Patent classifications
C22C38/38
High-strength hot-rolled steel sheet and method for manufacturing the same
A high-strength hot-rolled steel sheet that has excellent punching workability and hole expandability, and a method for manufacturing the same. The hot-rolled steel sheet has a tensile strength of 980 MPa or more. The hot-rolled steel sheet has a chemical composition containing C, Si, Mn, P, S, Al, N, Ti, Cr, and B, and has a microstructure including a bainite phase having an area ratio of 85% or more as a main phase, and a martensite phase or martensite-austenite constituent having an area ratio of 15% or less as a second phase, the balance being a ferrite phase. The second phase has an average grain diameter of 3.0 μm or less, prior-austenite grains have an average aspect ratio of 1.3 or more and 5.0 or less, and recrystallized prior-austenite grains have an area ratio of 15% or less relative to non-recrystallized prior-austenite grains.
Ultrahigh-strength hot-rolled steel sheet and steel strip having good fatigue and reaming properties and manufacturing method therefor
An ultra-high-strength hot-rolled steel plate and steel strip having good fatigue and reaming properties and a manufacturing method therefor. The weight percentages of the components of the steel plate and the steel strip are: C: 0.07-0.14%, Si: 0.1-0.4%, Mn: 1.55-2.00%, P≤0.015%, S≤0.004%, Al: 0.01-0.05%, N≤0.005%, Cr: 0.15-0.50%, V: 0.1-0.35%, Nb: 0.01%-0.06%, Mo: 0.15-0.50%, Ti≤0.02%, and the balance of Fe and unavoidable impurities. Such components need to meet: 1.0≤[(Cr/52)/(C/4)+(Nb/93+Ti/48+V/51+Mo/96)/(C/12)]≤1.6. The tensile strength of the ultrahigh-strength hot-rolled steel plate and steel strip is ≥780 MPa, the yield strength thereof is ≥660 MPa, the tensile fatigue limit (10 million cycles) FL thereof is ≥570 MPa, or the fatigue limit to tensile strength FL/Rm thereof is ≥0.72. The reaming rate meets: if an original hole is a punched hole, the reaming rate thereof is >85%; and if the original hole is a reamed hole, the reaming rate thereof is >120%.
Ultrahigh-strength hot-rolled steel sheet and steel strip having good fatigue and reaming properties and manufacturing method therefor
An ultra-high-strength hot-rolled steel plate and steel strip having good fatigue and reaming properties and a manufacturing method therefor. The weight percentages of the components of the steel plate and the steel strip are: C: 0.07-0.14%, Si: 0.1-0.4%, Mn: 1.55-2.00%, P≤0.015%, S≤0.004%, Al: 0.01-0.05%, N≤0.005%, Cr: 0.15-0.50%, V: 0.1-0.35%, Nb: 0.01%-0.06%, Mo: 0.15-0.50%, Ti≤0.02%, and the balance of Fe and unavoidable impurities. Such components need to meet: 1.0≤[(Cr/52)/(C/4)+(Nb/93+Ti/48+V/51+Mo/96)/(C/12)]≤1.6. The tensile strength of the ultrahigh-strength hot-rolled steel plate and steel strip is ≥780 MPa, the yield strength thereof is ≥660 MPa, the tensile fatigue limit (10 million cycles) FL thereof is ≥570 MPa, or the fatigue limit to tensile strength FL/Rm thereof is ≥0.72. The reaming rate meets: if an original hole is a punched hole, the reaming rate thereof is >85%; and if the original hole is a reamed hole, the reaming rate thereof is >120%.
Production method for high-strength steel sheet
A production method for a high-strength steel sheet having a tensile strength TS of 780 MPa or more is provided. The production method comprises: heating a steel slab having a predetermined chemical composition; hotrolling the steel slab; coiling the hot-rolled sheet; subjecting the hot-rolled sheet to pickling treatment; holding the hot-rolled sheet in a pre-determined temperature range for predetermined time; cold rolling the hot-rolled sheet to obtain a cold-rolled sheet; subjecting the cold-rolled sheet to first annealing treatment; cooling the cold-rolled sheet at a pre-determined average cooling rate; cooling the cold-rolled sheet to room temperature; reheating the clod-rolled sheet to perform second annealing treatment; cooling the cold-rolled sheet at a first average cooling rate; cooling the cold-rolled sheet at a second average cooling rate; reheating the cold-rolled sheet to a predetermined reheating temperature range; and holding the cold-rolled sheet in the reheating temperature range.
Production method for high-strength steel sheet
A production method for a high-strength steel sheet having a tensile strength TS of 780 MPa or more is provided. The production method comprises: heating a steel slab having a predetermined chemical composition; hotrolling the steel slab; coiling the hot-rolled sheet; subjecting the hot-rolled sheet to pickling treatment; holding the hot-rolled sheet in a pre-determined temperature range for predetermined time; cold rolling the hot-rolled sheet to obtain a cold-rolled sheet; subjecting the cold-rolled sheet to first annealing treatment; cooling the cold-rolled sheet at a pre-determined average cooling rate; cooling the cold-rolled sheet to room temperature; reheating the clod-rolled sheet to perform second annealing treatment; cooling the cold-rolled sheet at a first average cooling rate; cooling the cold-rolled sheet at a second average cooling rate; reheating the cold-rolled sheet to a predetermined reheating temperature range; and holding the cold-rolled sheet in the reheating temperature range.
COLD-ROLLED AND ANNEALED STEEL SHEET AND MANUFACTURING METHOD
A steel sheet has a composition comprising 0.060%≤C≤0.085%, 1.8%≤Mn≤2.0%, 0.4%≤Cr≤0.6%, 0.1%≤Si≤0.5%, 0.010%≤Nb≤0.025%, 3.42N≤Ti≤0.035%, 0≤Mo≤0.030%, 0.020%≤Al≤0.060%, 0.0012%≤B≤0.0030%, S≤0.005%, P≤0.050%, 0.002%≤N≤0.007% and optionally 0.0005%≤Ca≤0.005%, the remainder of the composition being iron and unavoidable impurities. The microstructure consists of 34% to 80% bainite, 10% to 16% martensite, and 10% to 50% of ferrite. The surface fraction of unrecrystallized ferrite, with respect to the whole structure, is of less than 30%. The martensite consists of self-tempered martensite and fresh martensite, the surface fraction of self-tempered martensite being comprised between 4% and 10%.
STAINLESS STEEL HAVING EXCELLENT SURFACE ELECTRICAL CONDUCTIVITY FOR FUEL CELL SEPARATOR AND MANUFACTURING METHOD THEREFOR
Disclosed is a stainless steel having excellent surface electrical conductivity for a fuel cell separator. According to an embodiment of the disclosed stainless steel having excellent surface electrical conductivity for a fuel cell separator, a value of the following surface oxide atomic ratio (1) may be 0.5 or less, as measured on the surface of a stainless steel containing 15 wt % or more of Cr by X-ray angle-resolved photoemission spectroscopy using an Al-Kα X-ray source under the condition where a take-off angle of photoelectrons is from 12° to 85°.
The metal oxide (MO) includes a mixed oxide: M represents an alloying element other than Cr and Fe or a combination thereof in the matrix; and O represents oxygen. The total oxides and hydroxides include a Cr oxide, a Cr hydroxide, an Fe oxide, an Fe hydroxide, and the metal oxide (MO).
HOT-STAMPING FORMED BODY
A hot-stamping formed body has a predetermined chemical composition and includes microstructure which includes residual austenite of which an area ratio is in a range of 20% to 30%. Among grain boundaries of crystal grains of bainite and tempered martensite in the microstructure, a ratio of a length of a grain boundary having a rotation angle in a range of 55° to 75° to a total length of a grain boundary having a rotation angle in a range of 4° to 12°, a grain boundary having a rotation angle in a range of 49° to 54°, and a grain boundary having a rotation angle in a range of 55° to 75° to the <011> direction as a rotation axis is 30% or more.
HOT-STAMPING FORMED BODY
A hot-stamping formed body has a predetermined chemical composition and includes microstructure which includes residual austenite of which an area ratio is in a range of 20% to 30%. Among grain boundaries of crystal grains of bainite and tempered martensite in the microstructure, a ratio of a length of a grain boundary having a rotation angle in a range of 55° to 75° to a total length of a grain boundary having a rotation angle in a range of 4° to 12°, a grain boundary having a rotation angle in a range of 49° to 54°, and a grain boundary having a rotation angle in a range of 55° to 75° to the <011> direction as a rotation axis is 30% or more.
STEEL SHEET AND METHOD OF MANUFACTURING THE SAME
A steel sheet includes a predetermined composition, in which a microstructure at a ¼ thickness position from a surface in a sheet thickness direction includes, by vol %, ferrite: 80% or more, martensite: 2% or less, and residual austenite: 2% or less, a proportion of unrecrystallized ferrite in the ferrite of 5% or less, and in the microstructure of the steel sheet stretched by 10% at the ¼ thickness position from the surface in the sheet thickness direction, a number density of voids having a maximum diameter of 1.0 μm or more is 1.0×10.sup.9 pieces/m.sup.2 or less.