Morphology, microstructure, compressive behavior, and biocorrosive properties of magnesium or magnesium alloy foams allow for their use in biodegradable biomedical, metal-air battery electrode, hydrogen storage, and lightweight transportation applications. Magnesium or Mg alloy foams are usually very difficult to manufacture due to the strong oxidation layer around the metallic particles; however, in this invention, they can be synthesized via a camphene-based freeze-casting process with the addition of graphite powder using precisely controlled heat-treatment parameters. The average porosity ranges from 45 to 85 percent and the median pore diameter is about a few tens to hundreds of microns, which are suitable for bio and energy applications utilizing their enhanced surface area. This invention based on powder-slurry freeze-casting method using camphene as a volatile solvent is also applicable for other metal foams such as iron, copper, or others to produce three-dimensional metal foams with high strut connectivity.

Morphology, microstructure, compressive behavior, and biocorrosive properties of magnesium or magnesium alloy foams allow for their use in biodegradable biomedical, metal-air battery electrode, hydrogen storage, and lightweight transportation applications. Magnesium or Mg alloy foams are usually very difficult to manufacture due to the strong oxidation layer around the metallic particles; however, in this invention, they can be synthesized via a camphene-based freeze-casting process with the addition of graphite powder using precisely controlled heat-treatment parameters. The average porosity ranges from 45 to 85 percent and the median pore diameter is about a few tens to hundreds of microns, which are suitable for bio and energy applications utilizing their enhanced surface area. This invention based on powder-slurry freeze-casting method using camphene as a volatile solvent is also applicable for other metal foams such as iron, copper, or others to produce three-dimensional metal foams with high strut connectivity.

The invention relates to a process for the preparation of sodium-based solid compounds, such as sodium-based solid alloys and sodium-based crystalline phases by ball-milling using metallic sodium as starting material.

The invention also relates to some sodium-based crystalline P2-phases and to Na-based vanadium phosphates phases (Na.sub.(3+y)V.sub.2(PO.sub.4).sub.3) with 0<y3 and Na-based vanadium fluorophosphates phases (Na.sub.(3+z)V.sub.2(PO.sub.4).sub.2F.sub.3) with 0<z3, in particular Na.sub.4V.sub.2(PO.sub.4).sub.2F.sub.3, obtained by such a process and to their use, as active material for positive electrode, in a Na-ion battery.

An object of the present invention is to provide a sintered alloy having high mechanical strength (specifically, high toughness suitable for a sputtering target material) and a sputtering target material including the sintered alloy, and the present invention provides a sintered alloy that includes: Mn; an A-group element consisting of one or more of Ga, Zn, Sn, Ge, Al, and Co; and optionally a B-group element consisting of one or more of Fe, Ni, Cu, Ti, V, Cr, Si, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, In, Ta, W, Re, Ir, Pt, Au, Bi, La, Ce, Nd, Sm, Gd, Tb, Dy, and Ho, wherein the balance is an inevitable impurity, wherein the sintered alloy includes one or more of a 1st to a 6th Mn phases that satisfy predetermined conditions.

A method of making a reinforced metal alloy component, the method including introducing a reinforcing phase precursor into a bulk alloy that is selected from the group consisting of high-entropy alloys, aluminum-based alloys, magnesium-based alloys and combinations thereof. The precursor is converted to a reinforcing phase by exposing the bulk alloy and precursor to an elevated temperature during one or more of a subsequent heat treating step, squeeze casting shaping or semi-solid metal shaping.

A manufacturing machine is capable of subtractive manufacturing and additive manufacturing for a workpiece. The manufacturing machine includes: a first headstock and a second headstock disposed in a first processing area and configured to hold a workpiece; a lower tool rest and a tool spindle disposed in the first processing area and configured to hold a tool to be used for subtractive manufacturing for the workpiece; an additive manufacturing head disposed in a second processing area; and a robot arm configured to hold a workpiece and transport the workpiece between the first processing area and the second processing area. The additive manufacturing head is configured to discharge a material toward the workpiece held by the robot arm during additive manufacturing for the workpiece. Accordingly, the manufacturing machine configured simply to be capable of subtractive manufacturing and additive manufacturing is provided.

There are provided reactive metal powder atomization manufacturing processes. For example, such processes include providing a heated metal source and contact the heated metal source with at least one additive gas while carrying out the atomization process. Such processes provide raw reactive metal powder having improved flowability. The at least one additive gas can be mixed together with an atomization gas to obtain an atomization mixture, and the heated metal source can be contacted with the atomization mixture while carrying out the atomization process. Reactive metal powder spheroidization manufacturing processes are also provided.

A method to form a metal matrix composite reinforced with eggshell (ES). The method includes preparing an ES powder, blending and milling the ES powder with at least one metal powder selected from the group consisting of magnesium (Mg), zirconium (Zr) to form a powder mixture, compacting and sintering the powder mixture to form the metal matrix composite. In addition, a MgZr-ES metal matrix composite with improved corrosion resistance, having an amount of magnesium from 95 to 97 wt. %, an amount of zirconium from 1 to 2 wt. %, and an amount of ES from 1 to 4 wt. %, may be used for biomedical applications.

A manufacturing machine is capable of additive manufacturing. The manufacturing machine includes: a connecting part configured to be connectable to a machine tool capable of subtractive manufacturing; and an additive manufacturing head configured to be positioned in a machining area of the machine tool and discharge a material, when the connecting part is connected to the machine tool. The manufacturing machine for additive manufacturing that can be installed at a low cost is thus provided.

A high-strength magnesium alloy member is suitable for products in which at least one of bending stress and twisting stress primarily acts. The member has required elongation and 0.2% proof stress, whereby strength and formability are superior, and has higher strength and large compressive residual stress in the vicinity of the surface of a wire rod. In the magnesium alloy member formed as a wire rod in which at least one of bending stress and twisting stress primarily acts, the wire rod includes a surface portion having the highest hardness of 170 HV or more in the vicinity of the surface and an inner portion having a 0.2% proof stress of 550 MPa or more and an elongation of 5% or more, and the wire rod has the highest compressive residue stress in the vicinity of the surface of 50 MPa or more.