An amorphous soft magnetic alloy of the formula (Fe.sub.1-αTM.sub.α).sub.100-w-x-y-zP.sub.wB.sub.xL.sub.ySi.sub.z Ti.sub.pC.sub.qMn.sub.rCu.sub.s, wherein TM is Co or Ni; L is Al, Cr, Zr, Mo or Nb; 0≦α≦0.3, 2≦w≦18 at %, 2≦x≦18 at %, 15≦w+x≦23 at %, 1<y≦5 at %, 0≦z≦4 at %; p, q, r, and s represents an addition ratio such that the total mass of Fe, TM, P, B, L and Si is 100, and 0≦p≦0.3, 0≦q≦0.5, 0≦r≦2, 0≦s≦1 and r+s>0; the composition fulfills one of the following conditions: L is Cr, Zr, Mo or Nb; or L is a combination of Al and Cr, Zr, Mo or Nb, wherein 0<Al≦5 at %, 1≦Cr≦4 at %, 0<Zr≦5 at %, 2≦Mo≦5 at %, and 2≦Nb≦5 at %; the alloy has a crystallization start temperature (Tx) which is 550° C. or less, a glass transition temperature (Tg) which is 520° C. or less, and a supercooled liquid region represented by ΔTx=Tx−Tg, which is 20° C. or more.

An R-T-B based permanent magnet includes R-T-B based compounds as main-phase crystal grains. R is a rare earth element. T is iron group element(s) essentially including Fe or Fe and Co. B is boron. A two-grain boundary is contained between the two adjacent main-phase crystal grains. An average grain size of the main-phase crystal grains is 0.9 μm or more and 2.8 μm or less. A thickness of the two-grain boundary is 5 nm or more and 200 nm or less.

An R-T-B based permanent magnet includes R-T-B based compounds as main-phase crystal grains. R is a rare earth element. T is iron group element(s) essentially including Fe or Fe and Co. B is boron. A two-grain boundary is contained between the two adjacent main-phase crystal grains. An average grain size of the main-phase crystal grains is 0.9 μm or more and 2.8 μm or less. A thickness of the two-grain boundary is 5 nm or more and 200 nm or less.

The present invention provides a primer insert for use in a polymeric ammunition cartridge includes a top surface opposite a bottom surface and a extraction flange that extends circumferentially about an outer edge of the top surface; a coupling element that extends from the bottom surface, wherein the substantially cylindrical coupling element is adapted to receive a polymer overmolding; a primer recess in the top surface that extends toward the bottom surface, wherein the primer recess comprises a recess bottom and a circular recess side wall; a primer flash aperture through the recess bottom that extends through the bottom surface, wherein the primer flash aperture is adapted to receive a polymer overmolding to form a flash hole; and a groove in the primer recess positioned around the primer flash aperture adapted to receive a polymer overmolding, wherein the groove extends at least partially over the bottom surface and at least partially over the circular recess side wall and the groove is adapted to receive polymer over the bottom surface and at least partially over the circular recess side wall.

The present invention provides an R-T-B based permanent magnet having excellent magnetic properties and corrosion resistance even when Co content is small. The R-T-B based permanent magnet in which R is a rare earth element including one or more selected from Nd and Pr and one or more selected from Dy and Tb, T is a combination of Fe and Co, and B is boron. The R-T-B based permanent magnet further includes Zr. A total content of Nd, Pr, Dy, and Tb is 30.00 mass % to 32.20 mass %, Co content is 0.30 mass % to 1.30 mass %, Zr content is 0.21 mass % to 0.85 mass %, and B content is 0.90 mass % to 1.02 mass % with respect to 100 mass % of the R-T-B based permanent magnet.

An article including a metal having an austenite transformation temperature of 850 degrees C. or more. The metal may be a steel, such as a stainless steel, a martensitic steel, or a martensitic stainless steel. In some embodiments, the metal is a steel including iron, molybdenum, and tungsten, and at least one of the following: manganese, nickel, chromium, and vanadium, where the manganese, nickel, chromium, and vanadium are in the following ranges: manganese: less than 0.1 wt %, nickel: less than 0.7 wt %, chromium: more than 12.5 wt %, and vanadium: more than 0.3 wt %. The article may have a surface coated with inorganic particles. In some embodiments, the article is an extrusion die, such as a honeycomb extrusion die.

An article including a metal having an austenite transformation temperature of 850 degrees C. or more. The metal may be a steel, such as a stainless steel, a martensitic steel, or a martensitic stainless steel. In some embodiments, the metal is a steel including iron, molybdenum, and tungsten, and at least one of the following: manganese, nickel, chromium, and vanadium, where the manganese, nickel, chromium, and vanadium are in the following ranges: manganese: less than 0.1 wt %, nickel: less than 0.7 wt %, chromium: more than 12.5 wt %, and vanadium: more than 0.3 wt %. The article may have a surface coated with inorganic particles. In some embodiments, the article is an extrusion die, such as a honeycomb extrusion die.

A molding composition contains a powder, a wax, an adhesive component, a molding component, and a plasticizer, in which a melt flow rate of the adhesive component at 190° C. is 200 g/10 min or more, and a density of the plasticizer is 1.0 g/cm.sup.3 or less.

A molding composition contains a powder, a wax, an adhesive component, a molding component, and a plasticizer, in which a melt flow rate of the adhesive component at 190° C. is 200 g/10 min or more, and a density of the plasticizer is 1.0 g/cm.sup.3 or less.

An iron powder and method of making an iron powder. The method includes a step of neutralizing an acidic aqueous solution containing a trivalent iron ion and a phosphorus-containing ion, with an alkali aqueous solution, so as to provide a slurry of a precipitate of a hydrated oxide, or a step of adding a phosphorus-containing ion to a slurry containing a precipitate of a hydrated oxide obtained by neutralizing an acidic aqueous solution containing a trivalent iron ion with an alkali aqueous solution. A silane compound is added to the slurry so as to coat a hydrolysate of the silane compound on the precipitate of the hydrated oxide. The precipitate of the hydrated oxide after coating is recovered through solid-liquid separation, the recovered precipitate is heated to provide iron particles coated with a silicon oxide, and a part or the whole of the silicon oxide coating is dissolved and removed.