In one aspect sintered cemented carbide articles are described herein which, in some embodiments, exhibit enhanced resistance to wear and thermal fatigue. Further, sintered cemented carbide articles described herein can tolerate variations in carbon content without formation of undesirable phases, including eta phase and/or free graphite (C-type porosity). Such tolerance can facilitate manufacturing and use of carbide grades where carbon content is not strictly controlled. A sintered cemented carbide body described herein comprises a hard particle phase including tungsten carbide and a metallic binder phase comprising at least one of cobalt, nickel and iron and one or more alloying additives, wherein the sintered cemented carbide has a magnetic saturation (MS) ranging from 0% to 73% and no eta phase.

Provided is a wear resistant, sintered body made of a binderless carbide, cermet or cemented carbide, e.g., WC, W2C and/or eta-phase, with a grain size less than 6.0 ?m, and less than 6% binder phase (e.g., CoNiFe). At least some working surfaces of the sintered body are surface treated with a boron yielding method including applying a low viscosity liquid medium having boron or aluminum content and heating at 1200? C. to 1450? C. under a pressure less than atmospheric pressure or a hydrogen containing atmosphere to from a hardness gradient with an increased hardness of the treated working surfaces of at least 50 to 200 HV5 and favorable compressive stresses in a surface zone that gives a tougher working surfaces of the boronized sintered bodies.

A surface-coated cutting tool having a rake face and a flank face includes a base material and a coating formed on the base material. The base material is a cemented carbide or a cermet. The coating includes an aluminum oxide layer containing a plurality of aluminum oxide crystal grains. The aluminum oxide layer includes: a first region made up of a region A on the rake face and a region B on the flank face; a second region on the rake face except for the region A; and a third region on the flank face except for the region B. The aluminum oxide layer satisfies a relation: ba>0.5, where a is an average value of TC(110) in the first region in texture coefficient TC(hkl), and b is an average value of TC(110) in the second or third region in texture coefficient TC(hkl).

A cutting tool includes a base material. The base material is a cemented carbide or a cermet. A surface of the base material includes a rake face, a flank face, and a cutting edge face connecting the rake face to the flank face. The base material has an oxygen concentration of less than or equal to 1 at. % at a depth position of 0.4 m from the cutting edge face.

The invention is concerned with the fields of cemented carbide materials and ceramic and/or powder-metallurgical process engineering and relates to a sintered cemented carbide granulate such as that which can, for example, be used for the production of wear parts or tools with cemented carbides, and to its use.

The object of the present invention is to specify a cemented carbide granulate with which cemented carbide green bodies and cemented carbide sintered bodies that exhibit a high green density and high green strength can be produced, and to specify the use thereof.

The object is attained with a sintered cemented carbide granulate which, for the majority of granules, has an inhomogeneous distribution of hard material and metallic binder in the individual granule, wherein the concentration of the metallic binder at the surface of the individual granule is, in total, at least 25% greater than in the interior of the granule.

A cutting insert may include a base member. The base member may include a first surface, a second surface adjacent to the first surface, and a first cutting edge located in at least a part of a first ridge line which the first surface intersects with the second surface. The base member may include a hard phase containing a titanium carbonitride, and a binding phase containing at least one of cobalt and nickel. The hard phase may include a first hard phase observed on a higher angle side, and a second hard phase observed on a lower angle side in a comparison of (422) plane peak in an X-ray diffraction analysis. A compressive residual stress of the second hard phase in the second surface may be less than a compressive residual stress of the second hard phase in the first surface.

The invention concerns the field of hardmetal materials and relates to hardmetals such as those which can, for example, be used as cutting material for tools. The object of the present invention is to specify hardmetals which include a novel concept for the structural composition of the hardmetals. The object is attained with hardmetals which are at least made up of hard phases in particle form and metal binder arranged therebetween, wherein a high-entropy hard phase (HEH) is composed of at least four metals (Me) of the 4th and/or 5th and/or 6th subgroup of the PTE in the form of a solid solution of carbides, nitrides, carbonitrides, oxycarbides, and/or oxycarbonitrides of the metals, wherein the respective amounts of the metals in the HEH are essentially equal.

The invention concerns the field of hardmetal materials and relates to hardmetals such as those which can, for example, be used as cutting material for tools. The object of the present invention is to specify hardmetals which include a novel concept for the structural composition of the hardmetals. The object is attained with hardmetals which are at least made up of hard phases in particle form and metal binder arranged therebetween, wherein a high-entropy hard phase (HEH) is composed of at least four metals (Me) of the 4th and/or 5th and/or 6th subgroup of the PTE in the form of a solid solution of carbides, nitrides, carbonitrides, oxycarbides, and/or oxycarbonitrides of the metals, wherein the respective amounts of the metals in the HEH are essentially equal.

Methods and compositions are provided for improving metal dusting corrosion, abrasion resistance and/or erosion resistance for various materials, preferably for applications relating to high-temperature reactors, including dense fluidized bed reactor components. In particular, cermets comprising (a) at least one ceramic phase selected from the group consisting of metal carbides, metal nitrides, metal borides, metal oxides, metal carbonitrides, and mixtures of thereof and (b) at least one metal alloy binder phase are provided. Ceramic phase materials include chromium carbide (Cr.sub.23C.sub.6). Metal alloy binder phase materials include ?-NiAl intermetallic alloys and Ni.sub.3Sn.sub.2 intermetallic alloys, as well as alloys that contain ?-Cr and/or ?-Ni.sub.3Al hard phases. Preferably, bimetallic materials are provided when the cermet compositions are applied using a laser, e.g., a laser cladding method such as high power direct diode (HPDD) laser, or by plasma-based methods such as plasma transfer arc (PTA) welding and powder plasma welding (PPW).

Methods and compositions are provided for improving metal dusting corrosion, abrasion resistance and/or erosion resistance for various materials, preferably for applications relating to high-temperature reactors, including dense fluidized bed reactor components. In particular, cermets comprising (a) at least one ceramic phase selected from the group consisting of metal carbides, metal nitrides, metal borides, metal oxides, metal carbonitrides, and mixtures of thereof and (b) at least one metal alloy binder phase are provided. Ceramic phase materials include chromium carbide (Cr.sub.23C.sub.6). Metal alloy binder phase materials include ?-NiAl intermetallic alloys and Ni.sub.3Sn.sub.2 intermetallic alloys, as well as alloys that contain ?-Cr and/or ?-Ni.sub.3Al hard phases. Preferably, bimetallic materials are provided when the cermet compositions are applied using a laser, e.g., a laser cladding method such as high power direct diode (HPDD) laser, or by plasma-based methods such as plasma transfer arc (PTA) welding and powder plasma welding (PPW).