The invention relates to a method and a device for rapidly cooling a metal strip and removing residues present on the strip after this cooling, wherein the residues are formed during a cooling of said metal strip by a non-oxidizing liquid solution for the metal strip and a stripping liquid solution for the oxides present on the surface of the strip, or by a mixture of this liquid solution and a gas.

The present invention relates to a zinc plated steel sheet having excellent surface quality and spot weldability, and a manufacturing method therefore. A zinc plated steel sheet according to one aspect of the present invention comprises a base steel sheet and a zinc-based plating layer formed on the surface of the base steel sheet, wherein the GDOES profile of oxygen, which is measured in the depth direction from the surface of the base steel sheet, has a form in which a local minimum point and a local maximum point alternately appear in the depth direction from the surface, and the difference (a local maximum value—a local minimum value) between the oxygen concentration (a local minimum value) at the local minimum point and the oxygen concentration (a local maximum value) at the local maximum point can be 0.1 wt % or more.

A cold-rolled sheet according to an example of the present invention comprises at most 0.004 wt % (exclusive of 0 wt %) of C, at most 0.02 wt % (exclusive of 0 wt %) of Si, 0.1 to 0.3 wt % of Mn, at most 0.05 wt % (exclusive of 0 wt %) of Al, at most 0.02 wt % (exclusive of 0 wt %) of P, at most 0.001 wt % (exclusive of 0 wt %) of S, at most 0.004 wt % (exclusive of 0 wt %) of N, 0.015 to 0.035 wt % of Ti, and 0.001 to 0.003 wt % of B, with the balance being Fe and other inevitable impurities, and has a microstructure in which the crystal grain aspect ratio defined by the following equation 1 is 1.4 to 4.0.

Crystal grain aspect ratio=average crystal grain diameter in the rolling direction/average crystal grain diameter in the thickness direction   [Equation 1]

Equipment for the continuous hot dip-coating of a metal strip 9 including an annealing furnace, a tank 2 containing a liquid metal bath 3, a snout connecting the annealing furnace and tank 2, through which the metal strip 9 runs in a protective atmosphere and the lower part of the snout, the sabot 5, is at least partly immersed in the liquid metal bath 3 in order to define with the surface of the bath, and inside this snout, a liquid seal 6, an overflow 7 not connected to the snout, the overflow 7 including at least one tray 8, placed in the vicinity of the strip 9 when entering the liquid metal bath 3 and encompassed by liquid seal 6.

A method and an apparatus for environmentally-friendly batch hot-dip coating of high-performance alloy are provided. The method is that workpiece is heated to the process temperature in the heating box with inner gas before galvanizing. The heating box body consist of two or three zones, which are waiting zone, heating zone and post-plating turnover zone (the post-plating turnover zone can be omitted). A zinc pot is arranged in the heating zone, and the zinc pot is configured for hot-dip coating. Workpieces can be processed with zinc or zinc-based alloys. A transporting device is configured to successively transport in a sealed state the workpiece to be processed to the waiting zone, the heating zone, the zinc pot, and the post-plating turnover zone (the post-plating turnover zone can be omitted). The new method realizes hot-dip coating with zinc and other zinc-based alloys without the use of the flux.

Fe-Al-based plated hot-stamped member exhibiting excellent formed part corrosion resistance and post-coating corrosion resistance and manufacturing method. The hot-stamping member includes Fe-Al-based plated layer on one or both surfaces of a base material, the base material has a predetermined steel component, Fe-Al-based plated layer has a thickness of 10 μm or more and 60 μm or less, formed by A, B, C and D layers sequentially from a surface toward the base material, and each of the four layers is a Fe-Al-based intermetallic compound containing Al, Fe, Si, Mn and Cr for predetermined contents with the balance made up of impurities, the D layer further contains Kirkendall voids each of which cross-sectional area is 3 μm.sup.2-30 μm.sup.2 for 10 pieces/6000 μm.sup.2 or more and 40 pieces/6000 μm.sup.2 or less.

Provided is a highly corrosion-resistant plated steel sheet having plating adhesion and resistance to liquid metal embrittlement. A highly corrosion-resistant plated steel sheet comprises a base steel sheet and a plated layer, which sequentially comprises an Fe—Al alloy layer and an MgZn.sub.2 layer from an interface with the base steel sheet.

A steel sheet has a predetermined chemical composition, in which a microstructure in a ¼ width portion, a microstructure in a ½ width portion, and a microstructure in a ¾ width portion, include, by area %, ferrite: 80% or more, martensite: 2% or less, and residual austenite: 2% or less, in which a proportion of unrecrystallized ferrite in the ferrite is 5% to 60%, an average grain size of carbonitrides is 6.0 nm to 30.0 nm, and Expressions (2) to (5) are satisfied.

Δ.sub.SF/μ.sub.SF≤0.10  (2)

Δ.sub.dF/μ.sub.dF≤0.20  (3)

Δ.sub.SUF≤20  (4)

Δ.sub.dC/μ.sub.dC≤0.50  (5)

A method for producing a coated steel sheet having a tensile strength TS of at least 1450 MPa and a total elongation TE of at least 17% includes the successive steps of providing a cold rolled steel sheet made of a steel having a chemical composition comprising, in weight %: 0.34%≤C≤0.45%, 1.50%≤Mn≤2.30%, 1.50≤Si≤2.40%, 0%<Cr≤0.7%, 0%≤Mo≤0.3%, 0.10%≤Al≤0.7%, and optionally 0%≤Nb≤0.05%, the remainder being Fe and unavoidable impurities, annealing the cold-rolled steel sheet at an annealing temperature AT higher than the Ac3 transformation point of the steel, quenching the annealed steel sheet by cooling it down to a quenching temperature QT lower than the Ms transformation point of the steel and comprised between 150° C. and 250° C., and reheating the quenched steel sheet to a partitioning temperature PT between 350° C. and 450° C. and maintaining the steel sheet at the partitioning temperature PT for a partitioning time Pt of at least 80 s, and coating the steel sheet by galvannealing, with an alloying temperature GAT comprised between 470° C. and 520° C.

The present invention relates to a method for the manufacture of a hot-dip coated steel sheet coated with a zinc or an aluminum based coating including the provision of a specific steel sheet, a recrystallization annealing with specific heating, soaking and cooling sub-steps using an inert gas and a hot-dip coating; the hot dip coated steel sheet and the use of the hot-dip coated steel sheet.