A soft magnetic metal powder that has low coercivity Hcj and high saturation magnetic flux density Bs, and has high powder resistivity and high insulating performance is obtained. The soft magnetic metal powder is soft magnetic metal powder containing Fe. The soft magnetic metal powder has particles each including a soft magnetic metal portion and a coating portion coating the soft magnetic metal portion. The coating portion includes a first coating portion and a second coating portion. The first coating portion is closer to the soft magnetic metal portion than the second coating portion. The first coating portion and the second coating portion have oxides containing at least one element selected from Si, Fe, and B as a main component. The first coating portion includes amorphous material, the second coating portion includes crystals, and the second coating portion has a higher crystal content ratio than the first coating portion.

A metal magnetic particle provided with an oxide layer on a surface of an alloy particle containing Fe and Si. The oxide layer has a first oxide layer, a second oxide layer, and a third oxide layer from a side of the alloy particle. All of the first oxide layer, the second oxide layer, and the third oxide layer contain Si. Also, in line analysis of element content by using a scanning transmission electron microscope-energy dispersive X-ray spectroscopy, the first oxide layer is a layer having Fe content smaller than Si content in the alloy particle, the second oxide layer is a layer having Fe content larger than the Si content in the alloy particle, and the third oxide layer is a layer having Fe content smaller than the Si content in the alloy particle.

A metal magnetic particle provided with an oxide layer on a surface of an alloy particle containing Fe and Si. The oxide layer has a first oxide layer, a second oxide layer, and a third oxide layer from a side of the alloy particle. All of the first oxide layer, the second oxide layer, and the third oxide layer contain Si. Also, in line analysis of element content by using a scanning transmission electron microscope-energy dispersive X-ray spectroscopy, the first oxide layer is a layer having Fe content smaller than Si content in the alloy particle, the second oxide layer is a layer having Fe content larger than the Si content in the alloy particle, and the third oxide layer is a layer having Fe content smaller than the Si content in the alloy particle.

A three-dimensional printing kit can include a binding agent and a particulate build material. The binding agent can include a binder in an aqueous liquid vehicle. The particulate build material can include from about 80 wt % to 100 wt % metal particles that can have a D50 particle size from about 5 μm to about 200 μm. Individual metal particles can include an iron-containing core and can have an oxidation barrier formed thereon. The iron-containing core can include from about 90 wt % to 100 wt % iron. The oxidation barrier can have a stable average thickness from about 0.5% to about 10% of a D50 particle size of the metal particles.

A three-dimensional printing kit can include a binding agent and a particulate build material. The binding agent can include a binder in an aqueous liquid vehicle. The particulate build material can include from about 80 wt % to 100 wt % metal particles that can have a D50 particle size from about 5 μm to about 200 μm. Individual metal particles can include an iron-containing core and can have an oxidation barrier formed thereon. The iron-containing core can include from about 90 wt % to 100 wt % iron. The oxidation barrier can have a stable average thickness from about 0.5% to about 10% of a D50 particle size of the metal particles.

The present invention provides polymer ammunition having a primer insert having: a top surface; a bottom surface opposite the top surface; a coupling element that extends from the bottom surface, wherein the coupling element comprises an interior surface and an exterior surface, wherein the interior surface comprises: a transition region that transitions from the bottom surface to a second segment wherein the transition region has a radius of from 0.02 to 0.2; a first segment extending from the second segment and terminates at a tip, wherein the first segment has a first segment distance from 0.02 to 0.18 inches and the second segment has a second segment distance from 0.02 to 0.18 inches, wherein the second segment has a second segment angle from +3 to −3 degrees relative to the first segment angle and the first segment has a first segment angle from +6 to −6 degrees from perpendicular to the top surface; a primer recess in the top surface that extends toward the bottom surface; a primer flash aperture positioned in the primer recess through the bottom surface; and a flash aperture groove in the primer recess and positioned around the primer flash aperture and adapted to receive a polymer overmolding through the primer flash aperture.

A preparation method of improved sintered neodymium-iron-boron (Nd—Fe—B) casting strips includes the following steps: firstly nucleation assisted alloy particles used for sintered Nd—Fe—B casting strips are prepared, all elements are weighted as follows: 26.68-28% of Pr—Nd, 70-72.5% of Fe and 0.90-1% of B, and a Pr element in two elements of Pr—Nd accounts for 0-30 wt %; the compounded materials are smelted and poured to obtain alloy strips, then the alloy strips are crushed into particles with diameter of 1-10 mm; secondly, Nd—Fe—B casting strips are prepared: the prepared intermediate materials are smelted and melted into molten steel, and then are refined; after the intermediate materials are fully melted, the nucleation assisted alloy particles are added; and after the nucleation assisted alloy particles are added, smelting is performed for 3-15 minutes pouring is performed, and final Nd—Fe—B alloy casting strips are obtained.

A single crystal particle powder having a crystal structure of TbCu.sub.7-type of the present invention is represented by the general formula:

[Chemical Formula 1]

(R.sub.1-zM.sub.z)T.sub.x  (1)

or the general formula:

[Chemical Formula 2]

(R.sub.1-zM.sub.z)T.sub.xN.sub.y  (2)

and has a crystal structure of TbCu.sub.7-type,
wherein R is at least one element selected from the group consisting of Sm and Nd, T is at least one element selected from the group consisting of Fe and Co, x is 7.0≤x≤10.0, y is 1.0≤y≤2.0, and z is 0.0≤z≤0.3.

The present invention relates to a method for the economic production of metallic parts, with high flexibility in the geometry attainable. It also relates to the material required for the manufacturing of those parts. The method of the present invention allows for a very fast manufacturing of the parts. Also some forming technologies applicable to polymers can be used. The method allows for the fast and economic production of complex geometry metallic parts.

Provided are methods and devices for forming high nitrogen steel. The processes include heating a steel precursor to a temperature that transforms the steel into an austenite of FCC wherein the heating is in a nitrogen containing atmosphere. After an optional nitrogen uptake time, the precursor is further heated to a temperature above the T.sub.γN of the steel yet below the melting point of the steel thereby preserving a solid and creating a solid solution of nitrogen. The second temperature is optionally maintained for a nitride conversion time, optionally wherein the nitride conversion time is too short to result in sintering of the steel. The process further includes rapid quenching of the precursor powder to maintain the nitrogen solid solution and prevent nitride formation thereby forming a high nitrogen steel with little to no nitride content and including nitrogen in solid solution.