINITE MINE TAILINGS
The present disclosure broadly relates to a process for recovering magnesium as magnesium oxide and fibrous amorphous silica from serpentinite feedstocks. More specifically, but not exclusively, the present disclosure relates to metallurgical and chemical processes for recovering magnesium oxide and fibrous amorphous silica from serpentinite feedstocks. The process broadly comprises applying a sufficient amount of shear deformation force to the serpentine feedstocks to produce a particulate material of reduced size; subjecting the particulate material to magnetic separation to produce a primary magnetic separation product and iron-reduced tailings; and digesting the iron-reduced tailings into nitric acid, producing a magnesium-rich pregnant solution and insoluble solids. The process further comprises adjusting the pH of the pregnant solution to values ranging from about 5.0 to about 7.0.
PRODUCTION OF FINE GRAIN MAGNESIUM OXIDE AND FIBROUS AMORPHOUS SILICA FROM SERPENTINITE MINE TAILINGS
The present disclosure broadly relates to a process for recovering magnesium as magnesium oxide and fibrous amorphous silica from serpentinite feedstocks. More specifically, but not exclusively, the present disclosure relates to metallurgical and chemical processes for recovering magnesium oxide and fibrous amorphous silica from serpentinite feedstocks. The process broadly comprises applying a sufficient amount of shear deformation force to the serpentine feedstocks to produce a particulate material of reduced size; subjecting the particulate material to magnetic separation to produce a primary magnetic separation product and iron-reduced tailings; and digesting the iron-reduced tailings into nitric acid, producing a magnesium-rich pregnant solution and insoluble solids. The process further comprises adjusting the pH of the pregnant solution to values ranging from about 5.0 to about 7.0.