Provided herein are processes for recovering metal present at low concentration from an acidic aqueous solution, including contacting the acidic aqueous solution with an organic phase solution including one or more 5-(C.sub.8 to C.sub.14 alkyl)-2-hydroxyaryloxime, thereby extracting at least part of the metal from the acidic aqueous phase; increasing or maintaining the concentration of metal in the organic phase solution by recycling a portion of the organic phase solution containing the metal and contacting the organic phase with an acidic aqueous solution containing the metal; contacting the organic phase solution containing metal with an aqueous phase strip solution comprising an inorganic compound that back-extracts the metal, thereby stripping at least part of the metal from the organic phase solution to the aqueous phase strip solution; and separating the metal from the aqueous phase strip solution, thereby recovering the metal.

Provided herein are processes for recovering metal present at low concentration from an acidic aqueous solution, including contacting the acidic aqueous solution with an organic phase solution including one or more 5-(C.sub.8 to C.sub.14 alkyl)-2-hydroxyaryloxime, thereby extracting at least part of the metal from the acidic aqueous phase; increasing or maintaining the concentration of metal in the organic phase solution by recycling a portion of the organic phase solution containing the metal and contacting the organic phase with an acidic aqueous solution containing the metal; contacting the organic phase solution containing metal with an aqueous phase strip solution comprising an inorganic compound that back-extracts the metal, thereby stripping at least part of the metal from the organic phase solution to the aqueous phase strip solution; and separating the metal from the aqueous phase strip solution, thereby recovering the metal.

A method of forming a metal alloy. The method comprises forming a metal oxide precursor and conducting cathodic polarization of the metal oxide precursor in a molten salt electrolyte to form a metal alloy. In an additional method, a metal oxide precursor is formed. The metal oxide precursor is reduced to a metal in an electrochemical cell that comprises a working electrode, a counter electrode, and an electrolyte. The metal is reacted with a metal of the working electrode to form a metal alloy. In another method, a metal oxide precursor is formed on a base material. The base material is introduced into a molten salt electrolyte of an electrochemical cell and the metal oxide precursor is reduced to a metal in the electrochemical cell. The metal is reacted with the base material to form a metal alloy on the base material.

The invention relates to a method for preparing high-melting-point metal powder through multi-stage deep reduction, and belongs to the technical field of preparation of powder. The method includes the following steps of mixing dried high-melting-point metal oxide powder with magnesium powder and performing a self-propagating reaction, placing an intermediate product into a closed reaction kettle, leaching the intermediate product with hydrochloric acid as a leaching solution so as to obtain a low-valence oxide Me.sub.xO precursor of the low-valence high-melting-point metal; uniformly mixing the precursor with calcium powder, pressing the mixture, placing the pressed mixture into a vacuum reduction furnace, heating the vacuum reduction furnace to 700-1200° C., performing deep reduction for 1-6 h, leaching a deep reduction product with hydrochloric acid as a leaching solution and performing treatment, so as to obtain the high-melting-point metal powder.

A process for treating spent catalyst containing heavy metals, e.g., Group VIB metals and Group VIII metals is provided. In one embodiment after deoiling, the spent catalyst is treated with an ammonia leach solution under conditions sufficient to dissolve the group VIB metal and the Group VIII metal into the leaching solution, forming a leach slurry. After solid-liquid separation to recover a leach solution, chemical precipitation and solids repulping is carried out to obtain an effluent stream containing ammonium sulfate (Amsul), ammonium sulfamate, Group VB, Group VIB and Group VIII metals. Following sulfidation, the Group VIII metal is fully removed and Group VB and Group VI metals are partially removed from the Amsul stream. In the additional steps of oxydrolysis and iron precipitation, an effective amount of ferric ion at a pre-select pH is added to form insoluble complexes with the Group VB and Group VIB metals, which upon liquid-solid separation produces an effluent ammonium sulfate stream containing less than 10 ppm each of the Group VB and Group VIB metals.

The invention provides an automated method for isolating a targeted isotope, the method having the steps of supplying a dissolved uranium targets into a first reaction environment; precipitating non-targeted isotope within the first reaction environment transferring liquid phase targeted isotope to a second reaction environment; precipitating the liquid phase targeted isotope in the second reaction environment; dissolving the precipitated targeted isotope; transferring the dissolved targeted isotope to a third reaction environment; and precipitating non-targeted isotope (i.e., iodine), such that the targeted isotope remains in the solution. Also provided is an automated system for isolating isotopes, the system having a plurality of reaction environments adapted to pneumatically receive and disgorge reactants and products via remotely actuated valves positioned between each of the reaction environments.

A plant for recovering metals and/or metal oxides from industrial process waste, in particular oil product refining waste, comprises a furnace; a feed line connected to a main inlet of the furnace and configured to feed the furnace with a solid waste containing metals, in particular in oxide form; an outlet line, connected to a solid phase outlet of the furnace and configured to draw a metal-enriched solid phase out of the furnace; the furnace is a belt conveyor furnace having a belt conveyor closed in a loop with a substantially horizontal configuration and having a top face, which receives the waste to treat and conveys it between two longitudinal opposite ends of the belt conveyor furnace respectively provided with the main inlet and the solid phase outlet.

A plant for recovering metals and/or metal oxides from industrial process waste, in particular oil product refining waste, comprises a furnace; a feed line connected to a main inlet of the furnace and configured to feed the furnace with a solid waste containing metals, in particular in oxide form; an outlet line, connected to a solid phase outlet of the furnace and configured to draw a metal-enriched solid phase out of the furnace; the furnace is a belt conveyor furnace having a belt conveyor closed in a loop with a substantially horizontal configuration and having a top face, which receives the waste to treat and conveys it between two longitudinal opposite ends of the belt conveyor furnace respectively provided with the main inlet and the solid phase outlet.

There is a process for the selective recovery of transition metals from an organic stream containing transition metals. The organic stream and possibly a first extractor if solid, are melted up to the liquid state. The extractor consists of an ionic liquid or a mixture of two or more ionic liquids and the ionic liquid contains an ammonium salt as cation and as anion an anion with chelating properties. A melted organic stream and a first extractor, optionally melted, are fed to a first liquid-liquid extraction unit working at a temperature of at least 150° C. where the liquid-liquid extraction is carried out obtaining a liquid mixture containing an ionic liquid, or a mixture of two or more ionic liquids, and metals. After extraction, the liquid mixture is cooled at a temperature between 0° C. and 70° C. and becomes biphasic; then the cooled mixture is sent to a first separation unit, to separate a liquid phase that contains ionic liquids and metals, and a metal-depleted solid phase. After the first separation, the separated metal-depleted solid phase is optionally sent to a washing unit to which a solvent is fed, so as to eliminate the residual ionic liquid by transferring it into the solvent and obtaining a metal-depleted solid phase. Then the separate liquid phase containing ionic liquids and metals is sent into a liquid-liquid precipitation and separation unit, adding a counter-solvent, thereby obtaining a solid phase containing the metals and a liquid stream containing counter-solvent and ionic liquids.

The present disclosure provides a method of recovering copper, molybdenum, and a precious metal value from a metal-bearing material, the method comprising bulk flotation of the metal-bearing material to form a flotation product, wherein the metal-bearing material comprises a copper compound, a molybdenum compound, and at least one precious metal value, pressure oxidizing the flotation product to form a pressure oxidized discharge, separating the pressure oxidized discharge to form a separated liquid and separated solid, extracting molybdenum, via a molybdenum solution extraction, from the separated liquid to form a molybdenum-containing stream and a copper-containing stream, extracting copper, via a copper solution extraction, from the copper-containing stream, and extracting the precious metal value, via a cyanide leaching process, from the separated solid.